First homoleptic isocyanides of niobium and tantalum [10]

Journal of the American Chemical Society

Volumn 121, Issue 39, 1999, Pages 9237-9238

  Barybin, Mikhail V ^a   Young Jr , Victor G ^a   Ellis, John E ^a  

^a University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYANIDE; NIOBIUM; TANTALUM;

CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; LETTER;

EID: 0032850012     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992252+     Document Type: Letter

References (41)

1. Highly Reduced Organometallics. Part 50. Part 49: Tripepi, G.; Young, V. G., Jr.; Ellis, J. E. J. Organomet. Chem. In press.
2. For reviews see: (a) Malatesta, L. Prog. Inorg. Chem. 1959, 1, 283. (b) Malatesta, L.; Bonati, F. Isocyanide Complexes of Transition Metals; Wiley: New York, 1969. (c) Treichel, P. M. Adv. Organomet. Chem. 1973, 11, 21. (d) Bonati, F.; Minghetti, G. Inorg. Chim. Acta 1974, 9, 95. (e) Yamamoto, Y. Coord. Chem. Rev. 1980, 32, 193. (f) Singleton, E.; Oosthuizen, H. E. Adv. Organomet. Chem. 1983, 22, 209. (g) Weber, L. Angew. Chem., Int. Ed. Engl. 1998, 37, 1515.
3. For reviews see: (a) Malatesta, L. Prog. Inorg. Chem. 1959, 1, 283. (b) Malatesta, L.; Bonati, F. Isocyanide Complexes of Transition Metals; Wiley: New York, 1969. (c) Treichel, P. M. Adv. Organomet. Chem. 1973, 11, 21. (d) Bonati, F.; Minghetti, G. Inorg. Chim. Acta 1974, 9, 95. (e) Yamamoto, Y. Coord. Chem. Rev. 1980, 32, 193. (f) Singleton, E.; Oosthuizen, H. E. Adv. Organomet. Chem. 1983, 22, 209. (g) Weber, L. Angew. Chem., Int. Ed. Engl. 1998, 37, 1515.
4. For reviews see: (a) Malatesta, L. Prog. Inorg. Chem. 1959, 1, 283. (b) Malatesta, L.; Bonati, F. Isocyanide Complexes of Transition Metals; Wiley: New York, 1969. (c) Treichel, P. M. Adv. Organomet. Chem. 1973, 11, 21. (d) Bonati, F.; Minghetti, G. Inorg. Chim. Acta 1974, 9, 95. (e) Yamamoto, Y. Coord. Chem. Rev. 1980, 32, 193. (f) Singleton, E.; Oosthuizen, H. E. Adv. Organomet. Chem. 1983, 22, 209. (g) Weber, L. Angew. Chem., Int. Ed. Engl. 1998, 37, 1515.
5. For reviews see: (a) Malatesta, L. Prog. Inorg. Chem. 1959, 1, 283. (b) Malatesta, L.; Bonati, F. Isocyanide Complexes of Transition Metals; Wiley: New York, 1969. (c) Treichel, P. M. Adv. Organomet. Chem. 1973, 11, 21. (d) Bonati, F.; Minghetti, G. Inorg. Chim. Acta 1974, 9, 95. (e) Yamamoto, Y. Coord. Chem. Rev. 1980, 32, 193. (f) Singleton, E.; Oosthuizen, H. E. Adv. Organomet. Chem. 1983, 22, 209. (g) Weber, L. Angew. Chem., Int. Ed. Engl. 1998, 37, 1515.
6. For reviews see: (a) Malatesta, L. Prog. Inorg. Chem. 1959, 1, 283. (b) Malatesta, L.; Bonati, F. Isocyanide Complexes of Transition Metals; Wiley: New York, 1969. (c) Treichel, P. M. Adv. Organomet. Chem. 1973, 11, 21. (d) Bonati, F.; Minghetti, G. Inorg. Chim. Acta 1974, 9, 95. (e) Yamamoto, Y. Coord. Chem. Rev. 1980, 32, 193. (f) Singleton, E.; Oosthuizen, H. E. Adv. Organomet. Chem. 1983, 22, 209. (g) Weber, L. Angew. Chem., Int. Ed. Engl. 1998, 37, 1515.
7. For reviews see: (a) Malatesta, L. Prog. Inorg. Chem. 1959, 1, 283. (b) Malatesta, L.; Bonati, F. Isocyanide Complexes of Transition Metals; Wiley: New York, 1969. (c) Treichel, P. M. Adv. Organomet. Chem. 1973, 11, 21. (d) Bonati, F.; Minghetti, G. Inorg. Chim. Acta 1974, 9, 95. (e) Yamamoto, Y. Coord. Chem. Rev. 1980, 32, 193. (f) Singleton, E.; Oosthuizen, H. E. Adv. Organomet. Chem. 1983, 22, 209. (g) Weber, L. Angew. Chem., Int. Ed. Engl. 1998, 37, 1515.
8. For reviews see: (a) Malatesta, L. Prog. Inorg. Chem. 1959, 1, 283. (b) Malatesta, L.; Bonati, F. Isocyanide Complexes of Transition Metals; Wiley: New York, 1969. (c) Treichel, P. M. Adv. Organomet. Chem. 1973, 11, 21. (d) Bonati, F.; Minghetti, G. Inorg. Chim. Acta 1974, 9, 95. (e) Yamamoto, Y. Coord. Chem. Rev. 1980, 32, 193. (f) Singleton, E.; Oosthuizen, H. E. Adv. Organomet. Chem. 1983, 22, 209. (g) Weber, L. Angew. Chem., Int. Ed. Engl. 1998, 37, 1515.
9. (a) Barybin, M. V.; Young, V. G., Jr.; Ellis, J. E. J. Am. Chem. Soc. 1998, 120, 429.
10. (b) Barybin, M. V.; Ellis, J. E. To be submitted for publication.
11. (a) Silverman, L. D.; Dewan, J. C.; Giandomenico, C. M.; Lippard, S. J. Inorg. Chem. 1980, 19, 3379.
12. (b) Silverman, L. D.; Corfield, P. W. R.; Lippard, S. J. Inorg. Chem. 1981, 20, 3106.
13. Carnahan, E. M.; Protasiewicz, J. D.; Lippard, S. J. Acc. Chem. Res. 1993, 26, 90 and references therein.
14. (a) Collazo, C.; Rodewald, D.; Schmidt, H.; Rehder, D. Organometallics 1996, 15, 4884.
15. (b) Rehder, D.; Gailus, H. Trends Organomet. Chem. 1994, 1, 397 and references therein.
16. Wigley, D. E.; Gray, S. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: New York, 1995; Vol. 4, pp 65-66 and references therein.
17. (a) Barybin, M. V.; Pomije, M. K.; Ellis, J. E. Inorg. Chim. Acta 1998, 269, 58.
18. (b) Barybin, M. V.; Ellis, J. E.; Pomije, M. K.; Tinkham, M. L.; Warnock, G. F. Inorg. Chem. 1998, 37, 6518.
19. (c) Ellis, J. E.; Warnock, G. F.; Barybin, M. V.; Pomije, M. K. Chem. Eur. J. 1995, 1, 521.
20. Leach, P. A.; Geib, S. J.; Corella, J. A., II; Warnock, G. F.; Cooper, N. J. J. Am. Chem. Soc. 1994, 116, 8566.
21. 3
22. (a) Werner, R. P. M.; Podall, H. E. Chem. Ind. (London) 1961, 144.
23. (b) Ellis, J. E.; Davison, A. Inorg. Synth. 1976, 16, 68.
24. (c) Calderazzo, F.; Englert, U.; Pampaloni, G.; Pelizzi, G.; Zamboni, R. Inorg. Chem. 1983, 22, 1865.
25. (d) Dewey, C. G.; Ellis, J. E.; Fjare, K. L.; Pfahl, K. M.; Warnock, G. F. P. Organometallics 1983, 2, 388.
26. Detailed procedures for the syntheses of all new compounds are given in the Supporting Information.
27. 1/2 = 4 Hz, CN cis to NO) ppm.
28. Calderazzo, F.; Castellani, M.; Pampaloni, G.; Zanazzi, P. F. J. Chem. Soc., Dalton Trans. 1985, 1989.
29. Bergbreiter, D. E.; Killough, J. M. J. Am. Chem. Soc. 1978, 100, 2126.
30. 2.
31. The doubled van der Waals radius of a methyl group is 4.0 Å.
32. (a) Barybin, M. V. Ph.D. Dissertation, University of Minnesota, 1999.
33. (b) Details of this analysis will be discussed in a separate publication: Barybin, M. V.; Ellis, J. E. Manuscript in preparation.
34. Cap: C(37). Capped face: C(10), C(28), C(46). Uncapped face: C(1), C(19), C(55).
35. Cap: C(55). Capped tetragonal face: C(1), C(19), C(46), C(28). Unique edge: C(10), C(37).
36. Richter-Addo, G. B.; Legzdins, P. Metal Nitrosyls; Oxford University Press: New York, 1992.
37. 2. Some thermal ellipsoids in Figure 2 are odd-shaped, which is an artifact of the very small size (0.08 × 0.07 × 0.02 mm) of the crystal used. Nevertheless, all bond distances and angles observed for 5 are well within their expected values.
38. Barybin, M. V.; Young, V. G., Jr.; Ellis, J. E. Organometallics 1999, 18, 2744.
39. Daff, P. J.; Legzdins, P.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 2688.
40. For the CNXyl ligands trans to the nitrosyls.
41. Cotton, F. A.; Kraihanzel, C. S. J. Am. Chem. Soc. 1962, 84, 4432.