Femtosecond infrared studies of a prototypical one-electron oxidative- addition reaction: Chlorine atom abstraction by the Re(CO)s radical [5]

Journal of the American Chemical Society

Volumn 121, Issue 39, 1999, Pages 9227-9228

  Yang, Haw ^a   Snee, Preston T ^a   Kotz, Kenneth T ^a   Payne, Christine K ^a   Frei, Heinz ^b   Harris, Charles B ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE; RADICAL;

CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; INFRARED SPECTROSCOPY; LETTER; OXIDATION; REACTION TIME;

EID: 0032848770     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991682x     Document Type: Letter

References (24)

1. (a) Lian, T.; Bromberg, S. E.; Yang, H.; Proulx, G.; Bergman, R. G.; Harris, C. B. J. Am. Chem. Soc. 1996, 118 (15), 3769-3770.
2. (b) Yang, H.; Kotz, K. T.; Asplund, M. C.; Harris, C. B. J. Am. Chem. Soc. 1997, 119 (40), 9564-9565.
3. (c) Bromberg, S. E.; Yang, H.; Asplund, M. C.; Lian, T.; McNamara, B. K.; Kotz, K. T.; Yeston, J. S.; Wilkens, M.; Frei, H.; Bergman, R. G.; Harris, C. B. Science 1997, 278, 260-263.
4. (d) Yang, H.; Asplund, M. C.; Kotz, K. T.; Wilkens, M. J.; Frei, H.; Harris, C. B. J. Am. Chem. Soc. 1998, 120 (39), 10154-10165.
5. (e) Asbury, J. B.; Ghosh, H. N.; Yeston, J. S.; Bergman, R. G.; Lian, T. Q. Organometllics 1998, 17 (16), 3417-3419.
6. (a) Stiegman, A. E.; Tyler, D. R. Comments Inorg. Chem. 1986, 5, 215.
7. (b) Baird, M. C. Chem. Rev., 1988, 88, 1217-1227.
8. (c) Tyler, D. R. Acc. Chem. Res. 1991, 24, 325-331 and references therein.
9. Wrighton, M. S.; Ginley, D. S. J. Am. Chem. Soc. 1975, 97 (8), 2065-2072.
10. Please refer to the Supporting Information for technical details. All uncertainties reported herein represent one standard deviation.
11. Firth, H.; Klotzbücher, W. E.; Poliakoff, M.; Turner, J. J. Inorg. Chem. 1987, 26 (20), 3370-3375.
12. Firth, S.; Hodges, P. M.; Poliakoff, M.; Turner, J. J. Inorg. Chem. 1986, 25 (25), 4608-4610.
13. 10 will be described in a separate publication. The interaction energies shown here are gas-phase values.
14. Kim, S. K.; Pedersen, S.: Zewail, A. H. Chem. Phys. Lett. 1995, 233, 500-508.
15. (a) Naqvi, K. R.; Mork, K. J.; Waldenstrøm, S. J. Phys. Chem. 1980, 84 (11), 1315-1319.
16. (b) Bultmann, T.; Ernsting, N. P. J. Phys. Chem. 1996, 100 (50), 19417-19424.
17. (c) Scott, T. W.; Liu, S. N. J. Phys. Chem. 1989, 93, 1393.
18. (d) Churchill, M. R.; Amoh, K. N.; Wasserman, H. J. J. Inorg. Chem. 1981, 20 (5), 1609-1611.
19. -1, calculated from a set of Arrhenius parameters by: Meckstroth W. K.; Reed, D. T.; Wojcicki, A. Inorg. Chim. Acta 1985, 105, 147-151.
20. BT/h) exp-(-ΔG‡/RT), T = 298 K.
21. Hammond, G. S. J. Am. Chem. Soc. 1954, 77, 334-338.
22. There is, however, only a limited extent of charge-transfer character in the calculated transition states (Table 1 of the Supporting Information).
23. (a) Herrick, R. S.; Herrinton, T. R.; Walker, H. W.; Brown, T. L. Organometallics 1985, 4, 42-45.
24. (b) Lee, K.-W.; Brown, T. L. J. Am. Chem. Soc. 1987, 109, 3269-3275.