Electrochemical reduction reactions of 1,3-diaza-dihydroazulanone derivatives: 1,3- and 1,5-hydrogen migration reactions in electrochemical reductions

Heterocycles

Volumn 50, Issue 1, 1999, Pages 63-66

  Ido, Takayasu ^a   Kondo, Satoru ^a   Saito, Katsuhiro ^a  

^a NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

DIAZADIHYDROAZULANONE DERIVATIVE; HETEROCYCLIC COMPOUND; PHENYL GROUP; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTROCHEMICAL ANALYSIS; HYBRIDIZATION; NONHUMAN; THIN LAYER CHROMATOGRAPHY;

EID: 0032838664     PISSN: 03855414     EISSN: None     Source Type: Journal    
DOI: 10.3987/com-98-s(h)43     Document Type: Article

References (14)

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2. W. E. Stewart and T. H. Siddall, Chew. Rev., 1970, 70, 517; T. Sato, Y. Fukazawa, Y. Fujise, and S. Ito, Heterocycles, 1977, 7, 807.
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4. K. Ito, K. Saito, and K. Takahashi, Bull. Chem. Soc. Jpn., 1992, 65, 812; M. Nitta, H. Tomioka, A. Akaogi, K. Takahashi, K. Saito, and K. Ito, J. Chem. Soc., Parkin Trans. 1, 1994, 2625; K. Ito and K. Saito, Bull. Chem. Soc. Jpn., 1995, 68, 3539.
5. K. Ito, K. Saito, and K. Takahashi, Bull. Chem. Soc. Jpn., 1992, 65, 812; M. Nitta, H. Tomioka, A. Akaogi, K. Takahashi, K. Saito, and K. Ito, J. Chem. Soc., Parkin Trans. 1, 1994, 2625; K. Ito and K. Saito, Bull. Chem. Soc. Jpn., 1995, 68, 3539.
6. K. Ito and K. Saito, Heterocycles, 1994, 38, 2691; idem, ibid., 1995, 41, 2307.
7. K. Ito and K. Saito, Heterocycles, 1994, 38, 2691; idem, ibid., 1995, 41, 2307.
8. K. Saito, M. Hattori, T. Sato, and K. Takahashi, Heterocycles, 1992, 34, 129; S. Kondo, H. Suzuki, T. Hattori, T. Ido, and K. Saito, ibid., in press.
9. K. Saito, M. Hattori, T. Sato, and K. Takahashi, Heterocycles, 1992, 34, 129; S. Kondo, H. Suzuki, T. Hattori, T. Ido, and K. Saito, ibid., in press.
10. 2O: C, 80.20; H, 5.77; N,8.95. Found: C, 80.08; H, 5.42; N, 8.85.
11. K. Ito, K. Saito, and K. Takahashi, Heterocycles, 1991, 32, 1117; K. Ito, Y. Hara, R. Sakakibara, and K. Saito, ibid, 1995, 41, 1675.
12. K. Ito, K. Saito, and K. Takahashi, Heterocycles, 1991, 32, 1117; K. Ito, Y. Hara, R. Sakakibara, and K. Saito, ibid, 1995, 41, 1675.
13. The authors are indebted to Prof. Yoshiro Yamashita of Institute for Molecular Science for measurements of cyclic voltammetries and for MO calculations.
14. There is a possibility of a reversible 1,3-hydrogen migration between 6 and 7. A 1,3-hydrogen migration on cycloheptatriene moieties has been reported to proceed in a basic media. K. Takahashi, H. Yamamoto, and T. Nozoe, Bull. Chem. Soc. Jpn., 1970, 43, 200.