Spectrophotometric study of the formation of iron(III)-hydroperoxy complexes in homogeneous aqueous solutions

Water Research

Volumn 33, Issue 13, 1999, Pages 2929-2936

  Gallard, H ^a   De Laat, J ^a   Legube, B ^a  

^a UNIVERSITÉ DE POITIERS   (France)

Author keywords

Equilibrium constants; Fe(III) hydroperoxy complexes; Fenton's reagent; Ferric ions; Hydrogen peroxide; Spectrophotometric study

Indexed keywords

AGENTS; COMPLEXATION; FREE RADICALS; HYDROGEN PEROXIDE; PHASE EQUILIBRIA; SOLUTIONS; SPECTROPHOTOMETRY;

EQUILIBRIUM CONSTANTS; FENTONS REAGENT; IRON HYDROPEROXY COMPLEXES;

IRON COMPOUNDS;

FERRIC ION; HYDROGEN PEROXIDE; REAGENT;

AQUEOUS SOLUTION; ARTICLE; CALCULATION; CHEMICAL REACTION; COMPLEX FORMATION; EQUILIBRIUM CONSTANT; IONIC STRENGTH; PH; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 0032819859     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0043-1354(99)00007-X     Document Type: Article

References (34)

1. Barb W.G., Baxendale J.H., George P., Hargrave K.R. Reactions of ferrous and ferric ions with hydrogen peroxide. Nature. 163:1949;692-694.
2. Barb W.G., Baxendale J.H., George P., Hargrave K.R. Reactions of ferrous and ferric ions with hydrogen peroxide Part II - The ferric ion reaction. Trans. Faraday Soc. 47:1951;591-616.
3. Barbeni M., Minero C., Pelizzeti E. Chemical degradation of chlorophenols with Fenton's reagent. Chemosphere. 16:(10-12):1987;225-2237.
4. Baxendale J.H. Decomposition of hydrogen peroxide by catalysts in homogeneous aqueous solution. Adv. Catal. 4:1952;31-86.
5. Bishop D.F., Stern G., Fleischman M., Marshall L.S. Hydrogen peroxide catalytic oxidation of refractory organics in municipal waste waters. Ind. Eng. Chem. Process Des. Dev. 7:(1):1968;110-117.
6. Brown S.B., Jones P., Suggett A. Recent developments in the redox chemistry of peroxides. Prog. Org. Chem. 13:1970;159-204.
7. 2+ complexes. Trans. Faraday Soc. 45:1949;230-236.
8. Faust B.C., Hoigne J. Photolysis of Fe(III)-hydroxy complexes as sources of OH radicals in clouds, fog and rain. Atmos. Environ. 24A:(1):1990;79-89.
9. Graedel T.E., Mandich M.L., Weschler C.J. Kinetic model studies of atmospheric droplet chemistry 2. Homogeneous transition metal chemistry in raindrops. J. Geophys. Res. 91:(4):1986;5205-5221.
10. Haber F., Weiss J. The catalytic decomposition of hydrogen peroxide by iron salts. Proc. Roy. Soc. A. 134:1934;332-351.
11. Haggett M.L., Jones P., Wynne-Jones W.F.K. Peroxy-complexes as intermediates in the catalytic decomposition of hydrogen peroxide. Discussions Faraday Soc. 29:1960;153-162.
12. Jayson G.G., Keene J.P., Stirling D.A., Swallow A.J. Pulse-radiolysis study of some unstable complexes of iron. Trans. Faraday Soc. 65:1969;2453-2464.
13. Jayson G.G., Parsons B.J., Swallow A.J. Oxidation of ferrous ions by perhydroxyl radicals. J.C.S. Faraday I. 69:1973;236-242.
14. Jones P., Kitching R., Tobe M.L., Wynne-Jones W.F.K. Hydrogen peroxide+water mixtures. Part 4. Catalytic decomposition of hydrogen peroxide. Trans. Faraday Soc. 55:1959;79-90.
15. Jones P., Kitching R., Wynne-Jones W.F.K. Hydrogen peroxide+water mixtures. Part 5. Stabilization against the iron perchlorate catalyzed decomposition of hydrogen peroxide. Trans. Faraday Soc. 55:1959;91-97.
16. Knight R.J., Sylva R.N. Spectrophotometric investigation of iron(III) hydrolysis in light and heavy water at 25°C. J. Inorg. Nucl. Chem. 37:1975;779-783.
17. Kremer M.L. Oxidation reduction step in catalytic decomposition of hydrogen peroxide by ferric ions. Trans. Faraday Soc. 59:1963;2535-2542.
18. 2 by ferric ions. Int. J. Chem. Kinet. 17:1985;1299-1314.
19. Kremer M.L., Stein G. The catalytic decomposition of hydrogen peroxide by ferric perchlorate. Trans. Faraday. Soc. 55:1959;959-973.
20. 2 reaction: Steady-state and terminal-state analysis. Int. J. Chem. Kinet. 9:1977;179-184.
21. Lewis T.J., Richards D.H. and Salter D.A. (1963) Peroxy-complexes of inorganic ions in hydrogen peroxide-water mixtures. Part I. Decomposition by ferric ions. J. Chem. Soc. 2434-2442.
22. Milburn R.M., Vosburgh W.C. A spectrophotometric study of the hydrolysis of iron(III) ion. II. Polynuclear species. J. Am. Chem. Soc. 77:1955;1352-1355.
23. 3+-catalyzed degradation of chlorophenoxy herbicides by hydrogen peroxide. Environ. Sci. Technol. 26:(5):1992;944-951.
24. Safarzadeh-Amiri A., Bolton J.R., Cater S.R. The use of iron in advanced oxidation processes. J. Adv. Oxid. Technol. 1:(1):1996;18-26.
25. Sedlak D.L., Hoigne J. The role of copper and oxalate in the redox cycling of iron in atmospheric waters. Atmos. Environ. 27A:(14):1993;2173-2185.
26. Sedlak D.L., Hoigne J. Oxidation of S(IV) in atmospheric water by photooxidants and iron in the presence of copper. Environ. Sci. Technol. 28:(11):1994;1898-1906.
27. Sulzberger B., Canonica S., Egli T., Giger W., Klausen J., Von Gunten U. Oxidative transformations of contaminants in natural and in technical systems. Chimia. 51:(12):1997;900-907.
28. Sun Y., Pignatello J.J. Chemical treatment of pesticide wastes. Evaluation of Fe(III) chelates for catalytic hydrogen peroxide oxidation of 2,4-D at circumneutral pH. J. Agric. Food Chem. 40:(2):1992;322-327.
29. Turner D.R., Whitfield M., Dickson A.G. The equilibrium speciation of dissolved components in freshwater and seawater at 25°C and 1 atm pressure. Geochim. Cosmochim. Acta. 45:1981;855-881.
30. Voelker B.M., Sedlak D.L. Iron reduction by photoproduced superoxide in seawater. Mar. Chem. 50:1995;93-102.
31. Walling C., Cleary M. Oxygen evolution as a critical test of mechanism in the ferric-ion catalyzed decomposition of hydrogen peroxide. Int. J. Chem. Kinet. 9:1977;595-601.
32. Walling C., Goosen A. Mechanism of the ferric ion catalyzed decomposition of hydrogen peroxide. Effect of organic substrates. J. Am. Chem. Soc. 95:(9):1973;2987-2991.
33. Walling C., Weill T. The ferric ion catalyzed decomposition of hydrogen peroxide in perchloric acid solution. Int. J. Chem. Kinet. 6:1974;507-516.
34. Weschler C.J., Mandich M.L., Graedel T.E. Speciation, photosensitivity, and reactions of transition metals ions in atmospheric droplets. J. Geophys. Res. 91:(4):1986;5189-5204.