Kinetics on a supported catalyst at supercritical, nondeactivating conditions

AIChE Journal

Volumn 45, Issue 7, 1999, Pages 1559-1565

  Clark, Michael C ^a,b   Subramaniam, Bala ^a  

^a UNIVERSITY OF KANSAS   (United States)

^b EXXONMOBIL UPSTREAM RESEARCH COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATED ALUMINA; ACTIVATION ENERGY; ALUMINA; CATALYST ACTIVITY; CATALYSTS; IMPURITIES; ISOMERIZATION; PEROXIDES;

COKE PRECURSORS; EFFECTIVENESS FACTOR; ISOMERIZATION RATE; PEROXIDE IMPURITIES;

REACTION KINETICS;

ALUMINUM OXIDE;

ARTICLE; CATALYSIS; CATALYST; COKING INDUSTRY; ISOMERISM; REACTION ANALYSIS;

ARRHENIUS;

EID: 0032814680     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690450717     Document Type: Article

References (32)

1. Anderson, J. R., and P. Tsai, "Oxidation of Methane over H-ZSM-5 and Other Catalysts," App. Catal., 19, 141 (1985).
2. Baptist-Nguyen, S., and B. Subramaniam, "Coking and Activity of Porous Catalysts in Supercritical Reaction Media," AIChE J., 38, 1027 (1992).
3. Beal, E. J., and D. R. Hardy, "The Effect of Temperature on Jet Fuel Thermal Stability Defined by Direct Gravimetric Analysis of Both Surface and Fuel Insoluble Deposits," Preprints, Div. Pet. Chem. Am. Chem. Soc., 39, 82 (1994).
4. Butt, J. B., and E. E. Petersen, Activation, Deactivation, and Poisoning of Catalysts, Academic Press, San Diego (1988).
5. Cavani, F., "Role of Molecular Oxygen in the Catalytic Behavior of ZSM-5 Zeolite in Hydrocarbon Transformation," Appl. Catal. A: General, 94, 131 (1993).
6. Centi, G., and G. Golinelli, "The Effect of Oxygen on the Conversion of Light Paraffins on ZSM-5 Zeolites," J. Catal., 115, 452 (1989).
7. Che, M., and A. J. Tench, "Characterization and Reactivity of Mononuclear Oxygen Species on Oxide Surfaces," Advances in Catalysis, Vol. 77, Academic Press, New York, p. 77 (1982).
8. Chin, L. P., V. R. Katta, and S. P. Heneghan, "Numerical Modeling of Jet-Fuel Autoxidation in Flowing Systems," Preprints, Div. Pet. Chem. Amer. Chem. Soc., 39, 19 (1994).
9. Chen, N. Y., T. F. Degnan, Jr., and C. M. Smith, Molecular Transport and Reaction in Zeolites: Design and Application of Shape Selective Catalysts, VCH, New York, p. 42 (1994).
10. Clark, M. C., "Enhancing the Activity of Acidic Catalysts with Supercritical Reaction Media," PhD Diss., Univ. of Kansas (1998).
11. 3 Catalyst: The Dramatic Effects of Feed Peroxides on Catalyst Activity,γ Chem. Eng. Sci., 51, 2369 (1996).
12. Corma, A., and A. Martinez, "Chemistry, Catalysis, and Processes for Isoparaffin-Olefin Alkylation: Actual Situation and Future Trends," Catal. Rev.-Sci. Eng., 35, 483 (1993).
13. Gates, B. C., Catalytic Chemistry, Wiley, New York (1991).
14. Ginosar, D. M., and B. Subramaniam, "Olefinic Oligomer and Cosolvent Effects on the Coking and Activity of a Reforming Catalyst in Supercritical Reaction Mixtures," J. Catal., 152, 31 (1995).
15. Guisnet, M., P. Magnoux, and D. Martin, Catalyst Deactivation: Studies in Surface Science and Catalysis, C. H. Bartholomew and G. A. Fuentes, eds., Vol. III, Elsevier, Amsterdam, p. 1 (1997).
16. Heneghan, S. P., "Global Oxidation of Jet Fuels: Determining and Understanding the Parameters," Preprints, Div. Pet. Chem. Am. Chem. Soc., 39, 14 (1994).
17. Hunter, R., G. J. Hutchings, and W. Pickl, "Mechanistic Studies on Initial C-C Bond Formation in the Zeolite ZSM-5 Catalyzed Methanol Conversion Reaction - Evidence Against a Radical Pathway," J. Chem. Soc. - Chem. Commun., 11, 843 (1987).
18. Jones, E. G., W. J. Balster, and W. A. Rubey, "Fouling of Stainless Steel and Silcosteel Surfaces During Aviation-Fuel Autooxidation," Preprints, Div. Pet. Chem. Am. Chem. Soc., 40, 655 (1995).
19. Koetsier, W. T., and J. van Leenen, "Oxygen Induced Fouling in a Xylene Isomerization Reactor Bed," Catalyst Deactivation 1987: Studies in Surface Science and Catalysis, B. Delmon and G. F. Froment, eds., Vol. 34, Elsevier Science Publishers, Amsterdam, p. 579 (1987).
20. Lee, H., and G. Thodos, "Generalized Treatment of Self-Diffusivity for the Gaseous and Liquid States of Fluids," Ind. Eng. Chem. Fundam., 22, 17 (1983).
21. Morris, R. E., and M. A. Wechter, "The Application of Light Scattering Photometry to Evaluate Jet Fuel Stability," Preprints, Div. Pet. Chem. Am. Chem. Soc., 39, 58 (1994).
22. Polzer, J., and K. Bachmann, "Sensitive Determination of Alkyl Hydroperoxides by High-Resolution Gas Chromatography-Mass Spectrometry and High-Resolution Gas Chromatography with Flame Ionization Detector," J. Chromatog. A, 653, 283 (1993).
23. 3 Catalyst at Subcritical and Supercritical Conditions: Temperature, Pressure and Solvent Effects on Catalyst Coking," PhD Diss., Univ. of Kansas (1990).
24. Satterfield, C. N., Heterogeneous Catalysis in Industrial Practice, 2nd ed., McGraw-Hill, New York (1991).
25. Schmidt, B., "Reaktionstechnische Untersuchungen zur Isomerisierung von Buten-(1) an einem Schalenkontakt bei hohem Druck," Master's Thesis, Friedrich-Alexander-Universität Erlangen-Nurnberg, p. 54 (1988).
26. Shin, S., "Chemical Reaction of Alkenes and Alkynes with Solid State Defects on ZSM-5," J. Catal., 79, 390 (1983).
27. Sobkowiak, M., L. Selvaraj, E. Yoon, and E. E. Coleman, "Potential Stabilizers for Jet Fuels Subjected to Thermal Stress above 400°C: 2. NMR Studies," Preprints, Fuel Chem. Div., Amer. Chem. Soc., 37, 1664 (1992).
28. Song, C, W.-C. Lai, and H. H. Schobert, "Hydrogen-Transferring Pyrolysis of Long-Chain Alkanes and Thermal Stability Improvement of Jet Fuels by Hydrogen Donors," Ind. Eng. Chem. Res., 33, 548 (1994).
29. Striebich, R. C., W. A. Rubey, and S. D. Anderson, "Surface Adsorption Studies Using Inverse Gas Chromatography and Inverse Liquid Chromatography," Preprints, Div. Pet., Amer. Chem. Soc., 39, 64 (1994).
30. Takahashi, S., "Preparation of a Generalized Chart for the Diffusion Coefficients of Gases at High Pressure," J. Chem. Eng. Japan, 7, 417 (1974).
31. Taylor, W. F., "Deposit Formation from Deoxygenated Hydrocarbons: I. General Features," I&EC Prod. Res. Dev., 13, 133 (1974).
32. Trimm, D. L., Deactivation and Poisoning of Catalysts, J. Oudar and H. Wise, eds., Marcel Dekker, New York and Basel (1985).