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0009610519
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note
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1 micelles can be obtained by sonication of a water suspension and, if necessary, coarse filtration of the remaining microcrystalline solid.
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37
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0009562689
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note
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1 in water would show a B-band at energies similar (413 nm) to that of the other sulfonated tetraphenylporphyrins.
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0009612596
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note
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1 in pure water solutions. In the case of low soluble porphyrins the addition of the solid free base to the acid solutions results in undefined suspensions, which contain microcrystalline diprotonated porphyrin that incorporate part of the non-protonated porphyrin. The association degree increases for all homoassociates with the ionic strength. However, for the diprotonated systems, since all the results reported here refer to 1 M HCl solutions, the effect of the ionic strength when we compared different porphyrin concentrations is probably not significant.
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42
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43
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0009647177
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note
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1 results in an ordered organic phase, which includes ordered NaCl crystals in its matrix. Further details will be reported elsewhere.
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46
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0009562083
-
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note
-
We suspect that the use of rotational evaporators in the work-up of samples of diprotonated porphyrins is the reason for the spontaneous induced CD. A standard magnetic stirrer (anti-clockwise sign on Fig. 10 and Supplementary Data files) induces a M-vortex.
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0009595169
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note
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The sign and magnitude of the differential scattering (absorption) of circularly polarized light depends on the variation dσ/dn (dσ/dk) [where σ the optical cross section and n (k) the real (imaginary) part of the diffraction index]; see ref. 24. This differential scattering has been studied in aggregates of biorganic macro"molecules and supramolecular biological entities, such as chloroplasts.
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