Oxidation of enolate anion by hypervalent iodine compounds: Synthesis of α-tempo carbonyl compound, a new living radical polymerization initiator

Synthetic Communications

Volumn 29, Issue 24, 1999, Pages 4361-4366

  Ahn, Kwang Hyun ^a   Kim, Younghun ^a  

^a Kyung Hee University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

2,2,6,6 TETRAMETHYLPIPERIDINYL 1 OXYL RADICAL; FREE RADICAL; IODINE; STYRENE; UNCLASSIFIED DRUG;

ANION TRANSPORT; ARTICLE; MOLECULAR DYNAMICS; ORGANIC CHEMISTRY; OXIDATION; POLYMERIZATION; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0032805735     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1080/00397919908086598     Document Type: Article

References (8)

1. Paquette L.A. Ed., In "Encyclopedia of Reagents for Organic Synthesis," John Wiley & Sons, Chichester, 1995, Vol. 7, pp. 4821-4823.
2. Hawker, C.J. Acc. Chem. Res. 1997, 30, 373-382 and references cited therein.
3. Hawker, C. J.; Barclay, G.G.; Orellana, A.; Dao, J.; Devonport, W. Macromolecules 1996, 29, 5245-5254.
4. Braslau, R.; Burrill II, L.C.; Siano, M.; Naik, N.; Howden, R.K.; Mahal, L.K. Macromolecules 1997, 30, 6445-6450.
5. Kim, J.W.; Lee, J.-J.; Lee, S.-H.; Ahn, K.-H. Synth. Commun. 1998, 28, 1287-1292.
6. + 320.2226, found 320.2232.
7. 4 (47 mg) was formed in 33 % yield.
8. Jahn, U. J. Org. Chem. 1998, 63, 7130-7131.