Reduction of bis(phosphonio)isophosphindolides to phosphane- functionalized benzo[c]phospholides

European Journal of Inorganic Chemistry

Volumn , Issue 7, 1999, Pages 1169-1174

  Gudat, Dietrich ^a   Bajorat, Volker ^a   Häp, Stefan ^a   Nieger, Martin ^a   Schröder, Gisela ^a  

^a UNIVERSITY OF BONN   (Germany)

Author keywords

Nickel complexes; NMR spectroscopy; Phospholides; Phosphorus heterocycles; Reductions

Indexed keywords

LANTHANUM; NAPHTHALENE; NICKEL COMPOUNDS; PHOSPHORUS; X RAY DIFFRACTION ANALYSIS;

% REDUCTIONS; FUNCTIONALIZED; HETEROCYCLES; NICKEL COMPLEX; NMR-SPECTROSCOPY; PHOSPHANES; PHOSPHOLIDES; PHOSPHORUS HETEROCYCLES; SITU NMR STUDY; SUBSTITUTION PRODUCTS;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

CYCLOPENTADIENE DERIVATIVE; HETEROCYCLIC COMPOUND; NICKEL COMPLEX; PHOSPHONIUM DERIVATIVE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; X RAY DIFFRACTION;

EID: 0032803832     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1099-0682(199907)1999:7<1169::aid-ejic1169>3.0.co;2-q     Document Type: Article

References (29)

1. [1a] F. Mathey, Coord. Chem. Rev. 1994, 137, 1.
2. [1b] K. B. Dillon, F. Mathey, J. F. Nixon, Phosphorus: The Carbon Copy, J. Wiley & Sons, Chichester, 1998, p. 227.
3. [2a] E. J. Padma Malar, J. Org. Chem. 1992, 57, 3694.
4. [2b] D. B. Chesnut, L. D. Quin, J. Am. Chem. Soc. 1994, 116, 9638.
5. [2c] B. Goldfuss, P. v. R. Schleyer, F. Hampel, Organometallics 1996, 15, 1755.
6. See, for example: P. Jutzi, T. Redeker, Eur. J. Inorg. Chem. 1998, 663, and references cited therein
7. [4a] A. Espinosa Ferao, B. Deschamps, F. Mathey, Bull. Soc. Chim. Fr. 1993, 130, 695.
8. [4b] S. Roland, M. Jeanjean, F. Mathey, Angew. Chem. 1997, 109, 117; Angew. Chem. Int. Ed. Engl. 1997, 36, 98.
9. [4b] S. Roland, M. Jeanjean, F. Mathey, Angew. Chem. 1997, 109, 117; Angew. Chem. Int. Ed. Engl. 1997, 36, 98.
10. For the generation of side-chain-functionalized phospholides in metal coordination spheres, see: [5a] B. Deschamps, F. Mathey, Organometallics 1992, 11, 1411. [5b] C. Ganter, L. Brassat, C. Glinsböckel, B. Ganter, Organometallics 1997, 16, 2862. [5c] C. Ganter, L. Brassat, B. Ganter, Chem. Ber. 1997, 130, 1771.
11. For the generation of side-chain-functionalized phospholides in metal coordination spheres, see: [5a] B. Deschamps, F. Mathey, Organometallics 1992, 11, 1411. [5b] C. Ganter, L. Brassat, C. Glinsböckel, B. Ganter, Organometallics 1997, 16, 2862. [5c] C. Ganter, L. Brassat, B. Ganter, Chem. Ber. 1997, 130, 1771.
12. For the generation of side-chain-functionalized phospholides in metal coordination spheres, see: [5a] B. Deschamps, F. Mathey, Organometallics 1992, 11, 1411. [5b] C. Ganter, L. Brassat, C. Glinsböckel, B. Ganter, Organometallics 1997, 16, 2862. [5c] C. Ganter, L. Brassat, B. Ganter, Chem. Ber. 1997, 130, 1771.
13. H. J Cristau, F. Plenat, in The Chemistry of Organophosphorus Compounds, vol. 3 (Ed.: F. R. Hartley), J. Wiley & Sons, Chichester, 1994, p. 45.
14. D. Gudat, V. Bajorat, M. Nieger, Bull. Soc. Chim. Fr. 1995, 132, 280.
15. For the synthesis and characterization of a benzo[b]phospholide, see: E. Niecke, M. Nieger, P. Wenderoth, Angew. Chem. 1994, 106, 362; Angew. Chem. Int. Ed. Engl. 1994, 33, 353.
16. For the synthesis and characterization of a benzo[b]phospholide, see: E. Niecke, M. Nieger, P. Wenderoth, Angew. Chem. 1994, 106, 362; Angew. Chem. Int. Ed. Engl. 1994, 33, 353.
17. A. Schmidpeter, M. Thiele, Angew. Chem. 1991, 103, 333; Angew. Chem. Int. Ed. Engl. 1991, 30, 308.
18. A. Schmidpeter, M. Thiele, Angew. Chem. 1991, 103, 333; Angew. Chem. Int. Ed. Engl. 1991, 30, 308.
19. D. Gudat, Phosphorus Sulfur Silicon 1993, 77, 238.
20. W. A. Herrmann, C. Zybill, in Synthetic Methods of Organometallic and Inorganic Chemistry, vol. 1 (Ed.: W. A. Herrmann), Georg Thieme Verlag, Stuttgart, 1996, p. 41.
21. J. C. Tebby, in Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis (Eds.: J. G. Verkade, L. D. Quin), VCH, Deerfield Beach, 1987, p. 1.
22. All calculations were performed with the Gaussian 94 package: M. J. Frisch, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. A. Robb, J. R. Cheeseman, T. Keith, G. A. Petersson, J. A. Montgomery, K. Raghavachari, M. A. Al-Laham, V. G. Zakrzewski, J. V. Ortiz, J. B. Foresman, C. Y. Peng, P. Y. Ayala, W. Chen, M. W. Wong, J. L. Andres, E. S. Replogle, R. Gomperts, R. L. Martin, D. J. Fox, J. S. Binkley, D. J. Defrees, J. Baker, J. P. Stewart, M. Head-Gordon, C. Gonzalez, J. A. Pople, Gaussian 94, Rev. B.3, Gaussian, Inc., Pittsburgh PA, 1995.
23. D. Gudat, M. Nieger, M. Schrott, Chem. Ber. 1995, 128, 259.
24. International Tables for Crystallography, vol. C (Ed.: A. J. C. Wilson), Kluwer Academic Publishers, Dordrecht, 1992, p. 680.
25. [16a] N. Burford, B. W. Royan, A. Linden, T. S. Cameron, Inorg. Chem. 1989, 28, 144.
26. [16b] N. Burford, A. I. Dipchand, B. W. Royan, P. S. White, Inorg. Chem. 1990, 29, 4938.
27. [16c] N. Burford, A. I. Dipchand, B. W. Royan, P. S. White, Acta Crystallogr. 1989, C45, 1485.
28. A. W. Johnson, Ylides and Imines of Phosphorus, J. Wiley & Sons, New York, 1993, p. 139.
29. P(B),P(B′) = 5.5 Hz.