Kinetics of the aqueous-phase reaction between ozone and 2,4,6- trichlorophenol

AIChE Journal

Volumn 45, Issue 8, 1999, Pages 1802-1807

  Rinker, Edward B ^a   Ashour, Sami S ^a   Johnson, Michael C ^a   Kott, Gregory J ^a   Rinker, Robert G ^a   Sandall, Orville C ^a  

^a University of California   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIFFUSION; MATHEMATICAL MODELS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OZONE; PH EFFECTS; PHASE COMPOSITION; PHENOLS; RATE CONSTANTS; SOLUTIONS;

AQUEOUS PHASE REACTION; LAMINAR LIQUID FILMS; TRICHLOROPHENOL;

ABSORPTION;

2,4,6 TRICHLOROPHENOL; 2,6 DICHLOROHYDROQUINONE; 2,6 DICHLOROQUINONE; 4,6 DICHLOROCATECHOL; CARBON 13; OZONE; UNCLASSIFIED DRUG;

ABSORPTION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION KINETICS; DATA ANALYSIS; DIFFUSION; MATHEMATICAL MODEL; OZONE LAYER; WASTE WATER MANAGEMENT;

EID: 0032798927     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690450815     Document Type: Article

References (14)

1. Al-Ghawas, H. A., D. P. Hagewiesche, G. Ruiz-Ibarez, and O. C. Sandall, "Physicochemical Properties Important for Carbon Dioxide Adsorption in Aqueous Methydiethanolamine," J. Chem. Eng. Data, 34, 385 (1989).
2. Augugliaro, V., and L. Ruzzuti, "The pH Dependence of the Ozone Absorption Kinetics in Aqueous Phenol Solutions," Chem. Eng. Sci., 33, 1441 (1978).
3. Danckwerts, P. V., Gas-Liquid Reactions, McGraw-Hill, New York (1970).
4. Eisenhauer, H. R., "The Ozonation of Phenolic Wastes," J. WPCF, 40, 1887 (1968).
5. Gould, J. P., and W. J. Weber, "Oxidation of Phenols by Ozone," J. WPCF, 48, 47 (1976).
6. Hanna, O. T., and O. C. Sandall, Computational Methods in Chemical Engineering, Prentice Hall, Englewood Cliffs, NJ (1995).
7. Higbie, R., "The Rate of Absorption of a Pure Gas into a Still Liquid During Short Periods of Exposure," Trans. Amer. Inst. Chem. Eng., 31, 365 (1935).
8. Hoigne, J., and H. Bader, "Rate Constants of Reactions of Ozone with Organics and Inorganic Compounds in Water - II," Water Res., 17, 185 (1983).
9. Li, K. Y., C. H. Kuo, and J. L. Weeks, "A Kinetic Study of Ozone-Phenol Reaction in Aqueous Solution," AIChE J., 25, 583 (1979).
10. Lynn, S., J. R. Straatemeier, and H. Kramers, "Absorption Studies in the Light of the Penetration Theory: III. Absorption by Wetted Spheres, Singly and in Columns," Chem. Eng. Sci., 4, 63 (1955).
11. Rinker, E. B., S. S. Ashour, and O. C. Sandall, "Kinetics and Modeling of Carbon Dioxide Absorption into Aqueous Solutions of N-Methyldiethanolamine," Chem. Eng. Sci., 50, 755 (1995).
12. Roth, J. A., and D. E. Sullivan, "Solubility of Ozone in Water," Ind. Eng. Chem. Fundam., 20, 137 (1981).
13. Wegman, R. C. C., and H. H. van den Broek, "Chlorophenols in River Sediment in the Netherlands," Water Res., 17, 227 (1983).
14. Wild, J. D., and O. E. Potter, "Gas Absorption with Chemical Reaction into Liquid Flowing on a Sphere," Inst. Chem. Eng., Symp. Series, 28, 30 (1968).