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For the synthesis of various ethylsilanes by ethylation of halosilanes using appropriate organometallics, mainly Grignard reagents, see. R. N. Lewis, J. Am. Chem. Soc. 1947, 69, 717; M. F. Shostakovskii, D. A. Kochkin, I. A. Shikhiev, V. M. Vlassov, Zh. Obshch. Khim. 1955, 25, 622 (Chem. Abstr. 1956, 50, 3270b; L. H. Sommer, F. C. Whitmore, J. Am. Chem. Soc. 1946, 68, 485; V. F. Mironov, V. V. Nepomnina, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk 1959, 1231 (Chem. Abstr. 1960, 54, 1268e); G. V. Golodnikov, G. N. Koroleva, Zh. Obshch. Khim. 1961, 31, 3738 (Chem. Abstr 1962, 57, 8601d).
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2842516788
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Vlassov, V.M.4
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84987410411
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For the synthesis of various ethylsilanes by ethylation of halosilanes using appropriate organometallics, mainly Grignard reagents, see. R. N. Lewis, J. Am. Chem. Soc. 1947, 69, 717; M. F. Shostakovskii, D. A. Kochkin, I. A. Shikhiev, V. M. Vlassov, Zh. Obshch. Khim. 1955, 25, 622 (Chem. Abstr. 1956, 50, 3270b; L. H. Sommer, F. C. Whitmore, J. Am. Chem. Soc. 1946, 68, 485; V. F. Mironov, V. V. Nepomnina, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk 1959, 1231 (Chem. Abstr. 1960, 54, 1268e); G. V. Golodnikov, G. N. Koroleva, Zh. Obshch. Khim. 1961, 31, 3738 (Chem. Abstr 1962, 57, 8601d).
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Chem. Abstr.
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7
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0001549731
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For the synthesis of various ethylsilanes by ethylation of halosilanes using appropriate organometallics, mainly Grignard reagents, see. R. N. Lewis, J. Am. Chem. Soc. 1947, 69, 717; M. F. Shostakovskii, D. A. Kochkin, I. A. Shikhiev, V. M. Vlassov, Zh. Obshch. Khim. 1955, 25, 622 (Chem. Abstr. 1956, 50, 3270b; L. H. Sommer, F. C. Whitmore, J. Am. Chem. Soc. 1946, 68, 485; V. F. Mironov, V. V. Nepomnina, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk 1959, 1231 (Chem. Abstr. 1960, 54, 1268e); G. V. Golodnikov, G. N. Koroleva, Zh. Obshch. Khim. 1961, 31, 3738 (Chem. Abstr 1962, 57, 8601d).
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Sommer, L.H.1
Whitmore, F.C.2
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0011472899
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For the synthesis of various ethylsilanes by ethylation of halosilanes using appropriate organometallics, mainly Grignard reagents, see. R. N. Lewis, J. Am. Chem. Soc. 1947, 69, 717; M. F. Shostakovskii, D. A. Kochkin, I. A. Shikhiev, V. M. Vlassov, Zh. Obshch. Khim. 1955, 25, 622 (Chem. Abstr. 1956, 50, 3270b; L. H. Sommer, F. C. Whitmore, J. Am. Chem. Soc. 1946, 68, 485; V. F. Mironov, V. V. Nepomnina, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk 1959, 1231 (Chem. Abstr. 1960, 54, 1268e); G. V. Golodnikov, G. N. Koroleva, Zh. Obshch. Khim. 1961, 31, 3738 (Chem. Abstr 1962, 57, 8601d).
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Mironov, V.F.1
Nepomnina, V.V.2
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9
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13044283126
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For the synthesis of various ethylsilanes by ethylation of halosilanes using appropriate organometallics, mainly Grignard reagents, see. R. N. Lewis, J. Am. Chem. Soc. 1947, 69, 717; M. F. Shostakovskii, D. A. Kochkin, I. A. Shikhiev, V. M. Vlassov, Zh. Obshch. Khim. 1955, 25, 622 (Chem. Abstr. 1956, 50, 3270b; L. H. Sommer, F. C. Whitmore, J. Am. Chem. Soc. 1946, 68, 485; V. F. Mironov, V. V. Nepomnina, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk 1959, 1231 (Chem. Abstr. 1960, 54, 1268e); G. V. Golodnikov, G. N. Koroleva, Zh. Obshch. Khim. 1961, 31, 3738 (Chem. Abstr 1962, 57, 8601d).
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10
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13044253576
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For the synthesis of various ethylsilanes by ethylation of halosilanes using appropriate organometallics, mainly Grignard reagents, see. R. N. Lewis, J. Am. Chem. Soc. 1947, 69, 717; M. F. Shostakovskii, D. A. Kochkin, I. A. Shikhiev, V. M. Vlassov, Zh. Obshch. Khim. 1955, 25, 622 (Chem. Abstr. 1956, 50, 3270b; L. H. Sommer, F. C. Whitmore, J. Am. Chem. Soc. 1946, 68, 485; V. F. Mironov, V. V. Nepomnina, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk 1959, 1231 (Chem. Abstr. 1960, 54, 1268e); G. V. Golodnikov, G. N. Koroleva, Zh. Obshch. Khim. 1961, 31, 3738 (Chem. Abstr 1962, 57, 8601d).
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Golodnikov, G.V.1
Koroleva, G.N.2
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11
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85152996455
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For the synthesis of various ethylsilanes by ethylation of halosilanes using appropriate organometallics, mainly Grignard reagents, see. R. N. Lewis, J. Am. Chem. Soc. 1947, 69, 717; M. F. Shostakovskii, D. A. Kochkin, I. A. Shikhiev, V. M. Vlassov, Zh. Obshch. Khim. 1955, 25, 622 (Chem. Abstr. 1956, 50, 3270b; L. H. Sommer, F. C. Whitmore, J. Am. Chem. Soc. 1946, 68, 485; V. F. Mironov, V. V. Nepomnina, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk 1959, 1231 (Chem. Abstr. 1960, 54, 1268e); G. V. Golodnikov, G. N. Koroleva, Zh. Obshch. Khim. 1961, 31, 3738 (Chem. Abstr 1962, 57, 8601d).
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H. Matsumato, S. Nagashima, T. Kato, Y Nagai, Angew. Chem. 1978, 90, 288, Angew. Chem. Int. Ed. Engl. 1978, 17, 279; R. Calas, J. Dunoguès, G. Deleris, N. Duffaut, J. Organomet. Chem. 1982, 225, 117.
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H. Matsumato, S. Nagashima, T. Kato, Y Nagai, Angew. Chem. 1978, 90, 288, Angew. Chem. Int. Ed. Engl. 1978, 17, 279; R. Calas, J. Dunoguès, G. Deleris, N. Duffaut, J. Organomet. Chem. 1982, 225, 117.
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E. Lukevics, Z. V. Belyakova, M. G. Pomorentseva, M. G. Voronkov, J. Organomet. Chem Libr. 1977, 5, 1.
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0004052155
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A. D Petrov, B. F. Mironov, V. A. Ponomarenko, E. A. Chernyshev, Synthesis of Organosilicon Monomers, Heywood & Co., Ltd., London, 1964.
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0004250674
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Elsevier, New York
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That is why the reaction of silicon, alkyl chloride and copper as catalyst is almost restricted to the production of chloro-(methyl)silanes: R. J. H. Voorhoeve, Organohalosilanes, Precursors 10 Silicones, Elsevier, New York, 1967; A. G. MacDiarmid, Organometallic Compounds of the Group IV Elements, M. Dekker, Inc., New York, 1972, vol. 2 ("The Bond to Halogenes and Halogenoids", part 1).
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13044254861
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M. Dekker, Inc., New York
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That is why the reaction of silicon, alkyl chloride and copper as catalyst is almost restricted to the production of chloro-(methyl)silanes: R. J. H. Voorhoeve, Organohalosilanes, Precursors 10 Silicones, Elsevier, New York, 1967; A. G. MacDiarmid, Organometallic Compounds of the Group IV Elements, M. Dekker, Inc., New York, 1972, vol. 2 ("The Bond to Halogenes and Halogenoids", part 1).
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V. Bazant, V. Chvalovský, J. Rauthouský, Organosilicon Compounds, Academic Press, New York, 1965, vol. 1.
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85153008081
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note
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2 might affect the carbon skeletons of silaheterocycles.
-
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23
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84959148896
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Neopentylsilenes - Laboratory Curiosities or useful Building Blocks for the Synthesis of Silaheterocycles
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(Eds.: N. Auner, J. Weis), VCH Verlag, Weinheim
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N. Auner, "Neopentylsilenes - Laboratory Curiosities or useful Building Blocks for the Synthesis of Silaheterocycles" in Organosilicon Chemistry - From Molecules to Materials (Eds.: N. Auner, J. Weis), VCH Verlag, Weinheim, 1994, pp. 103.
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Organosilicon Chemistry - From Molecules to Materials
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0004281110
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G. R. Pearson, Acc. Chem. Res. 1971, 4, 152; G. R. Pearson, Trans Am. Crystallogr. Assoc. 1978, 14, 89.
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0003872738
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