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Volumn 32, Issue 7, 1999, Pages 551-560

Ultrafast infrared studies of bond activation in organometallic complexes

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; CARBON; HYDROGEN; METAL COMPLEX; SILANE;

EID: 0032772354     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar970133y     Document Type: Article
Times cited : (40)

References (44)
  • 1
    • 0002677068 scopus 로고
    • Silicon-transition metal chemistry. I. Photochemical preparation of silyl-(transition metal) hydrides
    • Jetz, W.; Graham, W. A. G. Silicon-Transition Metal Chemistry. I. Photochemical Preparation of Silyl-(transition metal) Hydrides. Inorg. Chem. 1971, 10, 4-9.
    • (1971) Inorg. Chem. , vol.10 , pp. 4-9
    • Jetz, W.1    Graham, W.A.G.2
  • 2
    • 33845554568 scopus 로고
    • C-H activation in completely saturated hydrocarbons: Direct observation of M + R-H → M(R)(H)
    • Janowicz, A. H.; Bergman, R. G. C-H Activation in Completely Saturated Hydrocarbons: Direct Observation of M + R-H → M(R)(H). J. Am. Chem. Soc. 1982, 104, 352-355.
    • (1982) J. Am. Chem. Soc. , vol.104 , pp. 352-355
    • Janowicz, A.H.1    Bergman, R.G.2
  • 3
    • 0000058263 scopus 로고
    • Activation of alkanes with organotransition metal complexes
    • Bergman, R. G. Activation of Alkanes with Organotransition Metal Complexes. Science 1984, 223, 902-908.
    • (1984) Science , vol.223 , pp. 902-908
    • Bergman, R.G.1
  • 4
    • 0242524722 scopus 로고
    • Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex
    • Hoyano, J. K.; Graham, W. A. G. Oxidative Addition of the Carbon-Hydrogen Bonds of Neopentane and Cyclohexane to a Photochemically Generated Iridium(I) Complex. J. Am. Chem. Soc. 1982, 104, 3723-3725.
    • (1982) J. Am. Chem. Soc. , vol.104 , pp. 3723-3725
    • Hoyano, J.K.1    Graham, W.A.G.2
  • 5
    • 0000313458 scopus 로고
    • Gasphase rates of alkane C-H oxidative addition to a transient CpRh(CO) complex
    • Wasserman, E. P.; Moore, C. B.; Bergman, R. G. GasPhase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex. Science 1992, 255, 315-318.
    • (1992) Science , vol.255 , pp. 315-318
    • Wasserman, E.P.1    Moore, C.B.2    Bergman, R.G.3
  • 6
    • 3342945390 scopus 로고
    • 2-spectroscopic and temporal resolution of rhodium-krypton and rhodium-alkane complex intermediates
    • 2-Spectroscopic and Temporal Resolution of Rhodium-Krypton and Rhodium-Alkane Complex Intermediates. J. Am. Chem. Soc. 1994, 116, 9585-9589.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 9585-9589
    • Bengali, A.A.1    Schultz, R.H.2    Moore, C.B.3    Bergman, R.G.4
  • 8
    • 0037943837 scopus 로고
    • C-H activation by organometallics-the role of matrix isolation studies
    • Perutz, R. N.; Belt, S. T.; McCamley, A.; Whittlesey, M. K. C-H Activation by Organometallics-The Role of Matrix Isolation Studies. Pure Appl. Chem. 1990, 62, 1539-1545.
    • (1990) Pure Appl. Chem. , vol.62 , pp. 1539-1545
    • Perutz, R.N.1    Belt, S.T.2    McCamley, A.3    Whittlesey, M.K.4
  • 9
    • 0000717560 scopus 로고
    • Photochemistry of tris(dimethylpyrazolyl)-boratorhodium dicarbonyl and bis(dimethylpyrazolyl)-boratorhodium dicarbonyl complexes in low temperature media at 12-298 K-some insights into C-H activation processes
    • Bloyce, P. E.; Mascetti, J.; Rest, A. J. Photochemistry of tris(Dimethylpyrazolyl)-boratorhodium Dicarbonyl and bis(Dimethylpyrazolyl)-boratorhodium Dicarbonyl Complexes in Low Temperature Media at 12-298 K-Some insights into C-H Activation Processes. J. Organomet. Chem. 1993, 444, 223-233.
    • (1993) J. Organomet. Chem. , vol.444 , pp. 223-233
    • Bloyce, P.E.1    Mascetti, J.2    Rest, A.J.3
  • 11
    • 0029985231 scopus 로고    scopus 로고
    • 2 (M = Ir, Rh) in solution - The origin of the low quantum yields for C-H bond activation
    • 2 (M = Ir, Rh) in Solution - The Origin of the Low Quantum Yields for C-H Bond Activation. J. Am. Chem. Soc. 1996, 118, 2069-2072.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 2069-2072
    • Bromberg, S.E.1    Lian, T.Q.2    Bergman, R.G.3    Harris, C.B.4
  • 13
    • 0030010552 scopus 로고    scopus 로고
    • Femtosecond IR studies of alkane C-H bond activation by organometallic compounds-direct observation of reactive intermediates in room temperature solutions
    • Lian, T.; Bromberg, S. E.; Yang, H.; Proulx, G.; Bergman, R. G.; Harris, C. B. Femtosecond IR Studies of Alkane C-H Bond Activation by Organometallic Compounds-Direct Observation of Reactive Intermediates in Room Temperature Solutions. J. Am. Chem. Soc. 1996, 118, 3769-3770.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 3769-3770
    • Lian, T.1    Bromberg, S.E.2    Yang, H.3    Proulx, G.4    Bergman, R.G.5    Harris, C.B.6
  • 14
    • 0030729612 scopus 로고    scopus 로고
    • Femtosecond infrared studies of silane silicon-hydrogen bond activation
    • Yang, H.; Kotz, K. T.; Asplund, M. C.; Harris, C. B. Femtosecond Infrared Studies of Silane Silicon-Hydrogen Bond Activation. J. Am. Chem. Soc. 1997, 119, 9564-9565.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 9564-9565
    • Yang, H.1    Kotz, K.T.2    Asplund, M.C.3    Harris, C.B.4
  • 15
    • 0032494426 scopus 로고    scopus 로고
    • Reaction mechanism of silicon-hydrogen bond activation studied using femtosecond to nanosecond spectroscopy and Ab initio methods
    • Yang, H.; Asplund, M. C.; Kotz, K. T.; Wilkens, M. J.; Harris, C. B.; Frei, H. Reaction Mechanism of Silicon-Hydrogen Bond Activation Studied Using Femtosecond to Nanosecond Spectroscopy and Ab Initio Methods. J. Am. Chem. Soc. 1998, 120, 10154-10165.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 10154-10165
    • Yang, H.1    Asplund, M.C.2    Kotz, K.T.3    Wilkens, M.J.4    Harris, C.B.5    Frei, H.6
  • 16
    • 0030197336 scopus 로고    scopus 로고
    • Femtosecond infrared studies of the dissociation and dynamics of transition metal carbonyls in solution
    • Lian, T. Q.; Bromberg, S. E.; Asplund, M. C.; Yang, H.; Harris, C. B. Femtosecond Infrared Studies of the Dissociation and Dynamics of Transition Metal Carbonyls in Solution. J. Phys. Chem. 1996, 100, 11994-12001.
    • (1996) J. Phys. Chem. , vol.100 , pp. 11994-12001
    • Lian, T.Q.1    Bromberg, S.E.2    Asplund, M.C.3    Yang, H.4    Harris, C.B.5
  • 17
    • 0031560552 scopus 로고    scopus 로고
    • Time-resolved step-scan fourier transform infrared spectroscopy of triplet excited duroquinone in a zeolite
    • Sun, H.; Frei, H. Time-Resolved Step-Scan Fourier Transform Infrared Spectroscopy of Triplet Excited Duroquinone in a Zeolite. J. Phys. Chem. B 1997, 101, 205-209.
    • (1997) J. Phys. Chem. B , vol.101 , pp. 205-209
    • Sun, H.1    Frei, H.2
  • 18
    • 0000532386 scopus 로고
    • Organometallic CO substitution kinetics in liquid Xe by fast time-resolved IR spectroscopy
    • Weiller, B. H.; Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Organometallic CO Substitution Kinetics in Liquid Xe by Fast Time-Resolved IR Spectroscopy. J. Am. Chem. Soc. 1993, 115, 4326-4330.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 4326-4330
    • Weiller, B.H.1    Wasserman, E.P.2    Moore, C.B.3    Bergman, R.G.4
  • 19
    • 0001648035 scopus 로고
    • 5-cyclopentadienyl)iridium in hydrocarbon solutions - Kinetics and mechanism of C-H bond activation
    • 5-Cyclopentadienyl)Iridium in Hydrocarbon Solutions - Kinetics and Mechanism of C-H Bond Activation. Inorg. Chem. 1988, 27, 1121-1122.
    • (1988) Inorg. Chem. , vol.27 , pp. 1121-1122
    • Marx, D.1    Lees, A.J.2
  • 20
    • 36449006233 scopus 로고
    • 2 photoproduct reactions in hydrocarbon solutions
    • 2 Photoproduct Reactions in Hydrocarbon Solutions. J. Chem. Phys. 1994, 100, 4006-4009.
    • (1994) J. Chem. Phys. , vol.100 , pp. 4006-4009
    • Dougherty, T.P.1    Heilweil, E.J.2
  • 21
    • 33845283295 scopus 로고
    • Efficient and selective carbon-hydrogen activation by a tris/(pyrazolyl)-borate rhodium complex
    • Ghosh, C. K.; Graham, A. G. Efficient and Selective Carbon-Hydrogen Activation by a tris/(Pyrazolyl)-borate Rhodium Complex. J. Am. Chem. Soc. 1987, 109, 4726-4727.
    • (1987) J. Am. Chem. Soc. , vol.109 , pp. 4726-4727
    • Ghosh, C.K.1    Graham, A.G.2
  • 22
    • 0001186391 scopus 로고
    • A rhodium complex that combines benzene activation with ethylene insertion-subsequent carbonylation and ketone formation
    • Ghosh, C. K.; Graham, A. G. A Rhodium Complex that Combines Benzene Activation with Ethylene Insertion-Subsequent Carbonylation and Ketone Formation. J. Am. Chem. Soc. 1989, 111, 375-376.
    • (1989) J. Am. Chem. Soc. , vol.111 , pp. 375-376
    • Ghosh, C.K.1    Graham, A.G.2
  • 23
    • 0040268573 scopus 로고
    • Photochemical mechanisms in intermolecular C-H bond activation reactions of organometallic complexes
    • Lees, A. J.; Purwoko, A. A. Photochemical Mechanisms in Intermolecular C-H Bond Activation Reactions of Organometallic Complexes. Coord. Chem. Rev. 1994, 132, 155-160.
    • (1994) Coord. Chem. Rev. , vol.132 , pp. 155-160
    • Lees, A.J.1    Purwoko, A.A.2
  • 24
    • 0001254543 scopus 로고
    • 2 (Pz* = 3,5-dimethylpyrazolyl) in hydrocarbon solution
    • 2 (Pz* = 3,5-Dimethylpyrazolyl) in Hydrocarbon Solution. Inorg. Chem. 1995, 34, 424-425.
    • (1995) Inorg. Chem. , vol.34 , pp. 424-425
    • Purwoko, A.A.1    Lees, A.J.2
  • 27
    • 36449002840 scopus 로고
    • 6 (M = Cr, Mo, W)-effect of metal mass on vibrational cooling dynamics and non-boltzmann internal energy
    • 6 (M = Cr, Mo, W)-Effect of Metal Mass on Vibrational Cooling Dynamics and Non-Boltzmann Internal Energy. J. Chem. Phys. 1993, 99, 7595-7601.
    • (1993) J. Chem. Phys. , vol.99 , pp. 7595-7601
    • King, J.C.1    Zhang, J.Z.2    Schwartz, B.J.3    Harris, C.B.4
  • 28
    • 0024798071 scopus 로고
    • Ultrafast studies of transition-metal carbonyl reactions in the condensed phase-solvation of coordinatively unsaturated pentacarbonyls
    • Lee, M.; Harris, C. B. Ultrafast Studies of Transition-Metal Carbonyl Reactions in the Condensed Phase-Solvation of Coordinatively Unsaturated Pentacarbonyls. J. Am. Chem. Soc. 1989, 111, 8963-8965.
    • (1989) J. Am. Chem. Soc. , vol.111 , pp. 8963-8965
    • Lee, M.1    Harris, C.B.2
  • 29
    • 0042693907 scopus 로고
    • Direct measurement of photodissociation, geminate recombination, and vibrational cooling in iodine using picosecond raman spectroscopy
    • Xu, X. B.; Lingle, R.; Yu, S. C.; Chang, Y. J.; Hopkins, J. B. Direct Measurement of Photodissociation, Geminate Recombination, and Vibrational Cooling in Iodine Using Picosecond Raman Spectroscopy. J. Chem. Phys. 1990, 92, 2106-2107.
    • (1990) J. Chem. Phys. , vol.92 , pp. 2106-2107
    • Xu, X.B.1    Lingle, R.2    Yu, S.C.3    Chang, Y.J.4    Hopkins, J.B.5
  • 30
    • 0030668913 scopus 로고    scopus 로고
    • C-H activation at Pt-(II) to form stable Pt(IV) alkyl hydrides
    • Wick, D. D.; Goldberg, K. I. C-H Activation at Pt-(II) To Form Stable Pt(IV) Alkyl Hydrides. J. Am. Chem. Soc. 1997, 119, 10235-10236.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 10235-10236
    • Wick, D.D.1    Goldberg, K.I.2
  • 31
    • 0001269224 scopus 로고    scopus 로고
    • Prediction of the reactive intermediates in alkane activation by tris(pyrazolyl)-rhodium carbonyl
    • Zaric, S.; Hall, M. B. Prediction of the Reactive Intermediates in Alkane Activation by tris(pyrazolyl)-rhodium carbonyl. J. Phys. Chem. A 1998, 102, 1963-64.
    • (1998) J. Phys. Chem. A , vol.102 , pp. 1963-1964
    • Zaric, S.1    Hall, M.B.2
  • 32
    • 0000958669 scopus 로고
    • Chromium carbonyl photocatalyzed 1,4-hydrosilation of 1,3 dienes. A synthesis of allylsilanes
    • Wrighton, M. S.; Schroeder, M. A. Chromium Carbonyl Photocatalyzed 1,4-Hydrosilation of 1,3 Dienes. A Synthesis of Allylsilanes. J. Am. Chem. Soc. 1974, 96, 6235-6237.
    • (1974) J. Am. Chem. Soc. , vol.96 , pp. 6235-6237
    • Wrighton, M.S.1    Schroeder, M.A.2
  • 33
    • 0000857956 scopus 로고
    • 2 coordination of Si-H σ bonds to transition metals
    • 2 Coordination of Si-H σ Bonds to Transition Metals. Adv. Organomet. Chem. 1990, 30, 151-187.
    • (1990) Adv. Organomet. Chem. , vol.30 , pp. 151-187
    • Schubert, U.1
  • 35
    • 33947291468 scopus 로고
    • Silicon-transition metal chemistry. VI. Kinetics and mechanism of the replacement of triphenylsilane by triphenylphosphine in hydridotriphenylsilyl(π-cyclopentadienyl)dicarbonylmanganese
    • Hart-Davis, A. J.; Graham, W. A. G. Silicon-Transition Metal Chemistry. VI. Kinetics and Mechanism of the Replacement of Triphenylsilane by Triphenylphosphine in Hydridotriphenylsilyl(π-cyclopentadienyl)dicarbonylmanganese. J. Am. Chem. Soc. 1971, 93, 4388-4393.
    • (1971) J. Am. Chem. Soc. , vol.93 , pp. 4388-4393
    • Hart-Davis, A.J.1    Graham, W.A.G.2
  • 38
    • 0001103544 scopus 로고
    • 2-Ab initio molecular orbital study
    • 2-Ab Initio Molecular Orbital Study. J. Am. Chem. Soc. 1993, 115, 6883-6892.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 6883-6892
    • Koga, N.1    Morokuma, K.2
  • 39
    • 0000100168 scopus 로고
    • Ab initio molecular orbital study of the mechanism of H-H, C-H, N-H, O-H, and Si-H bond activation on transient cyclopentadienylcarbonylrhodium
    • Musaev, D. G.; Morokuma, K. Ab Initio Molecular Orbital Study of the Mechanism of H-H, C-H, N-H, O-H, and Si-H Bond Activation on Transient Cyclopentadienylcarbonylrhodium. J. Am. Chem. Soc. 1995, 117, 799-805.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 799-805
    • Musaev, D.G.1    Morokuma, K.2
  • 41
    • 0000322089 scopus 로고
    • Mechanisms for the reactions between methane and the neutral transition metal atoms from yttrium to palladium
    • Blomberg, M. R. A.; Siegbahn, P. E. M.; Svensson, M. Mechanisms for the Reactions between Methane and the Neutral Transition Metal Atoms from Yttrium to Palladium. J. Am. Chem. Soc. 1992, 114, 6095-6102.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 6095-6102
    • Blomberg, M.R.A.1    Siegbahn, P.E.M.2    Svensson, M.3
  • 42
    • 0000285440 scopus 로고
    • Different electronic structure requirements on precursors and transition states for the oxidative addition reaction with methane
    • Siegbahn, P. E. M.; Svensson, M. Different Electronic Structure Requirements on Precursors and Transition States for the Oxidative Addition Reaction with Methane. J. Am. Chem. Soc. 1994, 116, 10124-10128.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 10124-10128
    • Siegbahn, P.E.M.1    Svensson, M.2
  • 43
    • 0000365588 scopus 로고
    • Gas phase reactions of second-row transition metal atoms with small hydrocarbons-experiment and theory
    • Carroll, J. J.; Weisshaar, J. C.; Huag, K. L.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Svensson, M. Gas Phase Reactions of Second-Row Transition Metal Atoms with Small Hydrocarbons-Experiment and Theory. J. Phys. Chem. 1995, 99, 13955-13969.
    • (1995) J. Phys. Chem. , vol.99 , pp. 13955-13969
    • Carroll, J.J.1    Weisshaar, J.C.2    Huag, K.L.3    Blomberg, M.R.A.4    Siegbahn, P.E.M.5    Svensson, M.6
  • 44
    • 0029962350 scopus 로고    scopus 로고
    • 5)(CO) for M = cobalt, rhodium, and iridium
    • 5)(CO) for M = Cobalt, Rhodium, and Iridium. J. Am. Chem. Soc. 1996, 118, 1487-1496.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 1487-1496
    • Siegbahn, P.E.M.1


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