Totally regio- and stereoselective P-O-to-P-C rearrangement in the synthesis of chiral P-(o-hydroxyaryl)diazaphospholidine P-oxides

European Journal of Organic Chemistry

Volumn , Issue 5, 1999, Pages 1099-1105

  Legrand, Olivier ^a   Brunel, Jean Michel ^a   Buono, Gérard ^a  

^a AIX MARSEILLE UNIVERSITY   (France)

Author keywords

Asymmetric synthesis; Chiral synthons; P (o Hydroxyaryl)diazaphospholidine P oxides; Rearrangements

Indexed keywords

PHOSPHONIC ACID DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; CONFORMATIONAL TRANSITION; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 0032766219     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0690(199905)1999:5<1099::AID-EJOC1099>3.0.CO;2-R     Document Type: Article

References (37)

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33. 1 from the systematic absences. A total of 1635 reflections were collected at T = 298 K. The standards were measured after every 120 reflections. Among the first 200 pairs of reflections, the signs of the corresponding calculated differences established that the molecule had been described with the correct absolute configuration (S).
34. 1 from the systematic absences. A total of 1749 reflections were collected at T = 298 K. The standards were measured after every 120 reflections. Among the first 200 pairs of reflections, the signs of the corresponding calculated differences established that the molecule had been described with the correct absolute configuration (S).
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