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0009648095
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note
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11b states that for a protected carbomethoxy cyclohexadienediol the regioselectivity was low, and this was ascribed to a rotation of the carbomethoxy group out of conjugation with the double bond, thus changing the electronic distribution in the dienic system.
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38
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see also ref. 5b.
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(b) see also ref. 5b.
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39
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85005759612
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The osmylations of protected cyclohexadienediols reported in the literature deal with bulky protecting groups, such as acetonide, that shield completely one face of the molecule: T. Hudlicky, F. Rulin, T. Tsunoda, H. Luna, C. Andersen and J. D. Price, Isr. J. Chem., 1991, 31, 229.
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(b) see ref. 1b.
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47
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0030842941
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