Comparison of column chromatographic and precipitation methods for the purification of a macrocyclic polyether extractant

Separation Science and Technology

Volumn 34, Issue 15, 1999, Pages 2943-2956

  Dietz, Mark L ^a   Felinto, Claudia ^a   Rhoads, Susan ^a   Clapper, Maureen ^a,d   Finch, Jeffrey W ^b,e   Benjamin P, Hay ^c  

^a ARGONNE NATIONAL LABORATORY   (United States)

^b JEOL USA INC   (United States)

^c PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^d U S DEPARTMENT OF ENERGY   (United States)

^e PERKINELMER INC   (United States)

Author keywords

Column chromatography; Crown ether; Precipitation

Indexed keywords

COLUMN CHROMATOGRAPHY; EXTRACTION; NITRATES; PRECIPITATION (CHEMICAL); SILICA; STRONTIUM;

PERCHLORIC ACID;

CROWN ETHERS;

CROWN ETHER; MACROCYCLIC COMPOUND; PERCHLORIC ACID; POLYETHER; SILICON DIOXIDE; STRONTIUM;

COLUMN SEPARATION; CROWN ETHER; PRECIPITATION; PURIFICATION;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; COLUMN CHROMATOGRAPHY; COMPLEX FORMATION; EXTRACTION; INTERMETHOD COMPARISON; PRECIPITATION; PURIFICATION; STEREOISOMERISM;

EID: 0032750548     PISSN: 01496395     EISSN: None     Source Type: Journal    
DOI: 10.1081/SS-100100814     Document Type: Article

References (29)

1. W. W. Schulz and L. A. Bray, Sep. Sci. Technol., 22, 191 (1987).
2. J. T. Bell and L. H. Bell, "Separations Technology: The Key to Radioactive Waste Minimization," in Chemical Pretreatment of Nuclear Waste for Disposal (W. W. Schulz and E. P. Horwitz, Eds.), Plenum Press, New York, NY, 1995, p. 1.
3. D. J. Wood and J. D. Law, Sep. Sci. Technol., 32, 241 (1997).
4. E. P. Horwitz, M. L. Dietz, and D. E. Fisher, Solv. Extr. Ion Exch., 8, 199 (1990).
5. E. P. Horwitz, M. L. Dietz, and D. E. Fisher, Ibid., 8, 557 (1990).
6. E. P. Horwitz, M. L. Dietz, and D. E. Fisher, Ibid., 9, 1 (1991).
7. M. L. Dietz, E. P. Horwitz, and R. D. Rogers, Ibid., 13, 1 (1995).
8. E. P. Horwitz, M. L. Dietz, and D. E. Fisher, Anal. Chem., 63, 522 (1991).
9. E. P. Horwitz, R. Chiarizia, and M. L. Dietz, Solv. Extr. Ion Exch., 10, 313 (1992).
10. R. Chiarizia, E. P. Horwitz, and M. L. Dietz, Ibid., 10, 337 (1992).
11. C. J. Pedersen, J. Am. Chem. Soc., 89, 7017 (1967).
12. M. Hiraoka, Crown Compounds: Their Characteristics and Applications, Elsevier, New York, NY, 1982, Chapter 2.
13. M. J. Gula and R. A. Bartsch, "Process for the Preparation of cis-syn-cis-4,4′(5′)-[Di-t-butyldicyclohexano]-18-crown-6," US Patent 5,478,953 (issued December 26, 1995).
14. B. P. Hay and M. D. Paulsen, The Effect of Adding Alkyl Groups to Dicyclohexano-18-crown-6 on the Complexation and Solvent Extraction of Strontium, Report to the Efficient Separations and Processing Integrated Program, United States Department of Energy, November 1996.
15. I. J. Burden, A. C. Coxon, J. F. Stoddart, and C. M. Wheatley, J. Chem. Soc., Perkin I, p. 220 (1977).
16. B. P. Hay, "A Molecular Mechanics Method for Predicting the Influence of Ligand Structure on Metal Ion Binding Affinity," in Metal Ion Separation and Preconcentration: Progress and Opportunities (ACS Symp. Ser., Vol. 716, A. H. Bond, M. L. Dietz, and R. D. Rogers, Eds.), American Chemical Society, Washington, DC, 1999, p. 102.
17. R. N. Greene, Tetrahedron Lett., p. 1793 (1972).
18. F. L. Cook, T. C. Caruso, M. P. Byrne, C. W. Bowers, D. H. Speck, and C. L. Liotta, Ibid., p. 4029 (1974).
19. G. W. Gokel, D. J. Cram, C. L. Liotta, H. P. Harris, and F. L. Cook, J. Org. Chem., 39, 2445 (1974).
20. T. Okada and T. Usui, J. Chromatogr. A, 676, 355 (1994).
21. T. Okada and T. Usui, J. Chem. Soc., Faraday Trans., 92, 4977 (1996).
22. S. Aoki, M. Shiga, M. Tazaki, H. Nakamura, M. Takagi, and K. Ueno, Chem. Lett., p. 1583 (1981).
23. T. Okada, Anal. Chem., 66, 2163 (1994).
24. R. M. Izatt, B. L. Haymore, J. S. Bradshaw, and J. J. Christensen, Inorg. Chem., 14, 3132 (1975).
25. V. Guyon, P. D. Landre, A. Guy, J. Foos, and M. Lemaire, Chem. Lett., p. 723 (1992).
26. V. V. Yakshin, N. G. Zhukova, N. A. Tsarenko, A. T. Fedorova, and B. N. Laskorin, Dokl. Akad. Nauk SSSR, 273, 160 (1983).
27. B. N. Laskorin, V. V. Yakshin, and A. T. Fedorova, Zh. Anal. Khim., 39, 1115 (1984).
28. L. Trézl, P. Bakó, L. Fenichel, and I. Rusznák, J. Chromatogr., 269, 40 (1983).
29. B. P. Hay, M. D. Paulsen, M. L. Dietz, E. P. Horwitz, J. W. Finch, and R. D. Rogers, Manuscript in Preparation (1999).