Novel synthesis of macrocyclic amine-thiophenolate ligands: X-ray crystal structure of a Ni4 complex of an N8S4 ligand

European Journal of Inorganic Chemistry

Volumn , Issue 12, 1999, Pages 2167-2172

  Kersting, Berthold ^a   Steinfeld, Gunther ^a   Fritz, Thorsten ^a   Hausmann, Julia ^a  

^a UNIVERSITY OF FREIBURG   (Germany)

Author keywords

Amine Thiolate Donors; Condensation reactions; Macrocyclic compounds; Nickel; Polynuclear Complexes

Indexed keywords

CHELATION; CONDENSATION; CONDENSATION REACTIONS; CRYSTAL STRUCTURE; LIGANDS; METAL COMPLEXES; SODIUM BOROHYDRIDE; SYNTHESIS (CHEMICAL); TRANSITION METALS;

AIR STABLE; AMINE-THIOLATE DONOR; HIGH-DILUTION CONDITIONS; MACROCYCLIC COMPOUNDS; MACROCYCLICS; NOVEL ROUTE; POLYNUCLEAR COMPLEXES; TETRANUCLEAR COMPLEXES; THIOLATES; X RAY CRYSTAL STRUCTURES;

NICKEL COMPOUNDS;

AMINE; MACROCYCLIC COMPOUND; PHENOL DERIVATIVE;

ANALYTIC METHOD; ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; DRUG SYNTHESIS; LIGAND BINDING; PHASE TRANSITION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0032743941     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1099-0682(199912)1999:12<2167::aid-ejic2167>3.0.co;2-f     Document Type: Article

References (48)

1. N. H. Pilkington, R. Robson, Aust. J. Chem. 1970, 23, 2225-2236.
2. B. F. Hoskins, N. J. McLeod, H. A. Schaap, Aust. J. Chem. 1976, 29, 515-521.
3. [3a] H. Okawa, S. Kida, Bull. Chem. Soc. Jpn. 1972, 45, 1759-1764.
4. [3b] M. Tadokoro, H. Okawa, N. Matsumoto, M. Koikawa, S. Kida, J. Chem. Soc., Dalton Trans. 1991, 1657-1663.
5. [3c] H. Okawa, J. Nishio, M. Ohba, M. Tadokoro, N. Matsumoto, M. Koikawa, S. Kida, D. E. Fenton, Inorg. Chem. 1993, 32, 2949-2957.
6. [4a] R. R. Gagne, C. A. Koval, T. J. Smith, J. Am. Chem. Soc. 1977, 99, 8367-8368.
7. [4b] R. R. Gagne, C. A. Koval, T. J. Smith, M. C. Cimolino, J. Am. Chem. Soc. 1979, 101, 4571-4580.
8. [4c] C. L. Spiro, S. L. Lambert, T. J. Smith, E. N. Duesler, R. R. Gagne, D. N. Hendrickson, Inorg. Chem. 1981, 20, 1229-1237.
9. [5a] S. K. Mandal, K. Nag, J. Chem. Soc., Dalton Trans. 1983, 2429-2434.
10. [5b] S. K. Mandal, K. Nag, J. Org. Chem. 1986, 51, 3900-3902.
11. [5c] R. Das, K. Nag. Inorg. Chem. 1991, 30, 2831-2833.
12. [6a] S. L. Lambert, D. N. Hendrickson, Inorg. Chem. 1979, 18, 2683-2686.
13. [6b] R. C. Long, D. N. Hendrickson, J. Am. Chem. Soc. 1983, 705, 1513-1521.
14. [7a] C. Fraser, L. Johnston, A. L. Rheingold, B. S. Haggerty, G. K. Williams, J. Whelan, B. Bosnich, Inorg. Chem. 1992, 31, 1835-1844.
15. [7b] B. Bosnich, Inorg. Chem. 1999, 38, 2554-2562.
16. [8a] M. Bell, A. J. Edwards, B. F. Hoskins, E. H. Kachab, R. Robson, J. Chem. Soc., Chem. Commun. 1987, 1852-1854.
17. [8b] M. Bell, A. J. Edwards, B. F. Hoskins, E. H. Kachab, R. Robson, J. Am. Chem. Soc. 1989, 111, 3603-3610.
18. [8c] B. F. Hoskins, R. Robson, P. Smith, J. Chem. Soc., Chem. Commun. 1990, 488-489.
19. [8d] M. J. Grannas, B. F. Hoskins, R. Robson, J. Chem. Soc., Chem. Commun. 1990, 1644-1646.
20. [8e] A. J. Edwards, B. F. Hoskins, E. H. Kachab, A. Markiewicz, K. S. Murray, R. Robson, Inorg. Chem. 1992, 31, 3585-3591.
21. [9a] V. McKee, S. S. Tandon, J. Chem. Soc., Chem. Commun. 1988, 385-387.
22. [9b] V. McKee, S. S. Tandon, Inorg. Chem. 1989, 28, 2901-2902.
23. [9c] S. S. Tandon, L. K. Thompson, J. N. Bridson, J. Chem. Soc., Chem. Commun. 1992, 911-913.
24. [9d] S. S. Tandon, L. K. Thompson, J. N. Bridson, C. Benelli, Inorg. Chem. 1995, 34, 5507-5515.
25. [10a] K. K. Nanda, K. Venkatsubramanian, D. Majumbar, K. Nag, Inorg. Chem. 1994, 33, 1581-1582.
26. [10b] K. K. Nanda, S. Mohanta, U. Flörke, S. K. Dutta, K. Nag, J. Chem. Soc., Dalton Trans. 1995, 3831-3836.
27. [10c] S. Mohanta, K. K. Nanda, R. Werner, W. Haase, A. K. Mukherjee, S. K. Dutta, K. Nag., Inorg. Chem. 1997, 36, 4656-4664.
28. [11a] A. J. Atkins, A. J. Blake, M. Schröder, J. Chem. Soc., Chem. Commun. 1993, 1662-1665.
29. [11b] A. J. Atkins, D. Black, A. J. Blake, A. Marin-Becerra, S. Parsons, L. Ruiz-Ramirez, M. Schröder, Chem. Commun. 1996, 457-464.
30. [11c] N. D. J. Branscombe, A. J. Blake, A. Marin-Becerra, W.-S. Li, S. Parsons, L. Ruiz-Ramirez, M. Schröder, Chem. Commun. 1996, 2573-2574.
31. [12a] S. Brooker, P. D. Croucher, J. Chem. Soc., Chem. Commun. 1995, 1493-1494.
32. [12b] S. Brooker, P. D. Croucher, J. Chem. Soc., Chem. Commun. 1995, 2075-2076.
33. [12c] S. Brooker, P. D. Croucher, F. M. Roxburgh, J. Chem. Soc., Dalton Trans. 1996, 3031-3037.
34. [12d] S. Brooker, P. D. Croucher, Chem. Commun. 1997, 459-460.
35. [12e] S. Brooker, P. D. Croucher, T. C. Davidson, G. S. Dunbar, A. J. McQuillan, G. B. Jameson, Chem. Commun. 1998, 2131-2132.
36. P. E Kruger, V. McKee, Chem. Commun. 1997, 1341-1342.
37. For the preparation of sulfur derivatives of 4-tert-butyl-calixarenes, see: [14a] C. G. Gibbs, C. D. Gutsche, J. Am. Chem. Soc. 1993, 115, 5338-5339.
38. [14b] X. Delaigue, M. W. Hosseini, N. Kyritsakas, A. De Cian, J. Fischer, J. Chem. Soc., Chem. Commun. 1995, 609-610.
39. T. Yamamura, M. Tadokoro, M. Hamaguchi, R. Kuroda, Chem. Lett. 1989, 1481-1484.
40. B. Kersting. Z. Naturforsch., 1998, 53b, 1379-1385.
41. [17a] B. Kersting, D. Siebert, Inorg. Chem. 1998, 37, 3820-3828.
42. [17b] B. Kersting, D. Siebert, Eur. J. Inorg. Chem. 1999, 189-193.
43. [17c] B. Kersting, D. Siebert, D. Volkmer, M. J. Kolm, C. Janiak, Inorg. Chem. 1999, 38, 3871-3882.
44. B. Kersting, G. Steinfeld, J. Hausmann, Eur. J. Inorg. Chem. 1999, 179-187.
45. B. Kersting, Eur. J. Inorg. Chem. in press.
46. B. Kersting, Eur. J. Inorg. Chem. 1998, 1071-77.
47. G. M. Sheldrick, SHELXS-86, University of Göttingen, Germany, 1990; G. M. Sheldrick, SHELXL-93, University of Göttingen, Germany, 1993.
48. G. M. Sheldrick, SHELXS-86, University of Göttingen, Germany, 1990; G. M. Sheldrick, SHELXL-93, University of Göttingen, Germany, 1993.