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note
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The data in Table 1 allow the relative acidities of the 2-propyldiazonium ion and the cyclopropyldiazonium ion to be compared. The reaction of the cyclopropyldiazonium ion with 2-diazopropane to give the 2-propyldiazonium ion and diazocyclopropane is calculated to be exothermic by -2.4 kcal/mol.
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24
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33847504423
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Frisch, M. J.; Trucks; G. W.; Schlegel, H. B.; Gill, P. M. W.; Johnson, B. G.; Robb; M. A.; Cheeseman, J. R.; Keith, T.; Petersson, G. A.; Montgomery, J. A.; Raghavachari, K.; Al-Laham, M. A.; Zakrzewski, V. G.; Ortis, J. V.; Foresman, J. B.; Cioslowski, J.; Sefanov, B. B.; Nanayakkara, A.; Challacombe, M.; Peng, C. Y.; Ayala, P. Y.; Chen, W.; Wong, M. W.; Andres, J. L.; Replogle, E. S.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Binkley, J. S.; Defrees, D. J.; Baker, J.; Stewart, J. P.; Head-Gordon, M.; Gonzalez, C.; Pople, J. A. Gaussian 95, Development Version (Rev. D); Gaussian, Inc.: Pittsburgh, PA, 1995.
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Frisch, M.J.1
Trucks, G.W.2
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Cheeseman, J.R.7
Keith, T.8
Petersson, G.A.9
Montgomery, J.A.10
Raghavachari, K.11
Al-Laham, M.A.12
Zakrzewski, V.G.13
Ortis, J.V.14
Foresman, J.B.15
Cioslowski, J.16
Sefanov, B.B.17
Nanayakkara, A.18
Challacombe, M.19
Peng, C.Y.20
Ayala, P.Y.21
Chen, W.22
Wong, M.W.23
Andres, J.L.24
Replogle, E.S.25
Gomperts, R.26
Martin, R.L.27
Fox, D.J.28
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Defrees, D.J.30
Baker, J.31
Stewart, J.P.32
Head-Gordon, M.33
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