Mechanism of the OH-initiated oxidation of methacrolein

Geophysical Research Letters

Volumn 26, Issue 14, 1999, Pages 2191-2194

  Orlando, John J ^a   Tyndall, Geoffrey S ^b   Paulson, Suzanne E ^a  

^a NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; CARBON MONOXIDE; CHEMICAL BONDS; FORMALDEHYDE; FOURIER TRANSFORM INFRARED SPECTROSCOPY; NITRATES; OLEFINS; OXIDATION; REACTION KINETICS; ABSTRACTING; ATOMS; CARBON; ENVIRONMENTAL CHAMBERS;

ISOPRENE; METHACROLEIN; ABSTRACTION CHANNELS; DOUBLE BONDS; END-PRODUCTS; FTIR SPECTROSCOPY; HYDROGEN ATOMS; HYDROXYACETONE;

AIR POLLUTION; OXIDATION;

BIOGENIC EMISSION; HYDROXYL RADICAL; ISOPRENE; OZONE; PHOTOCHEMISTRY;

EID: 0032696060     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/1999GL900453     Document Type: Article

References (24)

1. Chameides, W. L., R. L. Lindsay, J. Richardson, and C. S. Kiang, The role of biogenic hydrocarbons in urban photochemical smog: Atlanta as a case study. Science, 241, 1473-1475, 1988.
2. 2 + NO reaction using chemical ionization mass spectrometry, J. Phys. Chem. A, 101, 8002-8007, 1997.
3. DeMore, W. B., S. P. Sander, D. M. Golden, R. F. Hampson, M. J. Kurylo, C. J. Howard, A. R. Ravishankara, C. E. Kolb, and M. J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling; Evaluation 12, NASA JPL Publication 97-4, 1997.
4. 2) radical, J. Phys. Chem. A, 101, 4879-4886, 1997.
5. Fehsenfeld, F. C., J. G. Calvert, R. Fall, P. D. Goldan, A. B. Guenther, C. N. Hewitt, B. Lamb, S. Liu, M. Trainer, H. H. Westberg, and P. Zimmerman, Emissions of volatile organic compounds from the vegetation and the implications for atmospheric chemistry. Global Biogeochem. Cycles, 6,389-430, 1992.
6. 2 mixtures, J. Phys. Chem., 91, 1922-1930, 1987.
7. Gierczak, T., J. B. Burkholder, R. K. Talukdar, A. Mellouki, S. B. Barone, and A. R. Ravishankara, Atmospheric fate of methyl vinyl ketone and methacrolein, J. Photochem. Photobiol. A: Chemistry 110, 1-10, 1997.
8. 2, Int. J. Chem. Kinet, 25, 921-929, 1993.
9. Jenkin, M. E., R. A. Cox, M. Emrich, G. K. Moortgat, Mechanisms of the Cl-atom-initiated oxidation of acetone and hydroxyacetone in air, J. Chem. Soc. Faraday Trans,. 89, 2983-2991, 1993.
10. Orlando, J. J., G. S. Tyndall, J.-M. Fracheboud, E. G. Estupinan, S. Haberkorn, and A. Zimmer, The rate and mechanism of the gas phase oxidation of hydroxyacetone, Atmos. Environ., 33, 1621-1629 (1999).
11. Park, J.-Y., M. C. Heaven, and D. Gutman, Kinetics and mechanism of the reaction of vinyl radicals with molecular oxygen, Chem. Phys. Lett., 104, 469-474, 1984.
12. Paulson, S. E. and Seinfeld J. H., Development and evaluation of a photooxidation mechanism for isoprene, J. Geophys. Res., 97, 20703-20715, 1992a.
13. Paulson, S. E., R. C. Flagan, J. H. Seinfeld, Atmospheric photooxidation of isoprene part I: The hydroxyl radical and ground state atomic oxygen reactions, Int. J. Chem. Kinet., 24, 79-101, 1992b.
14. Peeters, J. W. Boullant, J. Von Hoeymissen, Site-specific rate constants for OH addition to alkenes and dienes, in Proc. of Eurotrac Symposium '94, ed. P. M. Borrell, p. 110-114, 1994.
15. Shetter, R. E., J. A. Davidson, C. A. Cantrell, and J. G. Calvert, Temperature variable long path cell for absorption measurements, Rev. Sci. Instrum., 58, 1427-1428, 1987.
16. Singh, H. B., and P. B. Zimmerman, Atmospheric distribution and sources of nonmethane hydrocarbons, Gaseous Pollutants: Characterization and Cycling, edited by J. O. Nriagu, 177-235, John Wiley, New York, 1992.
17. Slagle, I. R., J.-Y. Park, M. C. Heaven, D. Gutman, Kinetics of polyatomic free radicals produced by laser photolysis. 3. Reaction of vinyl radicals with molecular oxygen, J. Am. Chem. Soc., 106, 4356-4361, 1984.
18. Staffelbach, T. A., J. J. Orlando, G. S. Tyndall, and J. G. Calvert, The UV-visible absorption spectrum and photolysis quantum yields of methylglyoxal, J. Geophys. Res., 100, 14, 189-14,198, 1995.
19. Trainer, M., E. Y. Hsie, S. A. McKeen, R. Tallamraju, D. D. Parrish, F. C. Fehsenfeld, and S. C. Liu, Impact of natural hydrocarbons on hydroxyl and peroxy radicals at a remote site, J. Geophys. Res., 92, 11, 879-11,894, 1987a.
20. Trainer, M., E. J. Williams, D. D. Parrish, M. P. Buhr, E. J. Allwine, H. H. Westberg, F. C. Fehsenfeld, and S. C. Liu, Models and observations of the impact of natural hydrocarbons on rural ozone, Nature, 329, 705-707, 1987b.
21. x, Int. J. Chem. Kinet., 21, 1141-1152, 1989.
22. x, Int. J. Chem. Kinet., 22, 591-602, 1990a.
23. X, Int. J. Chem. Kinet., 22, 1221-1236, 1990b.
24. Tyndall, G. S., T. A. Staffelbach, J. J. Orlando, and J. G. Calvert, Rate coefficients for the reactions of OH with methylglyoxal and acetaldehyde, Int. J. Chem. Kin., 27, 1009-1020, 1995.