Transference numbers of alkali chlorides and characterization of salt bridges for use in methanol+water mixed solvents

Journal of Chemical and Engineering Data

Volumn 44, Issue 5, 1999, Pages 1002-1008

  Basili, Alessandro ^a   Mussini, Patrizia R ^a   Mussini, Torquato ^a   Rondinini, Sandra ^a   Sala, Barbara ^a   Vertova, Alberto ^a  

^a UNIVERSITY OF MILAN   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CONCENTRATION (PROCESS); ELECTROCHEMICAL ELECTRODES; HYDRATION; SODIUM CHLORIDE; SOLVENTS;

ELECTROMOTIVE FORCE MEASUREMENTS; TRANSFERENCE CELLS;

SOLUTIONS;

EID: 0032685002     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je9900979     Document Type: Article

References (48)

1. Åkerlöf, G. Dielectric Constants of Some Organic Solvent-Water Mixtures at Various Temperatures. J. Am. Chem. Soc. 1932, 54, 4125-4139.
2. Amis, E. S. The Polar Properties of Solvent and the Conductance of Electrolytes at Infinite Dilution. J. Phys. Chem. 1966, 60, 428-430.
3. 1-x|NaCl (m)|AgCl|Ag in (Methanol + Water) Solvent Mixtures. J. Chem. Thermodyn. 1996, 28, 923-933.
4. 1-x|MeCl (m)|AgCl|Ag (with Me = K, Rb) in (Methanol + Water) Solvent Mixtures. Ber. Bunsen-Ges.Phys. Chem. 1997, 101, 842-846.
5. Bates, R. G. Determination of pH-Theory and Practice, 2nd ed.; Wiley: New York, 1973; pp 311-313.
6. Bockris, J. O'M.; Reddy, A. K. N. Modern Electrochemistry; Plenum Press: New York, 1970; Vol. 1, pp 406-410.
7. Buizza, C.; Mussini, P. R.; Mussini, T.; Rondinini, S. Characterization of Aqueous Rubidium Chloride as an Equitransferent Ultraconcentrated Salt Bridge. J. Appl. Electrochem. 1996, 26, 337-341.
8. Butler, J. P.; Schiff, H. I.; Gordon, A. R. Equivalent and Ionic Conductances for Sodium and Potassium Chlorides in Anhydrous Methanol at 25 °C. J. Chem. Phys. 1961, 19, 752-754.
9. Ceccattini, P. D.; Mussini, P. R.; Mussini, T. Thermodynamics of NaCl in Aqueous Ethylene Glycol, Acetonitrile, and 1,4-Dioxane Mixtures from Emf Measurements at 25 °C. J. Solution Chem. 1997, 26, 1169-1186.
10. Ceccattini, P. D.; Mussini, P. R.; Mussini, T. Transference Numbers for NaCl in Aqueous Mixtures of Organic Solvents of Moderate to Low Permittivities. J. Solution Chem. 1998, 27, 1-16.
11. Covington, A. K. In Ion Selective Electrodes; Durst, R. A. Ed.; NBS Special Publication 314; National Bureau of Standards: Washington, DC, 1969; p 107 and literature cited therein.
12. Davies, J. A.; Kay, R. L.; Gordon, A. R. Transference Numbers for Sodium and Potassium Chlorides in Anhydrous Methanol at 25 °C. J. Chem. Phys. 1951, 19, 749-751.
13. Faverio, C. L.; Mussini, P. R.; Mussini, T. Characterization of Lithium Sulfate as an Unsymmetrical-Valence Salt Bridge for the Minimization of Liquid Junction Potentials in Aqueous -Organic Solvent Mixtures. Anal. Chem. 1998, 70, 2589-2595.
14. 2(Pt)|HCl|AgCl|Ag. J. Chem. Soc. 1957, 2581-2589.
15. Guggenheim, E. A. Cells with Liquid Junctions. J. Am. Chem. Soc. 1930, 52, 1315-1337; Studies of Cells with Liquid Junctions. II: Thermodynamic Significance and Relationship to Activity Coefficients. J. Phys. Chem. 1930, 34, 1758-1766.
16. Guggenheim, E. A. Cells with Liquid Junctions. J. Am. Chem. Soc. 1930, 52, 1315-1337; Studies of Cells with Liquid Junctions. II: Thermodynamic Significance and Relationship to Activity Coefficients. J. Phys. Chem. 1930, 34, 1758-1766.
17. Harned, H. S. A Rule for Calculation of the Activity Coefficients of Salts in Organic Solvent-Water Mixtures. J. Phys. Chem. 1962, 66, 589-591.
18. Harned, H. S.; Thomas, H. C. The Molal Electrode Potential of the Silver-Silver Chloride Electrode in Methyl Alcohol-Water Mixtures. J. Am. Chem. Soc. 1935, 57, 1666-1668.
19. Harned, H. S.; Owen, B. B. The Physical Chemistry of Electrolytic Solutions, 3rd ed.; Reinhold: New York, 1958; p 706.
20. Ives, D. J. G.; Janz, G. J. Reference Electrodes-Theory and Practice; Academic Press: New York, 1961a; pp 54-56.
21. Ives, D. J. G.; Janz, G. J. Reference Electrodes-Theory and Practice; Academic Press: New York, 1961b; pp 203-207.
22. Janz, G. J.; Tomkins, R. P. T. Nonaqueous Electrolytes Handbook; Academic Press: New York, 1972a; Vol. 1, p 318.
23. Janz, G. J.; Tomkins, R. P. T. Nonaqueous Electrolytes Handbook; Academic Press: New York, 1972b; Vol. 1, p 327.
24. Jervis, R. E.; Muir, D. R.; Butler, J. P.; Gordon, A. R. The Conductance at 25 °C of Lithium Chloride, Sodium and Potassium Chlorides and Potassium Iodide in Methanol, and of Lithium Chloride, Sodium Chloride and Potassium Iodide in Water. J. Am. Chem. Soc. 1953, 75, 2855-2858.
25. Longhi, P.; D'Andrea, F.; Mussini, P. R.; Mussini, T.; Rondinini, S. Averification of the Approximate Equitransference of the Aqueous Potassium Chloride Salt Bridge at High Concentrations. Anal. Chem. 1990, 62, 1019-1021.
26. Longsworth, L. G.; Maclnnes, D. A. Ion Conductances in Water-Methanol Mixtures. J. Phys. Chem. 1939, 43, 239-246.
27. Mussini, T. Concentrated "Equitransferent" Salt Bridge to Minimize Liquid Junction Potentials-A Revision. J. Chem. Educ. 1988, 65, 242-243.
28. Mussini, T.; Pagella, A. Standard Potentials of the Calcium Amalgam Electrode at Various Temperatures, with Related Thermodynamic Functions. J. Chem. Eng. Data 1971, 16, 49-52.
29. Mussini, P. R.; Mussini, T. Recent advances in the electromotive force method for determining transferase numbers of electrolytes and characterizing new salt bridges. J. Appl. Electrochem. 1998, 28 1305-1311.
30. Mussini, T.; Covington, A. K.; Longhi, P.; Rondinini, S. Criteria for Standardization of pH Measurements in Organic Solvents and Water + Organic Solvent Mixtures of Moderate to High Permit-tivities. Pure Appl. Chem. 1985, 57, 865-876.
31. Mussini, P. R.; Longhi, P.; Mussini, T.; Rondinini, S. Ion and Solvent Transfers at Homoionic Junctions between Concentrated Electrolyte Solutions. J. Appl. Electrochem. 1990a, 20, 645-650.
32. Mussini, P. R.; D'Andrea, F.; Galli, A.; Longhi, P.; Rondinini, S. Characterization and Use of Aqueous Cesium Chloride as an Ultra-Concentrated Salt Bridge. J. Appl. Electrochem. 1990b, 20, 651-656.
33. 4I, and their Characterization as Ultra-Concentrated Salt Bridges for the Minimization of Liquid Junction Potentials. Ber. Bunsen-Ges. Phys. Chem. 1993, 97, 1034-1037.
34. Mussini, P. R.; Mussini, T.; Perelli, A.; Rondinini, S. Transference Numbers of Concentrated Electrolytes and Characterization of Salt Bridges in the Ethanol + Water Solvent Mixtures. J. Chem. Eng. Data 1995, 40, 862-868.
35. 2O and Aqueous-Organic Solvent Mixtures: New Accessions and Assessments. Pure Appl. Chem. 1997, 69, 1007-1014.
36. Oiwa, I. T. The Activity Coefficients of Hydrochloric Acid in Methanol-Water Mixtures. J. Phys. Chem. 1956, 60, 754-759.
37. Robinson, R. A.; Stokes, R. H. Electrolyte Solutions, 2nd rev. ed.; Butterworth: London, 1965a; pp 155-157.
38. Robinson, R. A.; Stokes, R. H. Electrolyte Solutions, 2nd rev. ed.; Butterworth: London, 1965b; pp 463-465, 554.
39. Rondinini, S.; Ardizzone, S.; Longhi, P.; Mussini, T. Normalisation of Standard Electrode Potential Series and Evaluation of Liquid Junction Potentials between Different Solvents. J. Electroanal. Chem. Interface Electrochem. 1978, 89, 59-67.
40. Rondinini, S.; Mussini, P. R.; Mussini, T. Reference Value Standards and Primary Standards for pH Measurements in Organic Solvents and Water + Organic Solvent Mixtures of Moderate to High Permittivities. Pure Appl. Chem. 1987a, 59, 1549-1560.
41. Rondinini, S.; Longhi, P.; Mussini, P. R.; Mussini, T. Auroprotolysis Constants in Nonaqueous Solvents and Water + Organic Solvent Mixtures. Pure Appl. Chem. 1987b, 59, 1693-1702.
42. Sala, B. Thesis, cod. 482 099, University of Milan, 1999.
43. Schiff, H. I.; Gordon, A. R. The Conductance of Sodium and Potassium Chlorides in 50-Mole percent Methanol-Water Mixtures. J. Chem. Phys. 1948, 16, 336-339.
44. Shedlovsky, T.; Kay, R. L. The Ionization Constant of Acetic Acid in Water-Methanol Mixtures at 25 °C from Conductance Measurements. J. Phys. Chem. 1956, 60, 151-155.
45. Shemilt, L. W.; Davies, J. A.; Gordon, A. R. The Transference Numbers of Sodium and Potassium Chlorides in 50 Mole percent Methanol-Water Mixtures. J. Chem. Phys. 1948, 16, 340-343.
46. Spiro, M. In Physical Methods of Chemistry, Vol. I, Part IIA, Electrochemical Methods: Determination of Transference Numbers; Weissberger, A., Rossiter, B. W., Eds.; Wiley-Interscience: New York, 1971; pp 284-285.
47. Spiro, M. Conductance and Transference Determinations. In Physical Methods of Chemistry, Vol. 2, Electrochemical Methods, Rossiter, B. W., Hamilton, J. F., Eds.; Wiley-Interscience: New York, 1986; Chapter 8 and literature cited therein.
48. Stokes, R. H. The Variation of Transference Numbers with Concentration. J. Am. Chem. Soc. 1954, 76, 1988-1990.