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Volumn 103, Issue 28, 1999, Pages 5832-5840

Steady-state voltammetry with stationary disk millielectrodes in magnetic fields: Nonlinear dependence of the mass-transfer limited current on the electron balance of the faradaic process

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTER SIMULATION; CURRENT VOLTAGE CHARACTERISTICS; DIFFUSION IN SOLIDS; FARADAY EFFECT; HYDRODYNAMICS; MASS TRANSFER; MATHEMATICAL MODELS;

EID: 0032662891     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9903920     Document Type: Article
Times cited : (76)

References (48)
  • 11
    • 33847511107 scopus 로고    scopus 로고
    • Chapter 4
    • (b) Chapter 4,
  • 12
    • 33847521799 scopus 로고    scopus 로고
    • Chapter 8
    • (c) Chapter 8,
  • 20
    • 0007341166 scopus 로고    scopus 로고
    • 23 for which similar expressions are known. For an interesting recent exchange of views on the application of power laws, see: (a) Tsonis, A. A. Science 1998, 279, 1614.
    • (1998) Science , vol.279 , pp. 1614
    • Tsonis, A.A.1
  • 25
    • 0344357985 scopus 로고    scopus 로고
    • note
    • 15 A higher centripetal acceleration leads to higher vorticity, i.e., to higher circulation velocities and therefore more vigorous stirring.
  • 35
    • 0345652452 scopus 로고    scopus 로고
    • note
    • 1/2| (see Table 1).
  • 36
    • 0345220623 scopus 로고    scopus 로고
    • note
    • B ratio in a way that also includes effects from electron-transfer coupling of diffusional pathways. By that method, the value of f is calculated equal to 0.50.
  • 43
    • 0345220620 scopus 로고    scopus 로고
    • note
    • 5
  • 44
    • 0345220619 scopus 로고    scopus 로고
    • note
    • The limiting current data used for the calculation of the "constant" of eqs 2 and 3 came both from this report and from ref 5.
  • 45
    • 0344357983 scopus 로고    scopus 로고
    • note
    • 2 Nevertheless, the simulation results suggest that calculating an average uniform diffusion-layer thickness via eqs 15, 18, and 19 is an adequate approximation.
  • 46
    • 0345220617 scopus 로고    scopus 로고
    • note
    • Compare, for example, concentration profiles shown in refs 18 and 30.
  • 47
    • 0345220616 scopus 로고    scopus 로고
    • note
    • 24a (for |B| ∼ 1.8 T, as in our experiments, the stirring effect is equivalent to ∼ 100 rpm).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.