Evidence of nitrate formation from the thermal decay of alkali metal dinitramides

Propellants, Explosives, Pyrotechnics

Volumn 24, Issue 1, 1999, Pages 43-45

  Cliff, Matthew D ^a   Smith, Matthew W ^a   Edwards, Darren P ^b  

^a AERO AND MAR RESEARCH LABORATORY   (Australia)

^b NONE

Author keywords

[No Author keywords available]

Indexed keywords

ALKALI METAL DINITRAMIDES; DECAY RESIDUES; NITRATE FORMATION; SALT RESIDUES; THERMAL DECAY;

DECAY (ORGANIC); DERIVATIVES; DIFFERENTIAL SCANNING CALORIMETRY; MASS SPECTROMETRY; NITRATES; PYROLYSIS; SALTS; THERMOGRAVIMETRIC ANALYSIS; X RAY DIFFRACTION ANALYSIS;

ALKALI METAL COMPOUNDS;

EID: 0032656958     PISSN: 07213115     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-4087(199902)24:1<43::AID-PREP43>3.0.CO;2-V     Document Type: Article

References (17)

1. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 316 749 (1994), SRI International, USA. J. C. Bottaro, R. J. Schmitt, P. E. Penwell, and D. S. Ross, U.S. Patent 5254324 (1993), SRI International, USA. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 415 852 (1995), SRI International, USA. H. H. Michels and J. A. Montgomery, "On the Structure and Thermochemistry of Hydrogen Dinitramide", J. Phys. Chem. 97, 6602-6606 (1993). R. J. Doyle, "Sputtered Ammonium Dinitramide: Tandem Mass Spectrometry of a New Ionic Nitramine", Org. Mass Spectrom. 28, 83-91 (1993). S. Trammell, P. A. Goodson, and B. P. Sullivan, "Coordination Chemistry and Photoreactivity of the Dinitramide Ion", Inorg. Chem. 35, 1421-1422 (1996). T. P. Russell, G. J. Piermarini, S. Block, and P. J. Miller, "Pressure, Temperature Reaction Phase Diagram for Ammonium Dinitramide", J. Phys. Chem. 100, 3248-3251 (1996).
2. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 316 749 (1994), SRI International, USA. J. C. Bottaro, R. J. Schmitt, P. E. Penwell, and D. S. Ross, U.S. Patent 5254324 (1993), SRI International, USA. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 415 852 (1995), SRI International, USA. H. H. Michels and J. A. Montgomery, "On the Structure and Thermochemistry of Hydrogen Dinitramide", J. Phys. Chem. 97, 6602-6606 (1993). R. J. Doyle, "Sputtered Ammonium Dinitramide: Tandem Mass Spectrometry of a New Ionic Nitramine", Org. Mass Spectrom. 28, 83-91 (1993). S. Trammell, P. A. Goodson, and B. P. Sullivan, "Coordination Chemistry and Photoreactivity of the Dinitramide Ion", Inorg. Chem. 35, 1421-1422 (1996). T. P. Russell, G. J. Piermarini, S. Block, and P. J. Miller, "Pressure, Temperature Reaction Phase Diagram for Ammonium Dinitramide", J. Phys. Chem. 100, 3248-3251 (1996).
3. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 316 749 (1994), SRI International, USA. J. C. Bottaro, R. J. Schmitt, P. E. Penwell, and D. S. Ross, U.S. Patent 5254324 (1993), SRI International, USA. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 415 852 (1995), SRI International, USA. H. H. Michels and J. A. Montgomery, "On the Structure and Thermochemistry of Hydrogen Dinitramide", J. Phys. Chem. 97, 6602-6606 (1993). R. J. Doyle, "Sputtered Ammonium Dinitramide: Tandem Mass Spectrometry of a New Ionic Nitramine", Org. Mass Spectrom. 28, 83-91 (1993). S. Trammell, P. A. Goodson, and B. P. Sullivan, "Coordination Chemistry and Photoreactivity of the Dinitramide Ion", Inorg. Chem. 35, 1421-1422 (1996). T. P. Russell, G. J. Piermarini, S. Block, and P. J. Miller, "Pressure, Temperature Reaction Phase Diagram for Ammonium Dinitramide", J. Phys. Chem. 100, 3248-3251 (1996).
4. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 316 749 (1994), SRI International, USA. J. C. Bottaro, R. J. Schmitt, P. E. Penwell, and D. S. Ross, U.S. Patent 5254324 (1993), SRI International, USA. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 415 852 (1995), SRI International, USA. H. H. Michels and J. A. Montgomery, "On the Structure and Thermochemistry of Hydrogen Dinitramide", J. Phys. Chem. 97, 6602-6606 (1993). R. J. Doyle, "Sputtered Ammonium Dinitramide: Tandem Mass Spectrometry of a New Ionic Nitramine", Org. Mass Spectrom. 28, 83-91 (1993). S. Trammell, P. A. Goodson, and B. P. Sullivan, "Coordination Chemistry and Photoreactivity of the Dinitramide Ion", Inorg. Chem. 35, 1421-1422 (1996). T. P. Russell, G. J. Piermarini, S. Block, and P. J. Miller, "Pressure, Temperature Reaction Phase Diagram for Ammonium Dinitramide", J. Phys. Chem. 100, 3248-3251 (1996).
5. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 316 749 (1994), SRI International, USA. J. C. Bottaro, R. J. Schmitt, P. E. Penwell, and D. S. Ross, U.S. Patent 5254324 (1993), SRI International, USA. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 415 852 (1995), SRI International, USA. H. H. Michels and J. A. Montgomery, "On the Structure and Thermochemistry of Hydrogen Dinitramide", J. Phys. Chem. 97, 6602-6606 (1993). R. J. Doyle, "Sputtered Ammonium Dinitramide: Tandem Mass Spectrometry of a New Ionic Nitramine", Org. Mass Spectrom. 28, 83-91 (1993). S. Trammell, P. A. Goodson, and B. P. Sullivan, "Coordination Chemistry and Photoreactivity of the Dinitramide Ion", Inorg. Chem. 35, 1421-1422 (1996). T. P. Russell, G. J. Piermarini, S. Block, and P. J. Miller, "Pressure, Temperature Reaction Phase Diagram for Ammonium Dinitramide", J. Phys. Chem. 100, 3248-3251 (1996).
6. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 316 749 (1994), SRI International, USA. J. C. Bottaro, R. J. Schmitt, P. E. Penwell, and D. S. Ross, U.S. Patent 5254324 (1993), SRI International, USA. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 415 852 (1995), SRI International, USA. H. H. Michels and J. A. Montgomery, "On the Structure and Thermochemistry of Hydrogen Dinitramide", J. Phys. Chem. 97, 6602-6606 (1993). R. J. Doyle, "Sputtered Ammonium Dinitramide: Tandem Mass Spectrometry of a New Ionic Nitramine", Org. Mass Spectrom. 28, 83-91 (1993). S. Trammell, P. A. Goodson, and B. P. Sullivan, "Coordination Chemistry and Photoreactivity of the Dinitramide Ion", Inorg. Chem. 35, 1421-1422 (1996). T. P. Russell, G. J. Piermarini, S. Block, and P. J. Miller, "Pressure, Temperature Reaction Phase Diagram for Ammonium Dinitramide", J. Phys. Chem. 100, 3248-3251 (1996).
7. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 316 749 (1994), SRI International, USA. J. C. Bottaro, R. J. Schmitt, P. E. Penwell, and D. S. Ross, U.S. Patent 5254324 (1993), SRI International, USA. R. J. Schmitt, J. C. Bottaro, P. E. Penwell, and D. C. Bomberger, U.S. Patent 5 415 852 (1995), SRI International, USA. H. H. Michels and J. A. Montgomery, "On the Structure and Thermochemistry of Hydrogen Dinitramide", J. Phys. Chem. 97, 6602-6606 (1993). R. J. Doyle, "Sputtered Ammonium Dinitramide: Tandem Mass Spectrometry of a New Ionic Nitramine", Org. Mass Spectrom. 28, 83-91 (1993). S. Trammell, P. A. Goodson, and B. P. Sullivan, "Coordination Chemistry and Photoreactivity of the Dinitramide Ion", Inorg. Chem. 35, 1421-1422 (1996). T. P. Russell, G. J. Piermarini, S. Block, and P. J. Miller, "Pressure, Temperature Reaction Phase Diagram for Ammonium Dinitramide", J. Phys. Chem. 100, 3248-3251 (1996).
8. O. A. Lukyanov, O. V. Anikin, V. P. Gorelik, and V. A. Tartakovsky, "Dinitramide and its Salts 3. Metallic Salts of Dinitramide", Russ. Chem. Bull. 43, 1457-1461 (1994). V. A. Tartakovsky and O. A. Lukyanov, "Synthesis of Dinitramide Salts", 25th Int. Annual Conf. ICT, 28th June-1 st July 1994, Karlsruhe, Germany.
9. O. A. Lukyanov, O. V. Anikin, V. P. Gorelik, and V. A. Tartakovsky, "Dinitramide and its Salts 3. Metallic Salts of Dinitramide", Russ. Chem. Bull. 43, 1457-1461 (1994). V. A. Tartakovsky and O. A. Lukyanov, "Synthesis of Dinitramide Salts", 25th Int. Annual Conf. ICT, 28th June-1 st July 1994, Karlsruhe, Germany.
10. O. A. Lukyanov, A. R. Agevnin, A. A. Leichenko, N. M. Seregina, and V. A. Tartakovskii, "Dinitramide and its Salts 4. Dinitramide Salts Derived from Ammonium Bases", Russ. Chem. Bull. 44, 108-112 (1995).
11. O. A. Lukyanov, V. P. Gorelik, and V. A. Tartakovsky, "Dinitramide and its Salts 1. Synthesis of Dinitramide Salts by Decyanoethylation of N,N-Dinitro-β-aminopropionitrile", Russ. Chem. Bull. 43, 89-92 (1994). O. A. Lukyanov, Y. V. Konnova, T. A. Klimova, and V. A. Tartakovsky, "Dinitramide and its Salts 2. Dinitramide in Michael and Retro-Michael Type Reactions", Russ. Chem. Bull. 43, 1200-1202 (1994).
12. O. A. Lukyanov, V. P. Gorelik, and V. A. Tartakovsky, "Dinitramide and its Salts 1. Synthesis of Dinitramide Salts by Decyanoethylation of N,N-Dinitro-β-aminopropionitrile", Russ. Chem. Bull. 43, 89-92 (1994). O. A. Lukyanov, Y. V. Konnova, T. A. Klimova, and V. A. Tartakovsky, "Dinitramide and its Salts 2. Dinitramide in Michael and Retro-Michael Type Reactions", Russ. Chem. Bull. 43, 1200-1202 (1994).
13. R. J. Schmitt and J. C. Bottaro, "The Development of New Protecting/Leaving Groups and Application to the Synthesis of Cage Nitramines", Technical Report AD-A261-496 (1993), SRI International, USA.
14. M. D. Cliff and M. W. Smith, "Thermal Characteristics of Alkali Metal Dinitramide Salts", J. Energetic Materials, 17(1), 69-86 (1999).
15. JCPDS International Centre for Diffraction Data, 1601 Park Lane, Swarthmore, PA 19081-2389, USA.
16. Micro Powder Diffraction Search/Match; Fein-Marquart Association Inc.
17. 85Rb reported only.