Effect of NaCl or KCl on the excess enthalpies of alkanol + water mixtures at various temperatures and salt concentrations

Journal of Chemical and Engineering Data

Volumn 44, Issue 4, 1999, Pages 701-714

  Friese, Thorsten ^a   Ulbig, Peter ^a   Schulz, Siegfried ^a   Wagner, Katrin ^a  

^a TU DORTMUND UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CALORIMETRY; CHLORINE COMPOUNDS; ENTHALPY; MIXTURES; ORGANIC COMPOUNDS; SALTS; TEMPERATURE; THERMAL VARIABLES MEASUREMENT;

ALKANOL; FLOW MIX ENTHALPY;

COMPOSITION EFFECTS;

EID: 0032649997     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je980303x     Document Type: Article

References (14)

1. Achard, C.; Dussap, C. G.; Gros, J. B. Representation of Vapour-Liquid Equilibria in Water-Alcohol-Electrolyte Mixtures with a Modified UNIFAC Group-Contribution Method. Fluid Phase Equilibr. 1994, 98, 71-89.
2. Boyne, J. A.; Williamson, A. G. Enthalpies of Mixing of Ethanol and Water at 25 Degrees C. J. Chem. Eng. Data 1967, 12, 318.
3. Chand, A.; Fenby, D. V. Enthalpy of Deuterium Exchange Reactions in Water + Ethanol and Water + Methanol. J. Chem. Thermodyn. 1978, 10, 997-1001.
4. Costigan, M. J.; Hodges, L. J.; Marsh, K. N.; Stokes, R. H.; Tuxford, C. W. The Isothermal Displacement Calorimeter: Design Modifications for Measuring Exothermic Enthalpies of Mixing. Aust. J. Chem. 1980, 33, 2103-2119.
5. Friese, T.; Schulz, S.; Ulbig, P.; Wagner, K. Effect of NaCl on the Excess Enthalpies of Binary Liquid Systems. Thermochim. Acta 1998, 310, 87-94.
6. Gironi, F.; Lamberti, L. Vapour-Liquid Equilibrium Data for the Water-2-Propanol System in the Presence of Dissolved Salts. Fluid Phase Equilib. 1995, 105, 273-286.
7. Gomis, V.; Ruiz, F.; De Vera, G.; Lépez, E.; Saquete, M. D. Liquid-Liquid-Solid Equilibria for the Ternary Systems Water-Sodium Chloride or Potassium Chloride-1-Propanol or 2-Propanol. Fluid Phase Equilib. 1994, 98, 141-147.
8. Gomis, V.; Ruiz, F.; Boluda, N.; Saquete, M. D. The Influence of Temperature on the Liquid-Liquid-Solid Equilibrium of the Ternary System Water-Potassium Chloride-2-Propanol. Fluid Phase Equilib. 1997, 130, 223-229.
9. Larkin, J. A. Thermodynamic Properties of Aqueous Non-Electrolyte Mixtures. I. Excess Enthalpy for Water + Ethanol at 298.15 to 383.15. K. J. Chem. Thermodyn. 1975, 7, 137-148.
10. Loehe, J. R.; Donohue, M. D. Recent Advances in Modeling Thermodynamic Properties of Aqueous Strong Electrolyte Systems. AIChE J. 1997, 43, 180-195.
11. Löwen, B. Experimentelle Bestimmung und Korrelation von Exzessenthalpien binärer Gemische bei grosser Verdünnung; Shaker: Aachen, 1995.
12. Mock, B.; Evans, L. B.; Chen, C.-C. Thermodynamic Representation of Phase Equilibria of Mixed-Solvent Electrolyte Systems. AIChE J. 1986, 22, 1655-1664.
13. Renon, H. Models for Excess Properties of Electrolyte Solutions: Molecular Bases and Classification, Needs and Trends for New Developments. Fluid Phase Equilib. 1996, 116, 217-224.
14. Wagner, K.; Friese, T.; Schulz, S.; Ulbig, P. Solubilities of Sodium Chloride in Organic and Aqueous-Organic Solvent Mixtures. J. Chem. Eng. Data 1998, 43, 871-875.