Evaluating pore sizes in mesoporous materials: a simplified standard adsorption method and a simplified Broekhoff-de Boer method

Langmuir

Volumn 15, Issue 16, 1999, Pages 5403-5409

  Lukens Jr , Wayne W ^a   Schmidt Winkel, Patrick ^a   Zhao, Dongyuan ^a   Feng, Jianglin ^a   Stucky, Galen D ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; APPROXIMATION THEORY; GASES; MOLECULAR STRUCTURE; NITROGEN; PARTICLE SIZE ANALYSIS; STATISTICAL METHODS; VOLUME MEASUREMENT;

BROEKHOFF-DE BOER METHOD; FRENKEL-HALSEY-HILL THEORY; MESOPOROUS MATERIALS;

POROUS MATERIALS;

EID: 0032642669     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la990209u     Document Type: Article

References (45)

1. (a) Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Nature 1992, 359, 710.
2. (b) Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T-W.; Olsen, D. H.; Sheppard, E. W.; McCuller, S. B.; Higgins, J. B.; Schlenker, J. L. J. Am. Chem. Soc. 1992, 114, 10834.
3. (c) Inagaki, S.; Fukushima, Y.; Kuroda, K. J. Chem. Soc., Chem. Commun. 1993, 680.
4. (a) Blasco, T.; Corma, A.; Navarro, M. T.; Pérez Pariente, J. J. Catal. 1995, 156, 65.
5. (b) Gontier, S.; Tuel, A. Zeolites 1995, 15, 601.
6. (c) Zhang, W.; Wang, J.; Tanev, P. T.; Pinnavaia, T. J. Chem. Commun. 1996, 979.
7. (a) Maschmeyer, T.; Rey, F.; Sankar, G.; Thomas, J. M. Nature 1995, 378, 159.
8. (b) Burch, R.; Cruise, N.; Gleeson, D.; Tsang, S. C. Chem. Commun. 1996, 951.
9. (c) Walker, J. V.; Morey, M.; Carlsson, H.; Davidson, A.; Stucky, G. D.; Butler, A. J. Am. Chem. Soc. 1997, 119, 6921.
10. (a) Feng, X.; Fryxell, G. E.; Wang, L.-Q.; Kim, A. Y.; Liu, J.; Kemner, K. M. Science 1997, 276, 923.
11. (b) Mercier, L.; Pinnavaia, T. J. Adv. Mater. 1997, 9, 500.
12. (a) Schmidt, R.; Hansen, E. W.; Stöcker, M.; Akporiaye, D.; Ellestad, O. H. J. Am. Chem. Soc. 1995, 117, 4049.
13. (b) Ravikovitch, P. I.; Ó Domhnail, S. C.; Neimark, A. V.; Schüth, F.; Unger, K. K. Langmuir 1995, 11, 4765.
14. (c) Kruk, M.; Jaroniec, M.; Sayari, A. Langmuir 1997, 13, 6267.
15. (d) Sayari, A.; Liu, P.; Kruk, M.; Jaroniec, M. Chem. Mater. 1997, 9, 2499.
16. (e) Kruk, M.; Jaroniec, M.; Sayari, A. J. Phys. Chem. B. 1997, 101, 583.
17. (f) Morishige, K.; Shikimi, M. J. Chem. Phys. 1998, 108, 7821.
18. Ravikovitch, P. I.; Wei, D.; Chueh, W. T.; Haller, G. L.; Neimark, A. V. J. Phys. Chem. B. 1997, 101, 3671.
19. (a) Dabadie, T.; Ayral, A.; Guizard, C.; Cot, L.; Lacan, P. J. Mater. Chem. 1996, 6, 1789.
20. (b) Galarneau, A.; Desplantier, D.; Dutartre, R.; Di Renzo, F. Microporous Mesoporous Mater. 1999, 27, 297.
21. Bagshaw, S. A.; Prouzet, E.; Pinnavaia, T. J. Science 1995, 269, 1242.
22. (a) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.
23. (b) Zhao, D.; Huo, Q.; Feng, J.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1998, 120, 6024.
24. (c) Schmidt-Winkel, P.; Yang, P.; Margolese, D.; Chmelka, B. F.; Stucky, G. D. Adv. Mater, 1999, 11, 303.
25. (d) Schmidt-Winkel, P.; Lukens, W. W., Jr.; Zhao, D.; Yang, P.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1999, 121, 254.
26. Gregg, S. J.; Sing, K. S. W. Adsorption, Surface Area and Porosity; Academic Press: London, 1982.
27. Barrett, E. P.; Joyner, L. G.; Halenda, P. P. J. Am. Chem. Soc. 1951, 73, 373.
28. Broekhoff, J. C. P.; de Boer, J. H. J. Catal. 1967, 9, 8.
29. (a) Broekhoff, J. C. P.; de Boer, J. H. J. Catal. 1967, 9, 15.
30. (b) Broekhoff, J. C. P.; de Boer, J. H. J. Catal. 1968, 10, 153.
31. (c) Broekhoff, J. C. P.; de Boer, J. H. J. Catal. 1968, 10, 368.
32. (d) Broekhoff, J. C. P.; de Boer, J. H. J. Catal. 1968, 10, 377.
33. (a) Hill, T. L. Adv. Catal. 1952, 4, 211.
34. (b) Halsey, G. J. Chem. Phys. 1948, 16, 931.
35. (c) Halsey, G. Adv. Catal. 1952, 4, 259.
36. Jelinek, L.; sz. Kovátz, E. Langmuir, 1994, 10, 4225.
37. Developed at the U.S. National Institute of Health and available on the Internet at http://rsb.info.nih.gov/nih-image/.
38. Brunauer, S.; Emmett, P. H.; Teller, E. J. Am. Chem. Soc. 1938, 60, 309.
39. (a) Alexander, G. B.; Iler, R. K. J. Phys. Chem. 1953, 37, 932.
40. (b) Kodera, K; Onishi, Y. Bull. Chem. Soc. Jpn. 1960, 33, 338.
41. Carrott, P. J. M.; Sing, K. S. W. Pure Appl. Chem. 1989, 61, 1835.
42. 22 and 5 is determined empirically (see refs 7b and 14).
43. (a) Scherer, G. W. J. Non-Cryst. Solids 1998, 225, 192.
44. (b) Efremov, D. K; Fenelonov, V. B. React. Kinet. Catal. Lett. 1994, 52, 413.
45. Lippens, B. D.; Linsen, B. G.; de Boer, J. H. J. Catal. 1964, 3, 32.