Synthesis of 4,4′-trimethylenebis(1-benzyl-1-methylpiperidinium) diastereomers and their use as structure-directing agents in pure-silica molecular sieve syntheses

Microporous and Mesoporous Materials

Volumn 28, Issue 3, 1999, Pages 519-530

  Tsuji, K ^a   Beck, L W ^a   Davis, M E ^a  

^a California Institute of Technology   (United States)

Author keywords

Diastereomers; Organic inorganic composites; Pure silica molecular sieves; Synthesis

Indexed keywords

CRYSTALLIZATION; MOLECULAR SIEVES; MOLECULAR STRUCTURE; MOLECULES; SILICA; SYNTHESIS (CHEMICAL); TOPOLOGY;

DIASTEREOMERS; PIPERIDINIUM RING FLIPPING; STRUCTURE DIRECTING AGENTS;

AROMATIC HYDROCARBONS;

EID: 0032640808     PISSN: 13871811     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1387-1811(98)00341-2     Document Type: Article

References (8)

1. M.E. Davis, S.I. Zones, in: M.L. Occelli, H. Kessler (Eds.), Synthesis of Porous Materials: Zeolites, Clays and Nanostructures, Marcel Dekker, New York, 1996, pp. 1-35.
2. Davis M.E., Lobo R.F. Chem. Mater. 4:1992;756.
3. Tsuji K., Davis M.E. Microporous Mater. 11:1997;53.
4. M.A. Camblor, A. Corma, S. Valencia, Chem. Commun. (1996) 2365.
5. W.L.F. Armarego, Stereochemistry of Heterocyclic Compounds. Part 1. Nitrogen Heterocycles, Wiley, New York, 1977, pp. 166-168.
6. R.A.Y.Jones, A.R. Katritzky, P.G. Mente, J. Chem. Soc. B (1970) 1210.
7. M. Rubiralta, E. Giralt, A. Diez, Piperidine Structure, Preparation, Reactivity, and Synthetic Applications of Piperidine and its Derivatives Studies in Organic Chemistry 43, Elsevier, Amsterdam, 1991, pp. 107-110.
8. C. Reichardt, Solvents and Solvent Effects in Organic Chemistry 2nd ed., VCH Publishers, Weinheim, 1988, pp. 365-371.