Segmental dynamics in poly(methylphenylsiloxane) networks by dielectric relaxation spectroscopy

Macromolecules

Volumn 32, Issue 10, 1999, Pages 3518-3527

  Fitz, Benjamin D ^a   Mijovic, Jovan ^a  

^a POLYTECHNIC UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CROSSLINKING; DIELECTRIC RELAXATION; MOLECULAR ORIENTATION; MOLECULAR WEIGHT; ORGANIC POLYMERS; SPECTROSCOPY;

DIPOLE MOMENT; POLYMETHYLPHENYLSILOXANE;

MOLECULAR DYNAMICS;

EID: 0032625789     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma981937b     Document Type: Article

References (72)

1. Deng, Y.; Martin, G. Macromolecules 1994, 27, 5141.
2. Roland, C. M. Macromolecules 1994, 27, 4242.
3. Glatz-Reichenback, J.; Sorriero, L.; Fitzgerald, J. Macromolecules 1994, 27, 1338.
4. Tabellout, M.; Randriantoandro, H.; Emery, J.; Durrand, D.; Hayward, D.; Pethrick, R. Polymer 1995, 36, 4547.
5. Fournier, J.; Williams, G.; Duch, C.; Aldridge, G. Macromolecules 1996, 29, 7097.
6. Cassalini, R.; Livi, A.; Rolla, P. Levita, G.; Fioretto, D. Phys. Rev. B 1996, 53, 564.
7. Fitz, B.; Andjelic, S.; Mijovic, J. Macromolecules 1997, 30, 5227. Andjelic, S.; Fitz, B.; Mijovic, J. Macromolecules 1997, 30, 5239. Andjelic, S.; Mijovic, J. Macromolecules 1998, 31, 8463.
8. Fitz, B.; Andjelic, S.; Mijovic, J. Macromolecules 1997, 30, 5227. Andjelic, S.; Fitz, B.; Mijovic, J. Macromolecules 1997, 30, 5239. Andjelic, S.; Mijovic, J. Macromolecules 1998, 31, 8463.
9. Fitz, B.; Andjelic, S.; Mijovic, J. Macromolecules 1997, 30, 5227. Andjelic, S.; Fitz, B.; Mijovic, J. Macromolecules 1997, 30, 5239. Andjelic, S.; Mijovic, J. Macromolecules 1998, 31, 8463.
10. Wasylyshyn, D.; Johari, G. P.; Salvetti, G.; Tombari, E. J. Phys.: Condens. Matter 1997, 9, 10521. Ferrari, C.; Tombari, E.; Salvetti, G.; Johari, G. P. J. Chem. Soc., Faraday Trans. 1998, 94, 1293.
11. Wasylyshyn, D.; Johari, G. P.; Salvetti, G.; Tombari, E. J. Phys.: Condens. Matter 1997, 9, 10521. Ferrari, C.; Tombari, E.; Salvetti, G.; Johari, G. P. J. Chem. Soc., Faraday Trans. 1998, 94, 1293.
12. Fitz, B.; Mijovic, J. Segmental Dynamics And Density Fluctuations in Polymer Networks During Chemical Vitrification. Macromolecules, in press.
13. Donth, E. J. Non-Cryst. Solids 1982, 53, 325.
14. Adam, G.; Gibbs, J. J. Chem. Phys. 1965, 43, 139.
15. Matsuoka, S. J. Appl. Polym. Sci. 1997, 64, 77.
16. Helfand, E. Science 1984, 266, 647.
17. Schmidt-Rohr, K.; Spiess, H. Phys. Rev. Lett. 1991, 66, 3020.
18. Russel, E.; Israeloff, N.; Walther, L.; Gomariz, H. Phys. Rev. Lett. 1998, 81, 1461.
19. Floudas, G.; Paraskeva, S.; Hadjichristidis, N.; Fytas, G.; Chu, B.; Semenov, A. J. Chem. Phys. 1997, 107, 5502.
20. Arndt, M.; Stannarius, R.; Groothues, H.; Hempel, E.; Kremer, F. Phys. Rev. Lett. 1997, 79, 2077.
21. Hu, H.; Carson, G.; Granick, S. Phys. Rev. Lett. 1991, 66, 2758.
22. Inoue, T.; Cicerone, M.; Ediger, M. Macromolecules 1995, 28, 3425.
23. Fischer, E. Physica A 1993, 201, 183.
24. Fischer, E.; Donth, E.; Steffen, W. Phys. Rev. Lett. 1992, 68, 2344.
25. Debye, P.; Bueche, A. J. Appl. Phys. 1949, 20, 518.
26. Moynihan, C. T.; Schroeder, J. J. Non-Cryst. Solids 1993, 160, 52.
27. Schiener, B.; Bohmer, R.; Loidl, A.; Chamberlin, R. Science 1996, 274, 752.
28. Mel'cuk, A.; Ramos, R.; Gould, H.; Klein, W.; Mountain, R. Phys. Rev. Lett. 1995, 75, 2522.
29. Williams, G. In Keynote Lectures In Selected Topics Of Polymer Science; Riande, E., Ed.; CSIC: Madrid, 1997; Chapter 1, pp 1-40. Williams, G. In Dielectric Spectroscopy Of Polymeric Materials; Runt, J. P., Fitzgerald, J. J., Eds.; American Chemical Society: Washington, DC, 1997; Chapter 1, pp 3-65.
30. Williams, G. In Keynote Lectures In Selected Topics Of Polymer Science; Riande, E., Ed.; CSIC: Madrid, 1997; Chapter 1, pp 1-40. Williams, G. In Dielectric Spectroscopy Of Polymeric Materials; Runt, J. P., Fitzgerald, J. J., Eds.; American Chemical Society: Washington, DC, 1997; Chapter 1, pp 3-65.
31. Ferry, J. D. Viscoelastic Properties Of Polymers, 2nd ed.; Wiley: New York, 1980.
32. McCrum, N. G.; Read, B.; Williams, G. Anelastic and Dielectric Effects in Polymeric Solids, Wiley: New York, 1967.
33. Fröhlich, H. Theory Of Dielectrics, 2nd ed.; Oxford University Press: Oxford, 1958.
34. Williams, G.; Watts, D. C. Trans. Faraday Soc. 1970, 66, 80.
35. Dishon, M.; Weiss, G. H.; Bendler, J. T. J. Res. Natl. Bur. Stand. 1986, 90, 27.
36. Havriliak, S.; Negami, S. J. Polym. Sci., Part C 1966, 14, 99.
37. Richert, R.; Angell, C. A. J. Chem. Phys. 1998, 108, 9016.
38. Stickel, F.; Fischer, E.; Richert, R. J. Chem. Phys. 1995, 102, 6251. Laughlin, W. T.; Uhlmann, D. R. J. Phys. Chem. 1972, 76, 2317. Barlow, A. J.; Lamb, J.; Matheson, A. J. Proc. R. Soc. London, Ser. A. 1966, 292, 322.
39. Stickel, F.; Fischer, E.; Richert, R. J. Chem. Phys. 1995, 102, 6251. Laughlin, W. T.; Uhlmann, D. R. J. Phys. Chem. 1972, 76, 2317. Barlow, A. J.; Lamb, J.; Matheson, A. J. Proc. R. Soc. London, Ser. A. 1966, 292, 322.
40. Stickel, F.; Fischer, E.; Richert, R. J. Chem. Phys. 1995, 102, 6251. Laughlin, W. T.; Uhlmann, D. R. J. Phys. Chem. 1972, 76, 2317. Barlow, A. J.; Lamb, J.; Matheson, A. J. Proc. R. Soc. London, Ser. A. 1966, 292, 322.
41. Vogel, H. Phys. Z. 1921, 22, 645. Fulcher, G. J. Am. Ceram. Soc. 1923, 8, 339. Tammann, G.; Hesse, W. Z. Anorg. Allg. Chem. 1926, 156, 245.
42. Vogel, H. Phys. Z. 1921, 22, 645. Fulcher, G. J. Am. Ceram. Soc. 1923, 8, 339. Tammann, G.; Hesse, W. Z. Anorg. Allg. Chem. 1926, 156, 245.
43. Vogel, H. Phys. Z. 1921, 22, 645. Fulcher, G. J. Am. Ceram. Soc. 1923, 8, 339. Tammann, G.; Hesse, W. Z. Anorg. Allg. Chem. 1926, 156, 245.
44. Vilgis, T. Phys. Rev. B 1993, 47, 2882.
45. Goetze, W.; Sjogren, L. Rep. Prog. Phys. 1992, 55, 241.
46. Jäckle, J. Rep. Prog. Phys. 1986, 49, 171.
47. Angell, C. A. Polymer 1997, 38, 6261.
48. Angell, C. A. In Relaxations in Complex Systems; Ngai, K. L., Wright, G., Eds.; National Technical Information Service, U.S. Department of Commerce; Springfield, VA, 1984.
49. Ngai, K. L.; Rendell, R. W.; Rajagopal, A. K.; Teitler, S. Ann. N. Y. Acad. Sci. 1986, 484, 150.
50. Ngai, K. L.; Roland, M. C. Macromolecules 1993, 26, 6824.
51. Zallen, R. The Physics Of Amorphous Solids; Wiley: New York, 1989.
52. Roland, C. M.; Ngai, K. L. J. Non-Cryst. Solids 1997, 212, 74.
53. Plazek, D. J.; Ngai, K. L. Macromolecules 1991, 24, 1222.
54. Momper, B.; Wagner, Th.; Maschke, U.; Ballauff, M.; Fischer, E. Polym. Commun. 1990, 31, 186. Valles, E.; Macosko, C. Macromolecules 1979, 12, 521.
55. Momper, B.; Wagner, Th.; Maschke, U.; Ballauff, M.; Fischer, E. Polym. Commun. 1990, 31, 186. Valles, E.; Macosko, C. Macromolecules 1979, 12, 521.
56. Warrick, E.; Pierce, O.; Polmanteer, K; Saam, J. Rubber Chem. Technol. 1979, 52, 438.
57. Boese, D.; Momper, B.; Meier, G.; Kremer, F.; Hagenah, J.; Fischer, E. Macromolecules 1989, 22, 4416.
58. Angell, C. A. J. Res. NIST 1997, 102, 171.
59. DGEBA, diglycidyl ether of Bisphenol A. MDA, methylenedianiline. These are a typical epoxy and amine thermoset-forming system (cf. ref 7).
60. Kirst, K; Kremer, F.; Pakula, T.; Hollingshurst, J. Colloid Polym. Sci. 1994, 272, 1420.
61. Meier, G.; Fujara, F.; Petry, W. Macromolecules 1989, 22, 4421.
62. Böhmer, R.; Ngai, K. L.; Angell, C.; Plazek, D. J. Chem. Phys. 1993, 99, 4201.
63. Dixon, P.; Wu, L.; Nagel, S.; Williams, B.; Carini, J. Phys. Rev. Lett. 1990, 65, 1108.
64. Salom, C.; Freire, J.; Hernandez-Fuentes, I. Polym. J. 1988, 20, 1109.
65. Fytas, G.; Dorfmüller, Th.; Lin, Y.; Chu, B. Macromolecules 1981, 14, 1088.
66. Flory, P. J. Statistical Mechanics Of Chain Molecules; Wiley: New York, 1969.
67. Llorente, M.; Fernandez de Pierola, I.; Saiz, E. Macromolecules 1985, 18, 2663.
68. Mark, J. E.; Ko, J. J. Polym. Sci., Polym. Phys. Ed. 1975, 13, 2221
69. Flory, P.; Crescenzi, V.; Mark, J. J. Am. Chem. Soc. 1967, 86, 146.
70. Mark, J. J. Chem. Phys. 1968, 49, 1398.
71. The phenomena of a network relaxation becoming entirely local because of the networks disturbance of the cooperative domain size is the subject of a future report from our laboratory. This effect is similar to the situation of amorphous polymer material confined within a thin space between crystalline lamellar walls, e.g. Schick, C.; Donth, E. Phys. Scr. 1991, 43, 423. A similar finding on PVDF/PMMA semicrystalline blends is also the subject of a forthcoming article from our laboratory.
72. Alegria, A.; Guerrica-Echevarria, E.; Goitiandia, L.; Telleria, I.; Colmenero, J. Macromolecules 1995, 28, 1516.