A new class of self-assembled monolayers: closo-B12H11S3- on gold [11]

Journal of the American Chemical Society

Volumn 120, Issue 38, 1998, Pages 9961-9962

  Yeager, L J ^a   Saeki, F ^a   Shelly, K ^a   Hawthorne, M F ^a   Garrell, R L ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BORANE DERIVATIVE; DISULFIDE; GOLD; NANOPARTICLE; SULFUR;

ADSORPTION; CHEMICAL STRUCTURE; ELECTROCHEMISTRY; LETTER; RAMAN SPECTROMETRY; SURFACE PROPERTY;

EID: 0032582082     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9809253     Document Type: Letter

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9. The oxidative-reductive cycles used to prepare the gold electrodes for SER spectroscopy, along with the Raman instrumentation, have been described elsewhere.4 Typical incident power for obtaining SER spectra was 75 mW at the sample, with spectral integration times of 2-15 s. The data presented have been corrected for the instrumental response function.
10. 14
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24. Yeager, L. J.; Saeki, F.; Shelly, K.; Hawthorne, M. F.; Garrell, R. L., manuscript in preparation.
25. 10 Thus, we find no evidence for oxidation of the thiol to the disultide under our conditions.