Synthesis of the sesquiterpenoid trichodiene using a free radical fragmentation approach

Tetrahedron Letters

Volumn 39, Issue 31, 1998, Pages 5489-5492

  Lange, Gordon L ^a   Furlan, Lorena ^a   MacKinnon, Mark C ^a  

^a UNIVERSITY OF GUELPH   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

SESQUITERPENOID;

ARTICLE; METHODOLOGY; PHOTOCHEMISTRY; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0032581540     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)01140-X     Document Type: Article

References (19)

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13. 6. If a 3-fold excess of 3 is used, significant amounts of alkene dimer are formed.
14. 2 solvent the proportion of the undesired head-to-tail adduct was increased.
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16. 2 with the iodide and carbonyl groups may facilitate this fragmentation: Honda, T.; Naito, K.; Yamane, S.-i.; Suzuki, Y. J. Chem. Soc., Chem. Commun. 1992, 1218-1220.
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