Synthesis of D-mannofuranosyl-ethanethioamides and the corresponding ethanedithioate, the first C-glycosyl derivative with thioacylating properties

Tetrahedron Letters

Volumn 39, Issue 18, 1998, Pages 2755-2758

  Sandrinelli, Franck ^b   Le Roy Gourvennec, Sylvie ^b   Masson, Serge ^b   Rollin, Patrick ^a  

^a UNIVERSITÉ D'ORLÉANS   (France)

^b NONE

Author keywords

[No Author keywords available]

Indexed keywords

2,3:5,6 DI O ISOPROPYLIDENE ALPHA MANNOFURANOSE; CARBOHYDRATE; UNCLASSIFIED DRUG;

ARTICLE; CARBOHYDRATE ANALYSIS; CHEMICAL REACTION; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0032580425     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00304-9     Document Type: Article

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21. 2H mixture.
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26. 2 ; Calc. : C, 51.73; H, 6.89; S, 18.39. Found : C, 51.79, H, 7.04, S, 18.57. The crude product was purified by column chromatography (silica gel; EtOAc-light petroleum, 25:75).
27. 7S ; Calc. : S, 18.22. Found : S, 18.47. The crude product was purified by column chromatography (silica gel; EtOAc-light petroleum, 2:8) and by crystallisation from hexane.