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3542997075
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Issued as N.R.C.C. No. 40880
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Issued as N.R.C.C. No. 40880.
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3543002458
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N.R.C.C. Summer student 1994 and 1995
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N.R.C.C. Summer student 1994 and 1995.
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3542998906
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Gorlaeus Laboratories, Leiden University, 2300 RA Leiden, The Netherlands
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Gorlaeus Laboratories, Leiden University, 2300 RA Leiden, The Netherlands.
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3542994708
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Department of Chemistry, University of New England, Armidale, N.S.W. 2351, Australia
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Department of Chemistry, University of New England, Armidale, N.S.W. 2351, Australia.
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2 and partly to the fact that significantly higher peroxynitrite concentrations were used in the earlier work (vide infra).
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2-free conditions we opted for the simplicity of the ozone/azide method which can be justified by the fact that the DMSO concentration was always 10, or more, times greater than the concentration of peroxynitrite and, hence, than the concentration of nitrite.
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After this work was completed, ref 7 appeared, which reported that the decay of peroxynitrite was slower at 0.48 mM than at 0.048 mM [peroxynitrite]. Both of these concentrations are, unfortunately, below the minimum peroxynitrite concentration we felt we could employ for reliable quantitation of products.
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37 did not work in our DMSO/HOONO product mixtures, even when MSA was deliberately added! The culprit is residual azide (used in the synthesis of peroxynitrite), which destroys the diazonium salts even at very low concentrations.
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