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Volumn 120, Issue 16, 1998, Pages 3949-3962

Magnetic circular dichroism spectroscopic studies of mononuclear non- heme ferrous model complexes. Correlation of excited- and ground-state electronic structure with geometry

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CATALYSIS; CIRCULAR DICHROISM; ENZYME ACTIVE SITE; ENZYME ACTIVITY; METAL BINDING; SPECTROSCOPY;

EID: 0032577011     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja973735l     Document Type: Article
Times cited : (90)

References (76)
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    • personal communication
    • Crystallographic information is pending growth of crystals that are suitable for X-ray diffraction (Caradonna, J. P., personal communication).
    • Caradonna, J.P.1
  • 29
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    • Personal communication
    • Hagen, K. S. Personal communication.
    • Hagen, K.S.1
  • 36
    • 2642713755 scopus 로고    scopus 로고
    • Kitajima, N.; Moro-oka, Y. Unpublished results
    • Kitajima, N.; Moro-oka, Y. Unpublished results.
  • 37
    • 2642647456 scopus 로고    scopus 로고
    • note
    • -; PMAH, 2-((N-(aminoethyl)amino)methyl)-4-(N′-(2-(4-imidazolyl)ethyl)carbamoyl)-5- bromopyrimidine; PY5, 2,6-(bis(2-pyridyl)methoxymethane)pyridine; TMC, 1,4,8,11 -tetramethyl-1,4,8,11-tetraazacyclotetradecane; trpn, 3,3′,3″-triaminotripropylamine.
  • 51
    • 2642671558 scopus 로고    scopus 로고
    • note
    • Note that the Boltzmann factors for the ℬ-terms differ from that for the Script C sign-term because field-induced mixing is much greater for perpendicular fields; therefore, the Zeeman splitting will be governed by g⊥, which is very small for S = 2 systems (see ref 3).
  • 52
    • 2642677234 scopus 로고    scopus 로고
    • note
    • S = ±1 excited state.
  • 53
    • 2642640897 scopus 로고    scopus 로고
    • note
    • These data have been refit from the original reference (ref 38) using the +ZFS model and the updated fitting results are shown here.
  • 58
    • 2642680437 scopus 로고    scopus 로고
    • note
    • There is a typographical error in the earlier references for this equation (refs 3 and 5).
  • 66
    • 0027246677 scopus 로고
    • 11 and a recent low-temperature crystal structure at higher resolution (Minor et al. Biochemistry 1996, 35, 10687) indicate that an additional water ligand is also likely present in the 4C structure.
    • (1993) Science , vol.260 , pp. 1482
    • Boyington1
  • 67
    • 0029740369 scopus 로고    scopus 로고
    • 11 and a recent low-temperature crystal structure at higher resolution (Minor et al. Biochemistry 1996, 35, 10687) indicate that an additional water ligand is also likely present in the 4C structure.
    • (1996) Biochemistry , vol.35 , pp. 10687
    • Minor1
  • 70
    • 2642704656 scopus 로고    scopus 로고
    • note
    • 2v is chosen as a low-symmetry point group in which all orbital degeneracy is lifted, but x and y transform as different irreducible representations.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.