Stereodivergent allylindation of cyclopropenes. Remarkable stereodirection and acceleration by neighbouring carboxyl and hydroxyl groups

Tetrahedron Letters

Volumn 39, Issue 35, 1998, Pages 6327-6330

  Araki, Shuki ^a   Nakano, Hiroyuki ^a   Subburaj, Kandasamy ^a   Hirashita, Tsunehisa ^a   Shibutani, Kensuke ^a   Yamamura, Hatsuo ^a   Kawai, Masao ^a   Butsugan, Yasuo ^a  

^a NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; CARBOXYL GROUP; CARBOXYLIC ACID; HYDROXYL GROUP; PROPYLENE;

ARTICLE; CHELATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 0032572905     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)01343-4     Document Type: Article

References (29)

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12. 4. For selected examples of carbometalation of cyclopropenes, see: allylboration: (a) Bubnov, Y. N.; Kazanskii, B. A.; Nesmeyanova, O. A.; Rudashevskaya, T. Y.; Mikhailov, B. M. Izv. Akad. Nauk SSSR, Ser. Khim. 1977, 2545-2548; Chem. Abstr. 1978, 88, 74419; allylmagnesiation:
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29. 2: C, 74.29; H, 10.48. Found: C, 74.16; H, 10.40.