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Volumn 9, Issue 6, 1998, Pages 1065-1072

Asymmetric aza-Claisen rearrangement of allyl imidates catalyzed by homochiral cationic palladium(II) complexes

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPOUND; BENZAMIDE DERIVATIVE; PALLADIUM COMPLEX;

EID: 0032571580     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(98)00059-7     Document Type: Article
Times cited : (70)

References (46)
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    • Shibasaki and Overman independently reported an asymmetric Heck reaction, where cationic chiral palladium(II) brought about high catalytic activity as well as enantioselectivity, see: (a) Sato, Y.; Sodeoka, M.; Shibasaki, M. J. Org. Chem. 1989, 54, 4738. (b) Carpenter, N. E.; Kucera, D. J.; Overman, L. E. J. Org. Chem. 1989, 54, 5846.
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    • Shibasaki and Overman independently reported an asymmetric Heck reaction, where cationic chiral palladium(II) brought about high catalytic activity as well as enantioselectivity, see: (a) Sato, Y.; Sodeoka, M.; Shibasaki, M. J. Org. Chem. 1989, 54, 4738. (b) Carpenter, N. E.; Kucera, D. J.; Overman, L. E. J. Org. Chem. 1989, 54, 5846.
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    • Recent examples of catalytic asymmetric reactions by use of cationic chiral palladium complexes, see: (a) Sodeoka, M.; Ohrai, K.; Shibasaki, M. J. Org. Chem. 1995, 60, 2648. (b) Sugiura, M.; Nakai, T. Angew. Chem., Int. Ed. Engl. 1997, 36, 2366.
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  • 32
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    • Recent examples of catalytic asymmetric reactions by use of cationic chiral palladium complexes, see: (a) Sodeoka, M.; Ohrai, K.; Shibasaki, M. J. Org. Chem. 1995, 60, 2648. (b) Sugiura, M.; Nakai, T. Angew. Chem., Int. Ed. Engl. 1997, 36, 2366.
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    • note
    • 3 (little catalytic activity under the same reaction conditions).
  • 41
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    • For recent reviews, see: (a) Togni, A.; Venanzi, L. M. Angew. Chem., Int. Ed. Engl. 1994, 33, 497. (b) Pfaltz, A. Acc. Chem. Res. 1993, 26, 339.
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