Preparation and structure of new homochiral diazaphosphole ligands and their platinum(II) chloride complexes

Tetrahedron Asymmetry

Volumn 9, Issue 6, 1998, Pages 927-935

  Vasconcelos, Isabel C F ^a   Anderson, Gordon K ^a   Rath, Nigam P ^a   Spilling, Christopher D ^a  

^a UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; PLATINUM COMPLEX; PLATINUM DERIVATIVE;

ARTICLE; CATALYSIS; CHIRALITY; COMPLEX FORMATION; CRYSTAL STRUCTURE; ENANTIOMER; LIGAND BINDING; METAL BINDING; PRIORITY JOURNAL; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0032571223     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(98)00071-8     Document Type: Article

References (38)

1. This work was reported in part at the 129th Midwest Meeting of the American Chemical Society, Kansas City, MO, 1994, and the 212th National Meeting of the American Chemical Society, Orlando, FL, August 1996.
2. This work was reported in part at the 129th Midwest Meeting of the American Chemical Society, Kansas City, MO, 1994, and the 212th National Meeting of the American Chemical Society, Orlando, FL, August 1996.
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11. For reviews see: Kagan, H. B. In Asymmetric Synthesis; Morrison, J. D., Ed.; Academic Press: New York, 1985, Chapter 1; Nógrádi, M. Stereoselective Synthesis; VCH Publishers: New York, 1987; Davies, S. G. Organotransition Metal Chemistry Applications to Organic Synthesis; Pergamon Press: Oxford, 1982; Parshall, G. A.; Ittel, S. D. Homogeneous Catalysis; 2nd Edn, John Wiley & Sons: New York, 1992. Knowles, W. S. Acc. Chem. Res. 1983, 16, 106-112; J. Chem. Educ. 1986, 63, 222; Halpern, J. Science 1982, 217, 401-407.
12. For reviews see: Kagan, H. B. In Asymmetric Synthesis; Morrison, J. D., Ed.; Academic Press: New York, 1985, Chapter 1; Nógrádi, M. Stereoselective Synthesis; VCH Publishers: New York, 1987; Davies, S. G. Organotransition Metal Chemistry Applications to Organic Synthesis; Pergamon Press: Oxford, 1982; Parshall, G. A.; Ittel, S. D. Homogeneous Catalysis; 2nd Edn, John Wiley & Sons: New York, 1992. Knowles, W. S. Acc. Chem. Res. 1983, 16, 106-112; J. Chem. Educ. 1986, 63, 222; Halpern, J. Science 1982, 217, 401-407.
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25. The synthesis and chemistry of the amino-phosphines is reported in the following paper: Tetrahedron: Asymmetry 1998, 9, 937-948.
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29. Racemic cyclohexanediamine is available from Aldrich Chemical company (250 mL/$103.80) and is resolved with tartaric acid; Asperger, R. G.; Liu, C. F. Inorg. Chem. 1965, 4, 1492-1494; Denmark, S. E.; Stadler, H.; Dorow, R. L.; Kim, J. J. Org. Chem. 1991, 56, 5063-5079; Mangeney, P.; Tejero, T.; Alexakis, A.; Grosjean, F.; Normant, J. Synthesis 1988, 255-257; Larrow, J. F.; Jacobsen, E. N.; Gao, Y.; Hong, Y.; Nie, X.; Zepp, C. M. J. Org. Chem. 1994, 59, 1939-1942.
30. Racemic cyclohexanediamine is available from Aldrich Chemical company (250 mL/$103.80) and is resolved with tartaric acid; Asperger, R. G.; Liu, C. F. Inorg. Chem. 1965, 4, 1492-1494; Denmark, S. E.; Stadler, H.; Dorow, R. L.; Kim, J. J. Org. Chem. 1991, 56, 5063-5079; Mangeney, P.; Tejero, T.; Alexakis, A.; Grosjean, F.; Normant, J. Synthesis 1988, 255-257; Larrow, J. F.; Jacobsen, E. N.; Gao, Y.; Hong, Y.; Nie, X.; Zepp, C. M. J. Org. Chem. 1994, 59, 1939-1942.
31. Racemic cyclohexanediamine is available from Aldrich Chemical company (250 mL/$103.80) and is resolved with tartaric acid; Asperger, R. G.; Liu, C. F. Inorg. Chem. 1965, 4, 1492-1494; Denmark, S. E.; Stadler, H.; Dorow, R. L.; Kim, J. J. Org. Chem. 1991, 56, 5063-5079; Mangeney, P.; Tejero, T.; Alexakis, A.; Grosjean, F.; Normant, J. Synthesis 1988, 255-257; Larrow, J. F.; Jacobsen, E. N.; Gao, Y.; Hong, Y.; Nie, X.; Zepp, C. M. J. Org. Chem. 1994, 59, 1939-1942.
32. A similar instability is seen in the N-Me derivative, see Ref 7(a).
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