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Personal communication with John \V. Daly and T. Spande, NIDDK (National Institutes of Health). The GC-FTIR data was obtained on an HP-5 fused silica-bonded capillary column (25 m × 0.32 mm). The chiral GC analysis was performed using a Supelco Beta-DEX 120 fused silica capillary column (30 m, 0.25 mm i.d., 0.25 μm film thickness)
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Personal communication with John \V. Daly and T. Spande, NIDDK (National Institutes of Health). The GC-FTIR data was obtained on an HP-5 fused silica-bonded capillary column (25 m × 0.32 mm). The chiral GC analysis was performed using a Supelco Beta-DEX 120 fused silica capillary column (30 m, 0.25 mm i.d., 0.25 μm film thickness).
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36
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20644467542
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note
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In a separate experiment, chromatography of the imine 28 was attempted (2:1 ethyl acetate/hexane followed by methanol/chlorofonn). Although a pure sample of 28 could not be obtained due to its decomposition, an impure byproduct was isolated in 15% yield that had spectral data consistent with an aziridine. This material exhibited the same multiplet at δ 5.2 ppm as that observed in the sealed tube experiments.
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37
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0003688714
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