Silver ion-mediated coupling of 4-bromo-2,6-di-tert-butylcycohexa-2,5- dienone with phenols

Journal of Organic Chemistry

Volumn 63, Issue 26, 1998, Pages 10031-10034

  Omura, Kanji ^a  

^a KOSHIEN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

2 CYCLOHEXENONE DERIVATIVE; 4 BROMO 2,6 DI TERT BUTYLCYCLOHEXA 2,5 DIENONE; PHENOL DERIVATIVE; SILVER; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; HYDROGENATION; SYNTHESIS;

EID: 0032567396     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo981356k     Document Type: Article

References (19)

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2. 1H NMR spectrum of the crude reaction product suggested that it contained significant amounts of 4-(trifluoroacetoxy)-2,6-di-tert-butylphenol and its tautomer, 4- (trifluoroacetoxy)-2,6-di-tert-butylcyclohexa-2,5-dienone. Cf. ref 1.
3. The reaction with 2 molar equiv (in place of 4 mol equiv) of 3 gave 4 in 49% yield.
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