Free radical chlorination of alkanes in supercritical carbon dioxide: The chlorine atom cage effect as a probe for enhanced cage effects in supercritical fluid solvents

Journal of the American Chemical Society

Volumn 120, Issue 46, 1998, Pages 11839-11844

  Fletcher, Beth ^a   Suleman, N Kamrudin ^a   Tanko, J M ^a  

^a VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE DERIVATIVE; CARBON DIOXIDE; FREE RADICAL; SOLVENT;

ARTICLE; CHLORINATION; EXPERIMENT; GAS; SUPERCRITICAL FLUID EXTRACTION; VISCOSITY;

EID: 0032567141     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982289e     Document Type: Article

References (5)

1. McHugh, M.; Krukonis, V. Supercritical Fluid Extraction. Principles and Practice; Butterworth: Boston, MA, 1986; pp 1 -11.
2. Johnston, K. P. In Supercritical Fluid Science and Technology, Johnston, K. P., Penninger, J. M. L., Eds.; American Chemical Society: Washington, DC, 1989; pp 1-12.
3. Subramantam, B.; McHugh, M. A. Ind. Eng. Chem. Process Des. Dev. 1988, 25, 1-12.
4. Wu, B. C.; Paspek, S. C; Klein, M. T.; LaMarca, C. In Supercritical Fluid Technology: Reviews in Modern Theory and Applications; Bruno, T. J., Ely, J. F., Eds.; CRC Press: Boca Raton, FL, 1991; pp 511-524.
5. Savage, P. E.; Gopalan, S.; Mizan, T. I.; Martino, C. J.; Brock, E. E. AICHE J. 1995, 41, 1723-1778.