In situ generated, polymer-supported organotin hydrides as clean reducing agents

Tetrahedron Letters

Volumn 39, Issue 26, 1998, Pages 4663-4666

  Dumartin, Gilles ^a   Pourcel, Magali ^a   Delmond, Bernard ^a   Donard, Olivier ^b   Pereyre, Michel ^a  

^a UNIVERSITÉ DE BORDEAUX   (France)

^b UNIVERSITÉ DE PAU ET DES PAYS DE L'ADOUR   (France)

Author keywords

[No Author keywords available]

Indexed keywords

HALIDE; ORGANOTIN COMPOUND; POLYMER; TRIBUTYLTIN CHLORIDE;

ARTICLE; CHEMICAL BINDING; CHEMICAL REACTION KINETICS; METAL BINDING; ORGANIC CHEMISTRY; POLLUTION; REACTION ANALYSIS; REDUCTION;

EID: 0032565936     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00873-9     Document Type: Article

References (20)

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18. 2I, 0.17g (4.5 mmoles) of sodium borohydride, 0.03g (0.18 mmole) of AIBN and 20 ml of ethanol was added a solution of 1-bromoadamantane (0.387g, 1.8 mole) and dodecane as internal standard (0.153g, 0.90 mmole) in 10 ml of ethanol. The mixture was slowly stirred at 65°C for 12 hours. After filtration the liquid phase was washed with water and extracted with pentane. The organic layer was dried and filtered (diameter of filter: 0.45 μm). The yield of adamantane was evaluated by GC analysis.
19. 11 The polymer was found to contain 0.75 milliequivalent SnCl per gram (% Sn : 8.77, % Cl : 2.84).
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