The application of Ir-complexes of trans-2,5-dialkylpyrrolidinyl- benzyldiphenylphosphines to the enantioselective reduction of imines

Tetrahedron Asymmetry

Volumn 9, Issue 24, 1998, Pages 4307-4312

  Cahill, John P ^a   Lightfoot, Andrew P ^b   Goddard, Richard ^b   Rust, Jörg ^b   Guiry, Patrick J ^a  

^a UNIVERSITY COLLEGE DUBLIN   (Ireland)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

IMINE; IRIDIUM COMPLEX; PHOSPHINE DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CRYSTAL STRUCTURE; PRIORITY JOURNAL; REDUCTION; STEREOCHEMISTRY; SYNTHESIS;

EID: 0032564687     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(98)00451-0     Document Type: Article

References (33)

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14. Ir diphosphine complexes: (a) BDDP: Spindler, F.; Pugin, B.; Blaser, H.-U. Angew. Chem., Int. Ed. Engl. 1990, 29, 558. (b) Diop: Morimoto, M.; Nakajima, N.; Achiwa, K. Chem Pharm. Bull. 1994, 42, 1951. (c) Xyliphos (industrial process): Spindler, F.; Pugin, B.; Jalett, H. P.; Buser, H. P.; Pittelkow, U.; Blaser, H.-U. Chem. Ind. (Dekker) 1996, 68, 153. (d) BINAP: Tani, K.; Onouchi, J.; Yamagata, Y.; Kataoka, Y. Chem. Lett. 1995, 955. (e) Zhu, G.; Zhang, X. Tetrahedron: Asymmetry 1998, 9, 2415.
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20. Allylic substitutions: (a) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron: Asymmetry 1994, 5, 573. (b) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. Heck: Loiseleur, O.; Meier. P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. Hydrosilylations: Newman, L. M.; Williams, J. M. J.; McCague, R.; Potter, G. A. Tetrahedron: Asymmetry 1996, 6, 1597. Transfer hydrogenation: Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Diels-Alder: Sagasser, I.; Helmchen, G. Tetrahedron Lett. 1998, 39, 261. Olefin hydrogenation: Lightfoot, A.; Schnider, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1998, 37, 2897.
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22. Allylic substitutions: (a) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron: Asymmetry 1994, 5, 573. (b) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. Heck: Loiseleur, O.; Meier. P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. Hydrosilylations: Newman, L. M.; Williams, J. M. J.; McCague, R.; Potter, G. A. Tetrahedron: Asymmetry 1996, 6, 1597. Transfer hydrogenation: Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Diels-Alder: Sagasser, I.; Helmchen, G. Tetrahedron Lett. 1998, 39, 261. Olefin hydrogenation: Lightfoot, A.; Schnider, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1998, 37, 2897.
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24. Allylic substitutions: (a) von Matt, P.; Loiseleur, O.; Koch, G.; Pfaltz, A.; Lefeber, C.; Feucht, T.; Helmchen, G. Tetrahedron: Asymmetry 1994, 5, 573. (b) Lloyd-Jones, G. C.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1995, 34, 462. Heck: Loiseleur, O.; Meier. P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 200. Hydrosilylations: Newman, L. M.; Williams, J. M. J.; McCague, R.; Potter, G. A. Tetrahedron: Asymmetry 1996, 6, 1597. Transfer hydrogenation: Langer, T.; Helmchen, G. Tetrahedron Lett. 1996, 37, 1381. Diels-Alder: Sagasser, I.; Helmchen, G. Tetrahedron Lett. 1998, 39, 261. Olefin hydrogenation: Lightfoot, A.; Schnider, P.; Pfaltz, A. Angew. Chem., Int. Ed. Engl. 1998, 37, 2897.
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30. 6, 10%), 590 (100).
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