Influence of carbon group substituents on bond shift and electrochemical reduction of cyclooctatetraene

Journal of the American Chemical Society

Volumn 120, Issue 15, 1998, Pages 3671-3674

  Staley, Stuart W ^a   Grimm, Russell A ^a   Sablosky, Rachel A ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE DERIVATIVE; GERMANIUM; SILICON; TIN;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BINDING; ELECTROCHEMISTRY; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; OXIDATION REDUCTION POTENTIAL;

EID: 0032557211     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963359p     Document Type: Article

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39. .-. However, even if an electron is added to an antisymmetric orbital, the delocalization onto the substituent of the π electrons in the corresponding symmetric orbital will increase due to the increase in its π orbital energy illustrated in Figure 2. It is this delocalization that is addressed by our model.