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Volumn 120, Issue 15, 1998, Pages 3541-3548

Recombinant baker's yeast as a whole-cell catalyst for asymmetric Baeyer - Villiger oxidations

Author keywords

[No Author keywords available]

Indexed keywords

UNSPECIFIC MONOOXYGENASE;

EID: 0032557201     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja972942i     Document Type: Article
Times cited : (130)

References (89)
  • 19
    • 7144244562 scopus 로고    scopus 로고
    • in press
    • For a review of Baeyer-Villiger reactions catalyzed by cyclohexanone monooxygenase, see Stewart, J. D. Curr. Org. Chem. 1998, in press.
    • (1998) Curr. Org. Chem.
    • Stewart, J.D.1
  • 23
    • 7144246339 scopus 로고    scopus 로고
    • note
    • Plasmids used: M949 (David Stillman, University of Utah), ARS-CEN origin of replication, GAL promoter; pYES2 (Invitrogen, Inc.), 2 micron circle origin of replication, GAL promoter; pG-3 (Kieth Yamamoto, University of California, San Francisco), 2 micron circle origin of replication, GPD promoter.
  • 24
    • 7144230606 scopus 로고    scopus 로고
    • S. cerevisiae 15C: MATα, leu2, ura3-52, Δtrp1, his4-80, pep4-3
    • S. cerevisiae 15C: MATα, leu2, ura3-52, Δtrp1, his4-80, pep4-3.
  • 38
    • 7144229567 scopus 로고    scopus 로고
    • Details of this synthesis will be published elsewhere
    • Details of this synthesis will be published elsewhere.
  • 49
    • 7144237106 scopus 로고    scopus 로고
    • note
    • 1/(1 - E) where c = fractional conversion, ee(S) = enantiomeric excess of the remaining substrate, and E = enantioselectivity value.
  • 50
    • 7144231675 scopus 로고    scopus 로고
    • note
    • Note that there is a change in numbering priority for ketones 7d and 7f which inverts the (R/S) nomenclature.
  • 63
    • 7144225763 scopus 로고    scopus 로고
    • Both enantiomers of pulegone are commercially available from Fluka Chemical Corp.
    • Both enantiomers of pulegone are commercially available from Fluka Chemical Corp.
  • 71
    • 7144233531 scopus 로고    scopus 로고
    • note
    • - or OH.
  • 72
  • 74
    • 7144239811 scopus 로고    scopus 로고
    • note
    • The shape of the enzyme binding pocket in this diagram is only a schematic and does not accurately reproduce the cubic space model of ref 67.
  • 75
    • 7144231673 scopus 로고    scopus 로고
    • note
    • Details of this derivation are given in the Supporting Information for this article.
  • 76
    • 7144234615 scopus 로고    scopus 로고
    • -[ΔGs,eq,ax/(RT)]
    • -[ΔGs,eq,ax/(RT)].
  • 89
    • 7144248428 scopus 로고    scopus 로고
    • note
    • Although the high-resolution mass spectra were obtained under electron-impact conditions, only the M + H ions were observed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.