Isotope effect in oxidative nucleophilic substitution of hydrogen in nitroarenes

Tetrahedron Letters

Volumn 39, Issue 21, 1998, Pages 3575-3576

  Ma̧kosza, Mieczysław ^a   Staliński, Krzysztof ^a  

^a INSTITUTE OF ORGANIC CHEMISTRY   (Poland)

Author keywords

Carbonions; Nucleophilic aromatic substitution; Oxidation; Reaction mechanism

Indexed keywords

AMMONIA; AROMATIC NITRO COMPOUND; DEUTERIUM; HYDROGEN; ISOTOPE; NITRILE; NITROBENZENE DERIVATIVE;

ARTICLE; BINDING COMPETITION; HYDROGEN BOND; OXIDATION; REACTION ANALYSIS;

EID: 0032555014     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00552-8     Document Type: Article

References (6)

1. Ma̧kosza M. Staliński K, Klȩpka C. Chem. Commun. 1996:837-838.
2. Ma̧kosza M, Staliński K. Eur. J. Chem. 1997;3:2025-2031.
3. Terrier F. Nucleophilic Aromatic Displacement. Weiheim: Verlag Chemie, 1991.
4. Chupakhin ON, Charushin VN, van der Plas HC. Nucleophilic Aromatic Substitution of Hydrogen. San Diego: Academic Press, 1994.
5. 2 and purified by column chromatography on silica gel, yield 64 %.
6. 2 (D=2H): C 70.29, H 4.68, N 10.93; found: C 70.30, H 4.42, N 10.85.