Model correlations for ozone, reactive nitrogen, and peroxides for Nashville in comparison with measurements: Implications for O3-NOx-hydrocarbon chemistry

Journal of Geophysical Research Atmospheres

Volumn 103, Issue D17, 1998, Pages 22629-22644

  Sillman, Sanford ^a   He, Dongyang ^a   Pippin, Margaret R ^a   Daum, Peter H ^b   Imre, Daniel G ^b   Kleinman, Lawrence I ^b   Lee, Jai Hoon ^b   Weinstein Lloyd, Judith ^c  

^a UNIVERSITY OF MICHIGAN   (United States)

^b BROOKHAVEN NATIONAL LABORATORY   (United States)

^c STATE UNIVERSITY OF NEW YORK   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC PLUME; COMPARATIVE STUDY; MODELING; NITROGEN OXIDES; OZONE; VOLATILE ORGANIC COMPOUND;

NASHVILLE; TENNESSEE; UNITED STATES;

EID: 0032552703     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/98JD00349     Document Type: Article

References (58)

1. Andronache, C., W. L. Chameides, M. O. Rodgers, J. E. Martinez, P. Zimmerman, and J. Greenberg. Vertical distribution of isoprene in the lower boundary layer of the rural and urban southern United States, J. Geophys. Res., 99, 16,989-17,000, 1994.
2. Benjamin S. G., K. J. Brundage and L. L. Morone, Implementation of the Rapid Update Cycle, I. Analysis/model description, NOAA/NWS Tech. Procedures Bull. Ser. 416, Natl. Oceanic and Atmos. Admin., Silver Spring, Md., 1994.
3. Bollinger, M. J., R. E. Sievers, D. W. Fahey, and F. C. Fehsenfeld, Conversion of nitrogen dioxide, nitric acid and n-propyl nilrate to nitric oxide by gold-catalyzed reduction with carbon monoxide, Anal. Chem., 55, 1980-1986, 1983.
4. Chin, M., D. J. Jacob, J. W. Munger, D. D. Parrish, and B. G. Doddridge, Relationship of ozone and carbon monoxide over North America, J. Geophys. Res., 99, 14,565-14,573, 1994.
5. Daum, P. H., L. I. Kleinman, L. Newman, W. T. Luke, J. Weinstein-Lloyd, C. M. Berkowitz, and K. M. Busness, Chemical and physical properties of anthropogenic pollutants transported over the North Atlantic during NARE, J. Geophys. Res., 101, 29,029-29,042, 1996.
6. DeMore, W. B., S. P. Sander, D. M. Golden, R. F. Hampson, M. J. Kurylo, C. J. Howard, A. R. Ravishankara, C. E. Kolb, and M. J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, JPI. Publ., 94-26, 1994.
7. Enders, G., et al., Biosphere/atmosphere interactions: Integrated research in a European coniferous forest ecosystem, Atmos. Environ., Part A, 26A, 171-189, 1992.
8. Environmental Protection Agency (EPA), The 1985 NAPAP emissions inventory (version 2): Development of the annual data and modelers' tapes, EPA-600/7-89-012a, Environ. Prot. Agency, Research Triangle Park, N. C., 1989.
9. Environmental Protection Agency (EPA), Regional interim emission inventories (1987-1991), vols. 1 and 2, EPA-454/R93-021a and b, Environ. Prot. Agency, Research Triangle Park, N. C., 1993.
10. Flowers, E. C., R. A. McCormick, and K. R. Kurfis, Atmospheric turbidity over the United States, 1961-1966, J. Appl. Meteorol., 8, 955-962, 1969.
11. x, and NMOG in California's south coast air basin, J. Air Waste Manage. Assoc., 42, 264-276, 1992.
12. Gäb, S., W. Turner, S. Wolff, K. Becker, L. Rupert, and K. Brockman, Formation of hydroxyalkyl hydroperoxides on ozonolysis in water and air, Atmos. Environ., 29, 2401-2407, 1995.
13. Gao, D., W. R. Stockwell, and J. B. Milford, Global uncertainty analysis of a regional-scale gas phase chemical mechanism, J. Geophys. Res., 101, 9071-9078, 1996.
14. Geron, C. D., A. B. Guenther, and T. E. Pierce, An improved model for estimating emissions of volatile organic compounds from forests in the eastern United States, J. Geophys. Res., 99, 12,773-12,791, 1994.
15. Hall, B. D., and C. S. Claiborn, Measurements of the dry deposition of peroxides to a Canadian boreal forest, J. Geophys. Res., 102, 29,343-29,353, 1997.
16. Heffter, J. L., Air resources laboratories atmospheric transport and dispersion model, NOAA Tech. Memo, ERL ARL-81, 24 pp., Natl. Oceanic and Atmos. Admin., Silver Springs, Md., 1980.
17. Hewitt, C. N., and G. L. Kok, Formation and occurrence of organic peroxides in the troposphere: Laboratory and field observations, J. Atmos. Chem. 12, 181-194, 1991.
18. x at Harvard Forest, Massachusetts, J. Geophys. Res., 101, 12,659-12,666, 1996.
19. Hubler, G., R. Alvarez, P. Daum, R. Dennis, N. Gillani, L. Kleinman, W. Like, J. Meagher, D. Rider, M. Trainer, and R. Valente, An overview of the airborne activities during the 1995 summer intensive of the Southern Oxidants Study in Nashville, Tennessee, J. Geophys. Res., this issue.
20. Jacob, D. J., and S. C. Wofsy, Photochemistry of biogenic emissions over the Amazon forest, J. Geophys. Res., 93, 1477-1486, 1988.
21. Jacob, D. J., J. A. Logan, G. M. Gardner, R. M. Yevich, C. M. Spivakowsky, S. C. Wofsy, S. Sillman, and M. J. Prather, Factors regulating ozone over the United States and its export to the global atmosphere, J. Geophys. Res., 98, 14,817-14,827, 1993.
22. x- to hydrocarbon-limited ozone production over the eastern United States in September, J. Geophys. Res., 100, 9315-9324, 1995.
23. Kirchner, F., and W. R. Stockwell, The effect of peroxy radical reactions on the predicted concentrations of ozone, nitrogenous compounds, and radicals, J. Geophys. Res., 101, 21,007-21,023, 1996.
24. x tropospheric photochemistry, J. Geophys. Res., 99, 16,831-16,838, 1994.
25. Kleinman, L. I., Y-N. Lee, S. R. Springston, L. Nunnermacker, X. Zhou, R. Brown, K. Hallock, P. Klotz, D. Leahy, J. H. Lee, and L. Newman, Ozone formation at a rural site in the southeastern United States, J. Geophys. Res., 99, 3469-3482, 1994.
26. Kleinman, L. I., P. H. Daum, J. H. Lee, Y-N. Lee, L. J. Nunnermacker, S. R. Springston, L. Newman, J. Weinstein-Lloyd, and S. Sillman, Dependence of ozone production on NO and hydrocarbons in the troposphere, Geophys. Res. Lett., 24, 2299-2302, 1997
27. Kumar, N., and A. Russell, Development of a computationally efficient, reactive subgrid-scale plume model and the impact on the northeastern United States using increasing levels of chemical detail, J. Geophys. Res., 101, 16,737-16,744, 1996.
28. Lee, J. H., I. N. Tang, and J. B. Weinstein-Lloyd, Nonenzymatic method for the determination of hydrogen peroxide in atmospheric samples. Anal. Chem., 62, 2381-2384, 1990.
29. Lee, J. H., D. F. Leehy, I. N. Tang, and L. Newman, Measurement and speciation of gas phase peroxides in the atmosphere, J. Geophys. Res., 98, 2911-2915, 1993.
30. Lee, J. H., I. N. Tang, J. B. Weinstein-Lloyd, and E. B. Halper, An improved nonenzymatic method for the determination of gas-phase peroxides, Environ. Sci. Technol., 28, 1180-1185, 1994.
31. Lin, X., M. Trainer, and S. C. Liu, On the nonlinearity of tropospheric ozone, J. Geophys Res., 93, 15,879-15,888, 1988.
32. Liu, S. C., M. Trainer, F. C. Fehsenfeld, D. D. Parrish, E. J. Williams, D. W. Fahey, G. Hubler, and P. C. Murphy, Ozone production in the rural troposphere and the implications for regional and global ozone distributions, J. Geophys. Res., 92, 4191-4207, 1987.
33. Lurmann, F. W., A. C. Lloyd, and R. A. Atkinson, Chemical mechanism for use in long-range transport/acid deposition computer modeling, J. Geophys. Res., 91, 10,905-10,936, 1986.
34. Madronich, S., Photodissociation in the atmosphere, 1, Actinic flux and the effect of ground reflections and clouds, J. Geophys. Res., 92, 9740-9752, 1987.
35. Marsik, F. J., K. W. Fischer, T. D. McDonald, and P. J. Samson, Comparison of methods for estimating mixing heights used during the 1992 Atlanta field inteasive, J. Appl. Meteorol., 45, 8, 1995.
36. McNider, R. T., W. B. Norris, A. J. Song, R. L. Clymer, S. Gupta, R. M. Banta, R. J. Zamora, A. B. White, and M. Trainer, Meteorological conditions during the 1995 summer intensive of the Southern Oxidants Study in Nashville, Tennessee, J. Geophys. Res., this issue.
37. Meagher, J. F., E. B. Cowling, F. C. Fehsenfeld, and W. J. Parkh, Ozone formation and transport in the southeastern Uniled States: An overview of the 1995 summer intensive of the Southern Oxidants Study in Nashville, Tennessee, J. Geophys. Res., this issue.
38. x and hydrocarbons, J. Geophys. Res., 99, 3533-3542, 1994.
39. 3 and NO relationships at a rural site, J. Geophys. Res., 99, 14,557-14,563, 1994.
40. Parrish, D. D., J. S. Holloway, M. Trainer, P. C. Murphy, G. L. Forbes. and F. C. Fehsenfeld, Export of North American ozone pollution to the North Atlantic Ocean, Science, 259, 1436-1439, 1993.
41. Paulson, S. E., and J. H. Seinfeld, Development and evaluation of a photooxidation mechanism for isoprene, J. Geophys. Res., 97, 20,703-20,715, 1992.
42. Prather, M. J., Numerical advcection by conservation of second-order moment, J. Geophys Res., 91, 6671-6681, 1986.
43. Ryerson, T. B., M. P. Buhr, G. Frost, P. D. Goldan, J. S. Holloway, G. Hubler, B. T. Jobson, W. C. Kuster, S. A. McKeen, D. D. Parrish, J. M. Roberts, D. T. Sueper, M. Trainer, J. Williams, and F. C. Fehsenfeld, Emissions lifetimes and ozone formation in power plant plumes, J. Geophys. Res., this issue.
44. x-VOC sensitivity in urban locations, J. Geophys. Res., 100, 14,175-14,188, 1995.
45. Sillman, S., J. A. Logan, and S. C. Wofsy, A regional-scale model for ozone in the United States with subgrid representation of urban and power plant plumes, J. Geophys. Res., 95, 5731-5748, 1990a.
46. Sillman, S., J. A. Logan, and S. C. Wofsy, The sensitivity of ozone to nitrogen oxides and hydrocarbons in regional ozone episodes, J. Geophys. Res., 95, 1837-1851, 1990b.
47. Sillman, S., P. J. Samson, and J. M. Masters, Ozone production in urban plumes transported over water: Photochemical model and case studies in the northeastern and Midwestern United States, J. Geophys. Res., 98, 12,687-12,699, 1993.
48. Sillman, S., et al., Photochemistry of ozone formation in Atlanta, GA: Models and measurements, Atmos. Environ., 29, 3055-3066, 1995.
49. x-hydrocarbon sensitivity: Case studies from Atlanta, New York and Los Angeles, J. Air Waste Manage. Assoc., 47, 1030-1040, 1997.
50. Simonaitis, R., K. J. Olszyna, and J.F. Meagher, Production of hydrogen peroxide and organic peroxides in the gas phase reactions of ozone with natural alkenes, Geophys. Res. Lett., 18, 9-12, 1991.
51. Singh, H. B., D. O'Hara, D. Herlth, J. D. Bradshaw, S. T. Sandholm, G. L. Gregory, W. Sachse, D. R. Blake, P. J. Crutzen, and M. Kanakidou, Atmospheric measurements of peroxyacetyl nitrate and other organic nitrates at high latitudes: Possible sources and sinks, J. Geophys. Res., 97, 16,511-16,522, 1992.
52. Smolarkiewicz, P. K., A simple positive definite advection scheme with small implicit diffusion, Mon. Weather Rev., 111, 479-486, 1983.
53. Staffelbach, T., et al., Photochemical oxidant formation over southern Switzerland, I. Results from summer, 1994, J. Geophys. Res., 102, 23,345-23,362, 1997a.
54. Staffelbach, T., A. Neftel, and L. W. Horowitz, Photochemical oxidant formation over southern Switzerland, 2, Model results, J. Geophys. Res., 102, 23,363-23,373, 1997b.
55. Stockwell, W. R., F. Kirchner, and M. Kuhn, A new mechanism for regional atmospheric chemistry modeling, J. Geophys. Res., 102, 25,847-25,879, 1997.
56. Trainer, M., et al., Correlation of ozone with NOy in photochemically aged air, J. Geophys. Res., 98, 2917-2926, 1993.
57. Weinstein-Lloyd, J. B., J. H. Lee, P. H. Daum, L. Kleinman, L. J. Nunnermacker, S.R. Springston, and L. Newman, Measurements of peroxides and related species during the 1995 Summer intensive of the Southern Oxidants Study in Nashville, Tennessee, J. Geophys. Res., this issue.
58. Williams, E. J., et al., Intercomparison of ground-based NO measurement techniques, J. Geophys. Res., in press, 1998.