5-hydroxypentane-2,3-dione (Laurencione), a bacterial metabolite of 1- deoxy-D-threo-pentulose

Tetrahedron Letters

Volumn 39, Issue 34, 1998, Pages 6185-6188

  Putra, Surya Rosa ^a   Charon, Lionel ^a   Danielsen, Knut ^a   Pale Grosdemange, Catherine ^a   Lois, Luisa Maria ^b   Campos, Narciso ^b   Boronat, Albert ^b   Rohmer, Michel ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

^b UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLACETONE; GLYCERALDEHYDE; PENTOSE; PYRUVIC ACID; THIAMINE DERIVATIVE; XYLULOSE;

ARTICLE; BACTERIAL METABOLISM; BIOSYNTHESIS; CELL FREE SYSTEM; CHEMICAL LABELING; CHEMICAL REACTION; DERIVATIZATION; ESCHERICHIA COLI; KLEBSIELLA; NONHUMAN; REACTION ANALYSIS;

EID: 0032552065     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)01301-X     Document Type: Article

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27. 2,3=58Hz).
28. 13C-NMR: δ (ppm) = 25.2 (C-1).
29. 13C-NMR: δ (ppm) = 190.9 (C-2),
30. 13C-NMR: δ (ppm) = 125.0 (C-4).
31. 3COO-), 25.2 (C-1), 124.8 (C-4), 147.0 (C-3), 190.1 (C-2); signals of acetoxy carbonyl groups are overlapping with those of deoxyxylulose triacetate.
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