메뉴 건너뛰기




Volumn 562, Issue 2, 1998, Pages 217-227

π-Bonding in the star-type compound [{(CO)5Cr}3Sn]2-. How to rationalize its electronic absorption spectrum and its out-of-range 119Sn-NMR shift of δ=3924

Author keywords

119Sn NMR; Chromium tin system; Crystal structure; Tin; Trigonal planar coordination

Indexed keywords


EID: 0032551465     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)00542-7     Document Type: Article
Times cited : (12)

References (90)
  • 2
    • 33748240837 scopus 로고
    • and cited literature.
    • (a) T. Tsumuraya, S.A. Batcheller, S. Masamune, Angew. Chem. 103 (1991) 916; Angew. Chem. Int. Ed. Engl. 30 (1991) 902, and cited literature.
    • (1991) Angew. Chem. Int. Ed. Engl. , vol.30 , pp. 902
  • 3
    • 84984357835 scopus 로고
    • (b) and cited literature.
    • (b) M. Driess, Chem. unserer Zeit 27 (1993) 141, and cited literature.
    • (1993) Chem. Unserer Zeit , vol.27 , pp. 141
    • Driess, M.1
  • 4
    • 0000238248 scopus 로고    scopus 로고
    • (c)
    • (c) M. Driess, H. Grützmacher, Angew. Chem. 108 (1996) 900; Angew. Chem. Int. Ed. Engl. 35 (1996) 828, and cited literature.
    • (1996) Angew. Chem. , vol.108 , pp. 900
    • Driess, M.1    Grützmacher, H.2
  • 5
    • 33748880663 scopus 로고    scopus 로고
    • and cited literature
    • (c) M. Driess, H. Grützmacher, Angew. Chem. 108 (1996) 900; Angew. Chem. Int. Ed. Engl. 35 (1996) 828, and cited literature.
    • (1996) Angew. Chem. Int. Ed. Engl. , vol.35 , pp. 828
  • 8
    • 0002296105 scopus 로고
    • (c)
    • (c) W.A. Herrmann, Angew. Chem. 98 (1986) 57; Angew. Chem. Int. Ed. Engl. 25 (1986) 56, and cited literature.
    • (1986) Angew. Chem. , vol.98 , pp. 57
    • Herrmann, W.A.1
  • 9
    • 0039821434 scopus 로고
    • and cited literature.
    • (c) W.A. Herrmann, Angew. Chem. 98 (1986) 57; Angew. Chem. Int. Ed. Engl. 25 (1986) 56, and cited literature.
    • (1986) Angew. Chem. Int. Ed. Engl. , vol.25 , pp. 56
  • 12
    • 0000932484 scopus 로고
    • (f)
    • (f) K. Dehnicke, J. Strähle, Angew. Chem. 104 (1992) 978; Angew. Chem. Int. Ed. Engl. 31 (1992) 955, and cited literature.
    • (1992) Angew. Chem. , vol.104 , pp. 978
    • Dehnicke, K.1    Strähle, J.2
  • 13
    • 33751140722 scopus 로고
    • and cited literature.
    • (f) K. Dehnicke, J. Strähle, Angew. Chem. 104 (1992) 978; Angew. Chem. Int. Ed. Engl. 31 (1992) 955, and cited literature.
    • (1992) Angew. Chem. Int. Ed. Engl. , vol.31 , pp. 955
  • 15
    • 0031184792 scopus 로고    scopus 로고
    • (h) and cited literature.
    • (h) M. Scheer, Coord. Chem. Rev. 163 (1997) 271, and cited literature.
    • (1997) Coord. Chem. Rev. , vol.163 , pp. 271
    • Scheer, M.1
  • 21
    • 0024819495 scopus 로고
    • E=Pb, (e) F. Ettel, G. Huttner, L. Zsolnai, Angew. Chem. 101 (1989) 1525; Angew. Chem. Int. Ed. Engl. 28 (1989) 1496.
    • (1989) Angew. Chem. Int. Ed. Engl. , vol.28 , pp. 1496
  • 30
    • 84990100725 scopus 로고
    • E=S, (m) H. Braunwarth, G. Huttner, L. Zsolnai, Angew. Chem. 100 (1988) 731; Angew. Chem. Int. Ed. Engl. 27 (1988) 698.
    • (1988) Angew. Chem. Int. Ed. Engl. , vol.27 , pp. 698
  • 37
    • 84982349121 scopus 로고
    • (a) G. Huttner, J. von Seyerl, M. Marsili, H.-G. Schmid, Angew. Chem. 87 (1975) 455; Angew. Chem. Int. Ed. Engl. 14 (1975) 433.
    • (1975) Angew. Chem. Int. Ed. Engl. , vol.14 , pp. 433
  • 39
    • 84982382581 scopus 로고
    • (b) G. Huttner, H.-G. Schmid, Angew. Chem. 87 (1975) 454; Angew. Chem. Int. Ed. Engl. 14 (1975) 434.
    • (1975) Angew. Chem. Int. Ed. Engl. , vol.14 , pp. 434
  • 40
    • 0001483648 scopus 로고
    • (a)
    • (a) R. Hoffmann, Angew. Chem. 94 (1982) 725; Angew. Chem. Int. Ed. Engl. 21 (1982) 711.
    • (1982) Angew. Chem. , vol.94 , pp. 725
    • Hoffmann, R.1
  • 41
    • 84981883937 scopus 로고
    • (a) R. Hoffmann, Angew. Chem. 94 (1982) 725; Angew. Chem. Int. Ed. Engl. 21 (1982) 711.
    • (1982) Angew. Chem. Int. Ed. Engl. , vol.21 , pp. 711
  • 42
    • 0002941662 scopus 로고
    • (b)
    • (b) F.G.A. Stone, Angew. Chem. 96 (1984) 85; Angew. Chem. Int. Ed. Engl. 23 (1984) 89.
    • (1984) Angew. Chem. , vol.96 , pp. 85
    • Stone, F.G.A.1
  • 43
    • 33745341643 scopus 로고
    • (b) F.G.A. Stone, Angew. Chem. 96 (1984) 85; Angew. Chem. Int. Ed. Engl. 23 (1984) 89.
    • (1984) Angew. Chem. Int. Ed. Engl. , vol.23 , pp. 89
  • 53
    • 0003176969 scopus 로고
    • E=Te, (d) H. Herberhold, D. Reiner, D. Neugebauer, Angew. Chem. 95 (1983) 46; Angew. Chem. Int. Ed. Engl. 22 (1983) 59.
    • (1983) Angew. Chem. Int. Ed. Engl. , vol.22 , pp. 59
  • 63
    • 85033545225 scopus 로고    scopus 로고
    • CAChe, Extended Hückel, Release 3.6 with given parameters for Cr and Sn, basis STO-6G. The Sn-Cr distance (266 pm) refer to the structure of 1 while Sn-H, Cr-O and C-O distances are used as set by the program.
    • CAChe, Extended Hückel, Release 3.6 with given parameters for Cr and Sn, basis STO-6G. The Sn-Cr distance (266 pm) refer to the structure of 1 while Sn-H, Cr-O and C-O distances are used as set by the program.
  • 68
    • 0000147888 scopus 로고    scopus 로고
    • nM] fragments are especially prone to the sort of deformation observed for 1:
    • nM] fragments are especially prone to the sort of deformation observed for 1: R.A. Fischer, M.M. Schulte, E. Herdtweck, M.R. Mattner, Inorg. Chem. 36 (1997) 2010.
    • (1997) Inorg. Chem. , vol.36 , pp. 2010
    • Fischer, R.A.1    Schulte, M.M.2    Herdtweck, E.3    Mattner, M.R.4
  • 71
    • 85033511103 scopus 로고    scopus 로고
    • CHAChe, ZINDO 3.6, Parameter: INDO/1, CI-level=14, SCF-type: RHF.
    • CHAChe, ZINDO 3.6, Parameter: INDO/1, CI-level=14, SCF-type: RHF.
  • 72
    • 85033519420 scopus 로고    scopus 로고
    • 5Cr}-P] entities appeared problematic due to the steric congestion of the carbonyl groups.
    • 5Cr}-P] entities appeared problematic due to the steric congestion of the carbonyl groups.
  • 73
    • 0000474420 scopus 로고
    • Semiempirical molecular orbital methods
    • K.B. Lipkowitz, & D.B. Boyd. Weinheim: VCH
    • Zerner M.C. Semiempirical molecular orbital methods. Lipkowitz K.B., Boyd D.B. Reviews in Computational Chemistry. 1991;VCH, Weinheim.
    • (1991) Reviews in Computational Chemistry
    • Zerner, M.C.1
  • 74
    • 85033510264 scopus 로고    scopus 로고
    • It is observed that while after an EHT calculation on the model compound the e′′-orbitals of the π-system are at the position HOMO-3 and HOMO-4 they are at the HOMO and HOMO-1 position after allowing for CI interaction.
    • It is observed that while after an EHT calculation on the model compound the e′′-orbitals of the π-system are at the position HOMO-3 and HOMO-4 they are at the HOMO and HOMO-1 position after allowing for CI interaction.
  • 77
    • 84985627794 scopus 로고
    • (b) W.A. Herrmann, J. Weichmann, U. Kusthardt, A. Schäfer, R. Hörlein, C. Hecht, E. Voss, R. Serrano, Angew. Chem. 95 (1983) 1019; Angew. Chem. Int. Ed. Engl. 22 (1983) 979; Angew. Chem. Suppl. (1983) 1543.
    • (1983) Angew. Chem. Int. Ed. Engl. , vol.22 , pp. 979
  • 78
    • 85033512961 scopus 로고
    • (b) W.A. Herrmann, J. Weichmann, U. Kusthardt, A. Schäfer, R. Hörlein, C. Hecht, E. Voss, R. Serrano, Angew. Chem. 95 (1983) 1019; Angew. Chem. Int. Ed. Engl. 22 (1983) 979; Angew. Chem. Suppl. (1983) 1543.
    • (1983) Angew. Chem. Suppl. , pp. 1543
  • 84
    • 84985598492 scopus 로고
    • O. Scheidsteger, G. Huttner, K. Dehnicke, J. Pebler, Angew. Chem. 97 (1985) 434; Angew. Chem. Int. Ed. Engl. 24 (1985) 428.
    • (1985) Angew. Chem. Int. Ed. Engl. , vol.24 , pp. 428
  • 89
    • 85033515930 scopus 로고    scopus 로고
    • SHELX-86, University of Göttingen, 1986, SHELX-93, University of Göttingen, 1993.
    • G.M. Sheldrick, SHELX-86, University of Göttingen, 1986, SHELX-93, University of Göttingen, 1993.
    • Sheldrick, G.M.1
  • 90
    • 85033504846 scopus 로고    scopus 로고
    • XPMA, University of Heidelberg, 1998;
    • L. Zsolnai, G. Huttner, XPMA, University of Heidelberg, 1998; http://www.rzuser.uni-heidelberg.de/~v54/xpm.html.
    • Zsolnai, L.1    Huttner, G.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.