Measurement of C2-C7 hydrocarbons during the Polar Sunrise Experiment 1994: further evidence for halogen chemistry in the troposphere

Journal of Geophysical Research Atmospheres

Volumn 103, Issue D11, 1998, Pages 13169-13180

  Ariya, P A ^a,c   Jobson, B T ^a,d   Sander, R ^a   Niki, H ^a   Harris, G W ^a   Hopper, J F ^b   Anlauf, K G ^b  

^a YORK UNIVERSITY   (Canada)

^b ENVIRONMENT CANADA   (Canada)

^c MAX PLANCK INSTITUTE FOR CHEMISTRY   (Germany)

^d NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HALOGEN; NONMETHANE HYDROCARBON; TROPOSPHERIC CHEMISTRY;

MONODON;

EID: 0032551075     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/98JD00284     Document Type: Article

References (53)

1. Ariya, P. A., Studies of tropospheric halogen chemistry: Laboratory and field measurements, Ph.D. dissertation, York Univ., North York, Ont., Canada, 1996.
2. Ariya, P. A., V. Catoire, R. Sander, H. Niki, and G. W. Harris, Trichloroethane and tetrachloroethene: Tropospheric probes for Cl and Br-atom reactions during the polar sunrise, Tellus, Ser. B, 49, 583-591, 1997.
3. Ariya, P. A., H. Niki, and G. W. Harris, Rate constants for the Cl-atom reactions of benzene, ethyne and toluene at T = 296 ± 2 K, Int. J. Chem. Kinet., in press, 1998.
4. 8 alkanes at T = 296 ± 2 K, Int. J. Chem. Kinet., 27, 1197-1206, 1995.
5. Atkinson, R., Kinetics and mechanisms of the gas phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions, Chem. Rev., 86, 69-201, 1986.
6. Atkinson, R., D. L. Baulch, R. A. Cox, R. F. Hampson Jr., J. A. Kerr, and J. Troe, Evaluated kinetic and photochemical data for atmospheric chemistry: Supplement IV, J. Phys. Chem. Ref. Data, 21, 1125-1444, 1992.
7. Barnes, I., K. H. Becker, and R. D. Overath, Oxidation of organic sulfur compounds, in The Tropospheric Chemistry of Ozone in The Polar Regions, edited by H. Niki and K. H. Becker, NATO ASI Ser., Ser. I, vol. 17, pp. 371-383, Springer-Verlag, New York, 1993.
8. Barrie, L. A., J. W. Bottenheim, R. C. Schnell, P. J. Crutzen, and R. A. Rasmussen, Ozone destruction and photochemical reactions at polar sunrise in the lower Arctic atmosphere, Nature, 334, 138-141, 1988.
9. Barrie, L. A., R. Staebler, D. Toom, B. Georgi, G. Den Hartog, S. Landsberger, and D. Wu, Arctic aerosol size-segregated chemical observations in relation to ozone depletion during Polar Sunrise Experiment 1992, J. Geophys. Res., 99, 25,439-25,451, 1994.
10. Bottenheim, J. W., L. A. Barrie, E. Atlas, L. E. Heidt, H. Niki, R. A. Rasmussen, and P. B. Shepson, Depletion of lower tropospheric ozone during Arctic spring: The Polar Sunrise Experiment 1988, J. Geophys. Res., 95, 18,555-18,568, 1990.
11. Chameides, W. L., and D. D. Davis, Iodine: Its possible role in tropospheric photochemistry, J. Geophys. Res., 85, 7383-7398, 1980.
12. DeMore, W. B., S. P. Sander, D. M. Golden, R. F. Hampson, M. J. Kurylo, C. J. Howard, A. R. Ravishankara, C. E. Kolb, and M. J. Molina, Chemical kinetic and photochemical data for use in stratospheric modeling, Eval. 11, Jet Propul. Lab., Pasadena, Calif., 1994.
13. Doskey, P. V., and J. S. Gaffney, Non-methane hydrocarbons in the Arctic atmosphere at Barrow, Alaska, Geophys. Res. Lett., 19, 381-384, 1992.
14. Fan, S-M., and D. J. Jacob, Surface ozone depletion in the Arctic spring sustained by bromine reactions on aerosols, Nature, 359, 522-524, 1992.
15. 2 with NaCl and atmospheric implications of NOCl formation, Nature, 306, 676-677, 1983.
16. 2, Nature, 337, 241-244, 1989.
17. Galiba, I., J. M. Tedder, and K. A. Watson, Free-radical substitution in aliphatic compounds, V, The halogenation of 1,1,1-trifluoropentane, J. Chem. Soc. A, 1321-1324, 1964.
18. Hausmann, H., and U. Platt, Spectroscopic measurement of bromine oxide and ozone in the high Arctic during Polar Sunrise Experiment 1992, J. Geophys. Res., 99, 25,399-25,413, 1994.
19. Hoigne, J., H. Bader, W. R. Haag, and J. Staehlin, Rate constants of reactions of ozone with organic compounds in water, Water Res., 19, 993-1004, 1985.
20. Hopper, J. F., and W. Hart, Meteorological overview of the 1992 Polar Sunrise Experiment, J. Geophys. Res., 99, 25,315-25,328, 1994.
21. Hopper, J. F., B. Peters, Y. Yokouchi, H. Niki, B. T. Jobson, P. B. Shepson, and K. Muthuramu, Chemical and meteorological observations at ice camp SWAN during the 1992 Polar Sunrise Experiment, J. Geophys. Res., 99, 25,489-25,498, 1994.
22. Hopper, J. F., L. A. Barrie, A. Sills, W. Hart, A. J. Gallant, and H. Dryfhout, Ozone and meteorology during the 1994 Polar Sunrise Experiment, J. Geophys. Res., 103, 1481-1492, 1998.
23. Hov, O., S. A. Penkett, I. S. A. Isaksen, and A. Semb, Organic gases in the Norwegian Arctic, Geophys. Res. Lett., 11, 425-428, 1984.
24. Jenkin, M. E., A comparative assessment of the role of iodine photochemistry in tropospheric ozone depletion, in The Tropospheric Chemistry of Ozone in the Polar Regions, edited by H. Niki and K. H. Becker, NATO ASI Ser., Ser. I, vol. 17, pp. 405-416, Springer-Verlag, New York, 1993.
25. Jobson, B. T., Seasonal trends of nonmethane hydrocarbons at remote boreal and high Arctic sites in Canada, Ph.D. dissertation, York Univ., North York, Ont., Canada, 1994.
26. 6 hydrocarbons during the Polar Sunrise 1992 Experiment: Evidence for Cl atom and Br atom chemistry, J. Geophys. Res., 99, 25,355-25,368, 1994.
27. Keene, W. C., A. A. P. Pszenny, D. J. Jacob, R. A. Duce, J. N. Galloway, J. J. Schultz-Tokos, H. Sievering, and J. F. Boatman, The geochemical cycle of reactive chlorine through the marine troposphere, Global Biogeochem. Cycles, 4, 407-430, 1990.
28. Kieser, B. N., T. Sideris, H. Niki, J. W. Bottenheim, and W. R. Leaitch, Spring 1989 observations of tropospheric chemistry in the high Arctic, Atmos. Environ., 27, 2979-2988, 1993.
29. McConnell, J. C., and G. S. Henderson, Ozone depletion during polar sunrise, in The Tropospheric Chemistry of Ozone in Polar Regions, edited by H. Niki and K. H. Becker, NATO ASI Ser., Ser. I, vol. 17, Springer-Verlag, New York, 1993.
30. McConnell, J. C., G. S. Henderson, L. Barrie, J. Bottenheim, H. Niki, C. H. Langford, and E. M. J. Templeton, Photochemical bromine production implicated in Arctic boundary-layer ozone depletion, Nature, 355, 150-152, 1992.
31. Mickle, R. E., J. W. Bottenheim, W. R. Leaitch, and W. Evans, Boundary layer ozone depletion during AGASP-II, Atmos. Environ., 23, 2443-2449, 1989.
32. Mozurkewich, M., Mechanisms for the release of halogens from sea-salt particles by free radical reactions, J. Geophys. Res., 100, 14,199-14,207, 1995.
33. Muthuramu, K., P. B. Shepson, J. W. Bottenheim, B. T. Jobson, H. Niki, and K. G. Anlauf, Relationships between organic nitrates and surface ozone destruction during Polar Sunrise Experiment 1992, J. Geophys. Res., 99, 25,369-25,378, 1994.
34. Nangia, P. S., and S. W. Benson, The kinetics of dehydrogenation of propane by iodine vapor and the heat of formation of the isopropyl radical, J. Am. Chem. Soc., 86, 2773-2777, 1964.
35. 2, Int. J. Chem. Kinet., 22, 379-397, 1990.
36. Nicovich, J. M., K. D. Kreutter, and P. Wine, Kinetics of the reactions of Cl and Br with ozone, Int. J. Chem. Kinet., 22, 399-414, 1990.
37. Oltmans, S. J., L. A. Barrie, E. A. Atlas, L. E. Heidt, H. Niki, R. A. Rasmussen, and P. B. Shepson, Seasonal surface ozone and filterable bromine relationships in the high Arctic, Atmos. Environ., 23, 2431-2441, 1989.
38. Pszenny, A. A. P., W. C. Keene, D. J. Jacob, S. Fan, J. R. Maben, M. P. Zewto, M. Springer-Young, and J. N. Galloway, Evidence of inorganic chlorine gases other than hydrogen chloride in maine surface air, Geophys. Res. Lett., 20, 699-702, 1993.
39. 7: Study of the equilibrium R + HBr ↔ RH + Br, J. Am. Chem. Soc., 110, 3092-3099, 1988a.
40. 9 + Br, J. Am. Chem. Soc., 110, 3084-3991, 1988b.
41. Sander, R., and P. J. Crutzen, Model study indicating halogen activation and ozone destruction in polluted air masses transported to the sea, J. Geophys. Res., 101, 9121-9138, 1996.
42. Sander, R., R. Vogt, G. W. Harris, and P. J. Crutzen, Modeling the chemistry of ozone, halogen compounds and hydrocarbons during Arctic spring, Tellus, Ser. B, 49, 522-532, 1997.
43. Schroeder, W. H., and P. Urone, Formation of nitrosyl chloride from sea particles in air, Environ. Sci. Technol., 8, 756-758, 1974.
44. Singh, H. B., et al., Low ozone in the marine boundary layer of the tropical Pacific Ocean: Photochemical loss, chlorine atoms, and entrainment, J. Geophys. Res., 101, 1907-1917, 1996a.
45. Singh, H. B., A. N. Thakur, and Y. E. Chen, Tetrachloroethylene as an indicator of low Cl atom concentrations in the troposphere, Geophys. Res. Lett., 23, 1529-1532, 1996b.
46. Solberg, S., O. Hermansen, E. Joranger, N. Schmidtbauer, F. Strodel, and O. Hov, Tropospheric ozone depletion in the Arctic during spring: Measurements on the Zeppelin Mountain on Spitsbergen, NILU Rep. OR 27/94, Norw. Inst. for Air Res., Oslo, 1994.
47. Solberg, S., N. Scmidbauer, A. Semb, F. Strodal, and O. Hov, Boundary layer ozone depletion as seen in the Norwegian Arctic in spring, J. Atmos. Chem., 23, 301-332, 1996.
48. Solomon, S., R. R. Garcia, and A. R. Ravishankara, On the role of iodine in ozone depletion, J. Geophys. Res., 99, 20,491-20,499, 1994.
49. Staehlin, J., and J. Hoigne, Decomposition of ozone in water: Rate of initiation by hydroxide ions and hydrogen peroxide, Environ. Sci. Technol., 16, 676-681, 1982.
50. Warneck, P., Chemistry of the Natural Atmosphere, Int. Geophys. Ser., vol. 41, Academic, San Diego, Calif., 1988.
51. Wingenter, O. W., M. K. Kubo, N. J. Blake, T. W. Smith Jr., D. R. Blake, and F. S. Rowland, Hydrocarbon and halocarbon measurements as photochemical and dynamical indicators of atmospheric hydroxyl, atomic chlorine, and vertical mixing obtained during Lagrangian flights, J. Geophys. Res., 101, 4331-4340, 1996.
52. Worthy, D. E. J., N. B. A. Trivett, J. F. Hopper, and J. W. Bottenheim, Analysis of long-range transport events at Alert, Northwest Territories, during the Polar Sunrise Experiment, J. Geophys. Res., 99, 25,329-25,344, 1994.
53. Zetzsch, C., and W. Behnke, Heterogeneous reactions of chlorine compounds, in The Tropospheric Chemistry of Ozone in Polar Regions, edited by H. Niki and K. H. Becker, NATO ASI Ser., Ser. I, vol. 17, pp. 291-306, Springer-Verlag, New York, 1993.