Bis(benzene)chromium. A sandwich complex spin trap as revealed by ENDOR spectroscopy

Journal of the American Chemical Society

Volumn 120, Issue 32, 1998, Pages 8088-8092

  Samuel, E ^a   Caurant, D ^a   Gourier, D ^a   Elschenbroich, Ch ^b   Agbaria, K ^b  

^a PSL RESEARCH UNIVERSITY   (France)

^b PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

BIS(BENZENE)CHROMIUM; BUTYRONITRILE; CHROMIUM DERIVATIVE; NITROXIDE; RADICAL; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; ELECTRON NUCLEAR DOUBLE RESONANCE; METAL BINDING; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; SPECTROSCOPY;

EID: 0032547283     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja972539b     Document Type: Article

References (15)

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2. Trogler, W. C., Ed. Organometallic Radical Processes; Elsevier: Amsterdam, The Netherlands (J. Organomet. Chem. Library 1990, 22).
3. Herberich, G. E.; Schwarzer, J. Angew. Chem., Int. Ed. Engl. 1970, 9, 897.
4. 3 has been observed fairly recently and employed in organic synthesis: Schmalz, H. G.; Siegel, S.; Bats, J. W. Angew. Chem., Int. Ed. Engl. 1995, 34, 2383.
5. 3 has been observed fairly recently and employed in organic synthesis: Schmalz, H. G.; Siegel, S.; Bats, J. W. Angew. Chem., Int. Ed. Engl. 1995, 34, 2383.
6. (4) See for example: (a) Perkins, M. J. Adv. Phys. Org. Chem. 1980, 1, 17. (b) Chandra, H.; Davidson, M. T.; Symons, M. C. R. J. Chem. Soc., Faraday Trans. 1983, 79, 2705. (c) Janzen, E. G.; Liu, I. J. Magn. Reson. 1973, 9, 510.
7. (4) See for example: (a) Perkins, M. J. Adv. Phys. Org. Chem. 1980, 1, 17. (b) Chandra, H.; Davidson, M. T.; Symons, M. C. R. J. Chem. Soc., Faraday Trans. 1983, 79, 2705. (c) Janzen, E. G.; Liu, I. J. Magn. Reson. 1973, 9, 510.
8. (4) See for example: (a) Perkins, M. J. Adv. Phys. Org. Chem. 1980, 1, 17. (b) Chandra, H.; Davidson, M. T.; Symons, M. C. R. J. Chem. Soc., Faraday Trans. 1983, 79, 2705. (c) Janzen, E. G.; Liu, I. J. Magn. Reson. 1973, 9, 510.
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11. (7) For measuring techniques of the proton hyperfine parameters, see: (a) Gourier, D.; Samuel, E. J. Am. Chem. Soc. 1987, 109, 4571. (b) Gourier, D.; Samuel, E.; Bochmann, B.; Hahn, F.; Heck, J. Inorg. Chem. 1992, 31, 86.
12. For measuring techniques of the proton hyperfine parameters, see: (a) Gourier, D.; Samuel, E. J. Am. Chem. Soc. 1987, 109, 4571. (b) Gourier, D.; Samuel, E.; Bochmann, B.; Hahn, F.; Heck, J. Inorg. Chem. 1992, 31, 86.
13. 7)Cr: Elschenbroich, Ch.; Gerson, F.; Stohler, F. J. Am. Chem. Soc. 1973, 95, 6956.
14. Fossey, J.; Lefort, D.; Sorba, J. Free Radicals in Organic Chemistry; Wiley: Chichester, England, 1995; Chapter 14.
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