A photoluminescent copper(I) complex with an exceptionally high Cu(II)/Cu(I) redox potential: [Cu(bfp)2]+ (bfp = 2,9-bis-(trifluoromethyl)-1,10-phenanthroline)

Angewandte Chemie - International Edition

Volumn 37, Issue 11, 1998, Pages 1556-1558

  Miller, Mark T ^a   Gantzel, Peter K ^a   Karpishin, Timothy B ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Copper; Cyclic voltammetry; Electrochemistry; N ligands; Photochemistry

Indexed keywords

EID: 0032547052     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980619)37:11<1556::AID-ANIE1556>3.0.CO;2-W     Document Type: Article

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45. + couple is +1100 mV. For other high-potential Cu complexes with N ligands, see refs. [5g, 18] and a) B. R. James, R. J. P. Williams, J. Chem. Soc. 1961, 2007-2019; b) T. N. Sorrell, D. L. Jameson, Inorg. Chem. 1982, 21, 1014-1019; c) D. Datta, A. Chakravorty, ibid. 1983, 22, 1085-1090; d) E. Müller, C. Piguet, G. Bernardinelli, A. F. Williams, ibid. 1988, 27, 849-855; e) S. M. Carrier, C. E. Ruggiero, R. P Houser, W. B. Tolman, ibid. 1993, 32, 4889-4899; f) J. McMaster, R. L. Beddoes, D. Collison, D. R. Eardley, M. Helliwell, C. D. Garner, Chem. Eur. J. 1996, 2, 685-693.
46. + couple is +1100 mV. For other high-potential Cu complexes with N ligands, see refs. [5g, 18] and a) B. R. James, R. J. P. Williams, J. Chem. Soc. 1961, 2007-2019; b) T. N. Sorrell, D. L. Jameson, Inorg. Chem. 1982, 21, 1014-1019; c) D. Datta, A. Chakravorty, ibid. 1983, 22, 1085-1090; d) E. Müller, C. Piguet, G. Bernardinelli, A. F. Williams, ibid. 1988, 27, 849-855; e) S. M. Carrier, C. E. Ruggiero, R. P Houser, W. B. Tolman, ibid. 1993, 32, 4889-4899; f) J. McMaster, R. L. Beddoes, D. Collison, D. R. Eardley, M. Helliwell, C. D. Garner, Chem. Eur. J. 1996, 2, 685-693.
47. + couple is +1100 mV. For other high-potential Cu complexes with N ligands, see refs. [5g, 18] and a) B. R. James, R. J. P. Williams, J. Chem. Soc. 1961, 2007-2019; b) T. N. Sorrell, D. L. Jameson, Inorg. Chem. 1982, 21, 1014-1019; c) D. Datta, A. Chakravorty, ibid. 1983, 22, 1085-1090; d) E. Müller, C. Piguet, G. Bernardinelli, A. F. Williams, ibid. 1988, 27, 849-855; e) S. M. Carrier, C. E. Ruggiero, R. P Houser, W. B. Tolman, ibid. 1993, 32, 4889-4899; f) J. McMaster, R. L. Beddoes, D. Collison, D. R. Eardley, M. Helliwell, C. D. Garner, Chem. Eur. J. 1996, 2, 685-693.
48. + couple is +1100 mV. For other high-potential Cu complexes with N ligands, see refs. [5g, 18] and a) B. R. James, R. J. P. Williams, J. Chem. Soc. 1961, 2007-2019; b) T. N. Sorrell, D. L. Jameson, Inorg. Chem. 1982, 21, 1014-1019; c) D. Datta, A. Chakravorty, ibid. 1983, 22, 1085-1090; d) E. Müller, C. Piguet, G. Bernardinelli, A. F. Williams, ibid. 1988, 27, 849-855; e) S. M. Carrier, C. E. Ruggiero, R. P Houser, W. B. Tolman, ibid. 1993, 32, 4889-4899; f) J. McMaster, R. L. Beddoes, D. Collison, D. R. Eardley, M. Helliwell, C. D. Garner, Chem. Eur. J. 1996, 2, 685-693.
49. + couple is +1100 mV. For other high-potential Cu complexes with N ligands, see refs. [5g, 18] and a) B. R. James, R. J. P. Williams, J. Chem. Soc. 1961, 2007-2019; b) T. N. Sorrell, D. L. Jameson, Inorg. Chem. 1982, 21, 1014-1019; c) D. Datta, A. Chakravorty, ibid. 1983, 22, 1085-1090; d) E. Müller, C. Piguet, G. Bernardinelli, A. F. Williams, ibid. 1988, 27, 849-855; e) S. M. Carrier, C. E. Ruggiero, R. P Houser, W. B. Tolman, ibid. 1993, 32, 4889-4899; f) J. McMaster, R. L. Beddoes, D. Collison, D. R. Eardley, M. Helliwell, C. D. Garner, Chem. Eur. J. 1996, 2, 685-693.
50. + couple is +1100 mV. For other high-potential Cu complexes with N ligands, see refs. [5g, 18] and a) B. R. James, R. J. P. Williams, J. Chem. Soc. 1961, 2007-2019; b) T. N. Sorrell, D. L. Jameson, Inorg. Chem. 1982, 21, 1014-1019; c) D. Datta, A. Chakravorty, ibid. 1983, 22, 1085-1090; d) E. Müller, C. Piguet, G. Bernardinelli, A. F. Williams, ibid. 1988, 27, 849-855; e) S. M. Carrier, C. E. Ruggiero, R. P Houser, W. B. Tolman, ibid. 1993, 32, 4889-4899; f) J. McMaster, R. L. Beddoes, D. Collison, D. R. Eardley, M. Helliwell, C. D. Garner, Chem. Eur. J. 1996, 2, 685-693.
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