Alkenyl diols by E-Selective Horner-Wittig elimination: Formal synthesis of any isomer (RR, RS, SR or SS) bearing 1,5-related stereogenic centres across an E double bond

Tetrahedron Letters

Volumn 39, Issue 12, 1998, Pages 1633-1636

  Nelson, Adam ^a   Warren, Stuart ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENYL GROUP; FURAN DERIVATIVE; SODIUM BOROHYDRIDE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; OXIDATION; REDUCTION; STEREOISOMERISM; SYNTHESIS;

EID: 0032546221     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)10859-0     Document Type: Article

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34. 22. Nelson, A.; Warren, S. J. Chem. Soc., Perkin Trans. 1, 1997, 2645-2657.
35. 2a
36. 1,5syn-6 could be made from the same β-hydroxy phosphine oxide (4a) since 4c was itself synthesized from 4a by an oxidation-reduction sequence.
37. 25. For other ways to analyse remote stereochemical relationships, see reference 28, references therein and: Neeland, E. G.; Sharadenda, A.; Weiler, L. Tetrahedron Lett., 1996, 37, 5069-5072; Stanway, S. J.; Thomas, E. J. J. Chem. Soc., Chem. Commun., 1994, 285-286.
38. 25. For other ways to analyse remote stereochemical relationships, see reference 28, references therein and: Neeland, E. G.; Sharadenda, A.; Weiler, L. Tetrahedron Lett., 1996, 37, 5069-5072; Stanway, S. J.; Thomas, E. J. J. Chem. Soc., Chem. Commun., 1994, 285-286.
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