Stereoselective synthesis of arabinose-derived phosphonates

Tetrahedron Letters

Volumn 39, Issue 8, 1998, Pages 825-828

  Bouix, Claire ^a   Bisseret, Philippe ^a   Eustache, Jacques ^a  

^a UNIVERSITÉ DE HAUTE ALSACE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ARABINOSE DERIVATIVE; GLYCOSYLTRANSFERASE; PHOSPHONIC ACID DERIVATIVE;

ARTICLE; CONTROLLED STUDY; DRUG SYNTHESIS; ENZYME INHIBITION; NONHUMAN; STEREOCHEMISTRY;

EID: 0032546145     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)10723-7     Document Type: Article

References (18)

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3. 3. While this work was in progress, the preparation of (difluoromethyl) phosphonate azasugars, using a different synthetic route was published: Behr, J-B.; Evina, C,M.; Phung, N.; Guillerm, G. J.Chem.Soc., Perkin Trans.1 1997, 1597-1597.
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14. b-P). Enamino form: d 3.85 (dd, J = 13 and 1 Hz, =C(H)-P), 7.06 (broad s, NH).
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17. 16. Using palladium 10% on charcoal (2-propanol, P = 1 bar) no reaction occured at 20°C. In refluxing 2-propanol, only incomplete hydrogenolysis of the benzyl groups and no reduction of the imine / enamine system were observed.
18. 3).