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Compound 15 of unknown enantiomeric composition was identified as a constituent of Virginia tobacco and recognized as a valuable flavor component: A. J. N. Bolt, S. W. Purkis, J. S. Sadd, Phytochemistry 1983, 22, 613; D. Helmlinger, V. Krasnobajew (Givaudan), CH654,567, 1986 [Chem. Abstr. 1986, 105, 113607h].
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0344278410
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The anti π face of 7pe displays a higher electron density in the HOMO than the syn face (PM3)
-
The anti π face of 7pe displays a higher electron density in the HOMO than the syn face (PM3).
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41
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0345572393
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[15] for 1pa-7pa, 1pe-7pe, and 22 showed that the syn faces exhibit a more negative electrostatic field
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[15] for 1pa-7pa, 1pe-7pe, and 22 showed that the syn faces exhibit a more negative electrostatic field.
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