Redox-active nanotubes of vanadium oxide

Angewandte Chemie - International Edition

Volumn 37, Issue 9, 1998, Pages 1263-1265

  Spahr, Michael E ^a   Bitterli, Petra ^b   Nesper, Reinhard ^a   Müller, Martin ^b   Krumeich, F ^b   Nissen, Hans U ^b  

^a LABORATORY OF INORGANIC CHEMISTRY   (Switzerland)

^b NONE

Author keywords

Electron microscopy; Nanostructures; Oxides; Vanadium

Indexed keywords

EID: 0032543183     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980518)37:9<1263::AID-ANIE1263>3.0.CO;2-R     Document Type: Article

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16. 2O (15 mL) under vigorous stirring followed by the aging of the hydrolysis product for a few hours to a full day leads to a yellow, lamellar-structured composite of surfactant and hydrolyzed vanadium oxide component. The hydrothermal reaction of this hydrolysis product in an autoclave at 180°C afforded after about a week black, isolated or starlike grown-together nanotubes with open ends as the main product. A molar ratio of 1:1 afforded predominantly nanotubes with closed ends.
17. International patent number PCT/CH97/00470, Swiss Federal Institute of Interlectual Property, Bern, Switzerland